Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature
Room-temperature absorption and luminescence spectra of the R 1 and R 2 bands in a single crystal of Ruby Al 2 O 3 :Cr 3+ (0.05%) are analyzed. The luminescence in these bands was induced both by crystal excitation by radiation of a halogen lamp and by selective excitation of two upper levels of the...
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| Veröffentlicht in: | Optics and spectroscopy 2021, Vol.129 (4), p.440-451 |
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| container_title | Optics and spectroscopy |
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| creator | Arakelyan, V. S. Butaeva, T. I. Muzhikyan, P. H. Zargaryan, D. G. Kostanyan, R. B. |
| description | Room-temperature absorption and luminescence spectra of the
R
1
and
R
2
bands in a single crystal of Ruby Al
2
O
3
:Cr
3+
(0.05%) are analyzed. The luminescence in these bands was induced both by crystal excitation by radiation of a halogen lamp and by selective excitation of two upper levels of the
2
T
1
state by radiation of a tunable laser diode (656–662 nm). Four different shifts of the
R
1
and
R
2
bands and four different distances between these bands the change in which is a multiple of ~0.52 cm
–1
are discovered in spectra of se-lectively excited luminescence bands. Detailed comparative analysis of the obtained spectral bands of luminescence and corresponding absorption spectra allowed determining combined structure of each of the
R
1
and
R
2
bands formed by satellite doublets of these bands associated with all four stable isotopes
50
Cr
3+
,
52
Cr
3+
,
53
Cr
3+
, and
54
Cr
3–
of chromium ions. Splitting of these doublets varies from 7.04 to 9.14 сm
–1
depending on the isotope mass. |
| doi_str_mv | 10.1134/S0030400X21040056 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2638062741</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2638062741</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1136-2649d9c42a8d7e2e293d3009343356f27a24988a0f91779a761609b53b28afb3</originalsourceid><addsrcrecordid>eNp1UEtLxDAQDqLg-vgB3gIepTqTpGlz1MXHwoLQ3YO3krbpPthtapIe9t-buoIH8fQN8z2G-Qi5QbhH5OJhAcBBAHwwHCGVJ2SCqWSJVIinZDLSycifkwvvtwCIuVATsl4EN9RhcIbaloa1oQVS3TW0YPQpoh_XM2-D7c33PHX8js5sRzcd1XSx6VY7E5cHH_Ru5IuhOlAdaGHtni7NvjdOj_FX5KzVO2-uf_CSLF-el9O3ZP7-Ops-zpM6_iETJoVqVC2YzpvMMMMUbziA4oLzVLYs00yoPNfQKswypTOJElSV8orluq34Jbk9xvbOfg7Gh3JrB9fFiyWTPAfJMoFRhUdV7az3zrRl7zZ77Q4lQjn2Wf7pM3rY0eOjtlsZ95v8v-kLjhNzUA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2638062741</pqid></control><display><type>article</type><title>Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature</title><source>SpringerNature Journals</source><creator>Arakelyan, V. S. ; Butaeva, T. I. ; Muzhikyan, P. H. ; Zargaryan, D. G. ; Kostanyan, R. B.</creator><creatorcontrib>Arakelyan, V. S. ; Butaeva, T. I. ; Muzhikyan, P. H. ; Zargaryan, D. G. ; Kostanyan, R. B.</creatorcontrib><description>Room-temperature absorption and luminescence spectra of the
R
1
and
R
2
bands in a single crystal of Ruby Al
2
O
3
:Cr
3+
(0.05%) are analyzed. The luminescence in these bands was induced both by crystal excitation by radiation of a halogen lamp and by selective excitation of two upper levels of the
2
T
1
state by radiation of a tunable laser diode (656–662 nm). Four different shifts of the
R
1
and
R
2
bands and four different distances between these bands the change in which is a multiple of ~0.52 cm
–1
are discovered in spectra of se-lectively excited luminescence bands. Detailed comparative analysis of the obtained spectral bands of luminescence and corresponding absorption spectra allowed determining combined structure of each of the
R
1
and
R
2
bands formed by satellite doublets of these bands associated with all four stable isotopes
