Experimental observations of amorphization in multiple generations of boron carbide
Boron carbide is an excellent armor material due to its light weight and ultrahigh hardness. However, high‐rate mechanical behavior can be degraded by stress‐induced amorphization. In this paper, we review the progressive advances in the understanding of amorphization in three successive generations...
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| Veröffentlicht in: | Journal of the American Ceramic Society 2022-05, Vol.105 (5), p.3008-3029 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Xie, Kelvin Y. Yang, Qirong Marvel, Christopher J. He, Mo‐Rigen LaSalvia, Jerry C. Harmer, Martin P. Hwang, Chawon Haber, Richard A. Hemker, Kevin J. |
| description | Boron carbide is an excellent armor material due to its light weight and ultrahigh hardness. However, high‐rate mechanical behavior can be degraded by stress‐induced amorphization. In this paper, we review the progressive advances in the understanding of amorphization in three successive generations of boron carbide: stoichiometric (undoped), B‐rich, and B/Si codoped boron carbides. For each generation of boron carbide, the crystal structure and microstructure are first discussed. Then, we outline the experimental observations of amorphization made by Raman spectroscopy and transmission electron microscopy. The susceptibility of amorphization in each generation of boron carbide will be compared and the fundamental mechanisms that explain the reduction in amorphization for B‐rich and B/Si codoped boron carbides elucidated. Comments on future research directions to further broaden and deepen the understanding of stress‐induced amorphization of boron carbide are also provided. |
| doi_str_mv | 10.1111/jace.18058 |
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However, high‐rate mechanical behavior can be degraded by stress‐induced amorphization. In this paper, we review the progressive advances in the understanding of amorphization in three successive generations of boron carbide: stoichiometric (undoped), B‐rich, and B/Si codoped boron carbides. For each generation of boron carbide, the crystal structure and microstructure are first discussed. Then, we outline the experimental observations of amorphization made by Raman spectroscopy and transmission electron microscopy. The susceptibility of amorphization in each generation of boron carbide will be compared and the fundamental mechanisms that explain the reduction in amorphization for B‐rich and B/Si codoped boron carbides elucidated. 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Comments on future research directions to further broaden and deepen the understanding of stress‐induced amorphization of boron carbide are also provided.</description><subject>Amorphization</subject><subject>Armor</subject><subject>Boron</subject><subject>Boron carbide</subject><subject>Crystal structure</subject><subject>doping</subject><subject>Mechanical properties</subject><subject>Raman spectroscopy</subject><subject>transmission electron microscopy</subject><subject>Weight reduction</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqWw4QsisUNK8TNxllVVXkJiAawtxxmDqzQOdgqUr8dtkNgxm9GMzp3HReic4BlJcbXSBmZEYiEP0IQIQXJakeIQTTDGNC8lxcfoJMZVKkkl-QQ9Lb96CG4N3aDbzNcRwocenO9i5m2m1z70b-5738lcl6037eD6FrJX6CD8gbUPCTA61K6BU3RkdRvh7DdP0cv18nlxmz883twt5g-5YayUOQUocUM4F1zWlOFaS25lU9ISCmqFYbaQtkk306qilNNGNEYYXmFNatZYxqboYpzbB_--gTiold-ELq1UtGClwEnKE3U5Uib4GANY1ad_ddgqgtXONLUzTe1NSzAZ4U_XwvYfUt3PF8tR8wOHWW9e</recordid><startdate>202205</startdate><enddate>202205</enddate><creator>Xie, Kelvin Y.</creator><creator>Yang, Qirong</creator><creator>Marvel, Christopher J.</creator><creator>He, Mo‐Rigen</creator><creator>LaSalvia, Jerry C.</creator><creator>Harmer, Martin P.</creator><creator>Hwang, Chawon</creator><creator>Haber, Richard A.</creator><creator>Hemker, Kevin J.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8675-5321</orcidid><orcidid>https://orcid.org/0000-0002-7072-6961</orcidid><orcidid>https://orcid.org/0000-0002-6146-6862</orcidid><orcidid>https://orcid.org/0000-0001-8102-3041</orcidid><orcidid>https://orcid.org/0000-0002-5008-2222</orcidid></search><sort><creationdate>202205</creationdate><title>Experimental observations of amorphization in multiple generations of boron carbide</title><author>Xie, Kelvin Y. ; Yang, Qirong ; Marvel, Christopher J. ; He, Mo‐Rigen ; LaSalvia, Jerry C. ; Harmer, Martin P. ; Hwang, Chawon ; Haber, Richard A. ; Hemker, Kevin J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3378-2ee70d144548b230ba84f8d727e62f5c3f68fd7822992242d5dc5c490a1b3df33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Amorphization</topic><topic>Armor</topic><topic>Boron</topic><topic>Boron carbide</topic><topic>Crystal structure</topic><topic>doping</topic><topic>Mechanical properties</topic><topic>Raman spectroscopy</topic><topic>transmission electron microscopy</topic><topic>Weight reduction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, Kelvin Y.</creatorcontrib><creatorcontrib>Yang, Qirong</creatorcontrib><creatorcontrib>Marvel, Christopher J.</creatorcontrib><creatorcontrib>He, Mo‐Rigen</creatorcontrib><creatorcontrib>LaSalvia, Jerry C.</creatorcontrib><creatorcontrib>Harmer, Martin P.</creatorcontrib><creatorcontrib>Hwang, Chawon</creatorcontrib><creatorcontrib>Haber, Richard A.</creatorcontrib><creatorcontrib>Hemker, Kevin J.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, Kelvin Y.</au><au>Yang, Qirong</au><au>Marvel, Christopher J.</au><au>He, Mo‐Rigen</au><au>LaSalvia, Jerry C.</au><au>Harmer, Martin P.</au><au>Hwang, Chawon</au><au>Haber, Richard A.</au><au>Hemker, Kevin J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental observations of amorphization in multiple generations of boron carbide</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2022-05</date><risdate>2022</risdate><volume>105</volume><issue>5</issue><spage>3008</spage><epage>3029</epage><pages>3008-3029</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Boron carbide is an excellent armor material due to its light weight and ultrahigh hardness. 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| subjects | Amorphization Armor Boron Boron carbide Crystal structure doping Mechanical properties Raman spectroscopy transmission electron microscopy Weight reduction |
| title | Experimental observations of amorphization in multiple generations of boron carbide |
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