50
Cr
3+
,
52
Cr
3+
,
53
Cr
3+
, and
54
Cr
3–
of chromium ions. Splitting of these doublets varies from 7.04 to 9.14 сm
–1
depending on the isotope mass.</description><identifier>ISSN: 0030-400X</identifier><identifier>EISSN: 1562-6911</identifier><identifier>DOI: 10.1134/S0030400X21040056</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectra ; Aluminum oxide ; Banded structure ; Excitation ; Excitation spectra ; Isotopes ; Lasers ; Luminescence ; Optical Devices ; Optics ; Photonics ; Physics ; Physics and Astronomy ; Radiation ; Room temperature ; Ruby ; Semiconductor lasers ; Single crystals ; Spectral bands ; Trivalent chromium ; Tunable lasers</subject><ispartof>Optics and spectroscopy, 2021, Vol.129 (4), p.440-451</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0030-400X, Optics and Spectroscopy, 2021, Vol. 129, No. 4, pp. 440–451. © Pleiades Publishing, Ltd., 2021. ISSN 0030-400X, Optics and Spectroscopy, 2021. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Optika i Spektroskopiya, 2021, Vol. 129, No. 4, pp. 494–505.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1136-2649d9c42a8d7e2e293d3009343356f27a24988a0f91779a761609b53b28afb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0030400X21040056$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0030400X21040056$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Arakelyan, V. S.</creatorcontrib><creatorcontrib>Butaeva, T. I.</creatorcontrib><creatorcontrib>Muzhikyan, P. H.</creatorcontrib><creatorcontrib>Zargaryan, D. G.</creatorcontrib><creatorcontrib>Kostanyan, R. B.</creatorcontrib><title>Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature</title><title>Optics and spectroscopy</title><addtitle>Opt. Spectrosc</addtitle><description>Room-temperature absorption and luminescence spectra of the
R
1
and
R
2
bands in a single crystal of Ruby Al
2
O
3
:Cr
3+
(0.05%) are analyzed. The luminescence in these bands was induced both by crystal excitation by radiation of a halogen lamp and by selective excitation of two upper levels of the
2
T
1
state by radiation of a tunable laser diode (656–662 nm). Four different shifts of the
R
1
and
R
2
bands and four different distances between these bands the change in which is a multiple of ~0.52 cm
–1
are discovered in spectra of se-lectively excited luminescence bands. Detailed comparative analysis of the obtained spectral bands of luminescence and corresponding absorption spectra allowed determining combined structure of each of the
R
1
and
R
2
bands formed by satellite doublets of these bands associated with all four stable isotopes
50
Cr
3+
,
52
Cr
3+
,
53
Cr
3+
, and
54
Cr
3–
of chromium ions. Splitting of these doublets varies from 7.04 to 9.14 сm
–1
depending on the isotope mass.</description><subject>Absorption spectra</subject><subject>Aluminum oxide</subject><subject>Banded structure</subject><subject>Excitation</subject><subject>Excitation spectra</subject><subject>Isotopes</subject><subject>Lasers</subject><subject>Luminescence</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Radiation</subject><subject>Room temperature</subject><subject>Ruby</subject><subject>Semiconductor lasers</subject><subject>Single crystals</subject><subject>Spectral bands</subject><subject>Trivalent chromium</subject><subject>Tunable lasers</subject><issn>0030-400X</issn><issn>1562-6911</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UEtLxDAQDqLg-vgB3gIepTqTpGlz1MXHwoLQ3YO3krbpPthtapIe9t-buoIH8fQN8z2G-Qi5QbhH5OJhAcBBAHwwHCGVJ2SCqWSJVIinZDLSycifkwvvtwCIuVATsl4EN9RhcIbaloa1oQVS3TW0YPQpoh_XM2-D7c33PHX8js5sRzcd1XSx6VY7E5cHH_Ru5IuhOlAdaGHtni7NvjdOj_FX5KzVO2-uf_CSLF-el9O3ZP7-Ops-zpM6_iETJoVqVC2YzpvMMMMUbziA4oLzVLYs00yoPNfQKswypTOJElSV8orluq34Jbk9xvbOfg7Gh3JrB9fFiyWTPAfJMoFRhUdV7az3zrRl7zZ77Q4lQjn2Wf7pM3rY0eOjtlsZ95v8v-kLjhNzUA</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Arakelyan, V. S.</creator><creator>Butaeva, T. I.</creator><creator>Muzhikyan, P. H.</creator><creator>Zargaryan, D. G.</creator><creator>Kostanyan, R. B.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature</title><author>Arakelyan, V. S. ; Butaeva, T. I. ; Muzhikyan, P. H. ; Zargaryan, D. G. ; Kostanyan, R. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1136-2649d9c42a8d7e2e293d3009343356f27a24988a0f91779a761609b53b28afb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Absorption spectra</topic><topic>Aluminum oxide</topic><topic>Banded structure</topic><topic>Excitation</topic><topic>Excitation spectra</topic><topic>Isotopes</topic><topic>Lasers</topic><topic>Luminescence</topic><topic>Optical Devices</topic><topic>Optics</topic><topic>Photonics</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Radiation</topic><topic>Room temperature</topic><topic>Ruby</topic><topic>Semiconductor lasers</topic><topic>Single crystals</topic><topic>Spectral bands</topic><topic>Trivalent chromium</topic><topic>Tunable lasers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arakelyan, V. S.</creatorcontrib><creatorcontrib>Butaeva, T. I.</creatorcontrib><creatorcontrib>Muzhikyan, P. H.</creatorcontrib><creatorcontrib>Zargaryan, D. G.</creatorcontrib><creatorcontrib>Kostanyan, R. B.</creatorcontrib><collection>CrossRef</collection><jtitle>Optics and spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arakelyan, V. S.</au><au>Butaeva, T. I.</au><au>Muzhikyan, P. H.</au><au>Zargaryan, D. G.</au><au>Kostanyan, R. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature</atitle><jtitle>Optics and spectroscopy</jtitle><stitle>Opt. Spectrosc</stitle><date>2021</date><risdate>2021</risdate><volume>129</volume><issue>4</issue><spage>440</spage><epage>451</epage><pages>440-451</pages><issn>0030-400X</issn><eissn>1562-6911</eissn><abstract>Room-temperature absorption and luminescence spectra of the
R
1
and
R
2
bands in a single crystal of Ruby Al
2
O
3
:Cr
3+
(0.05%) are analyzed. The luminescence in these bands was induced both by crystal excitation by radiation of a halogen lamp and by selective excitation of two upper levels of the
2
T
1
state by radiation of a tunable laser diode (656–662 nm). Four different shifts of the
R
1
and
R
2
bands and four different distances between these bands the change in which is a multiple of ~0.52 cm
–1
are discovered in spectra of se-lectively excited luminescence bands. Detailed comparative analysis of the obtained spectral bands of luminescence and corresponding absorption spectra allowed determining combined structure of each of the
R
1
and
R
2
bands formed by satellite doublets of these bands associated with all four stable isotopes
50
Cr
3+
,
52
Cr
3+
,
53
Cr
3+
, and
54
Cr
3–
of chromium ions. Splitting of these doublets varies from 7.04 to 9.14 сm
–1
depending on the isotope mass.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0030400X21040056</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0030-400X |
| ispartof | Optics and spectroscopy, 2021, Vol.129 (4), p.440-451 |
| issn | 0030-400X 1562-6911 |
| language | eng |
| recordid | cdi_proquest_journals_2638062741 |
| source | SpringerNature Journals |
| subjects | Absorption spectra Aluminum oxide Banded structure Excitation Excitation spectra Isotopes Lasers Luminescence Optical Devices Optics Photonics Physics Physics and Astronomy Radiation Room temperature Ruby Semiconductor lasers Single crystals Spectral bands Trivalent chromium Tunable lasers |
| title | Structure of the R1 and R2 Bands of Isotopes of Cr3+ Ion in a Single Crystal of Ruby at Room Temperature |
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