Electric Current Aligning Component Units during Graphene Fiber Joule Heating

Joule heating is featured with an extremely high rising rate of temperature with hundreds of kelvin per second, which has shown superiorities of high efficiency and energy conservation in graphene fabrication. Herein, we design a dynamic joule heating system for continuous synthesis of graphene fibe...

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Veröffentlicht in:Advanced functional materials 2022-03, Vol.32 (11), p.n/a
Hauptverfasser: Cheng, Yi, Cui, Guang, Liu, Changhao, Liu, Zhetong, Yan, Longge, Liu, Bingyao, Yuan, Hao, Shi, Pengcheng, Jiang, Jun, Huang, Kewen, Wang, Kun, Cheng, Shuting, Li, Junliang, Gao, Peng, Zhang, Xinfang, Qi, Yue, Liu, Zhongfan
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container_issue 11
container_start_page
container_title Advanced functional materials
container_volume 32
creator Cheng, Yi
Cui, Guang
Liu, Changhao
Liu, Zhetong
Yan, Longge
Liu, Bingyao
Yuan, Hao
Shi, Pengcheng
Jiang, Jun
Huang, Kewen
Wang, Kun
Cheng, Shuting
Li, Junliang
Gao, Peng
Zhang, Xinfang
Qi, Yue
Liu, Zhongfan
description Joule heating is featured with an extremely high rising rate of temperature with hundreds of kelvin per second, which has shown superiorities of high efficiency and energy conservation in graphene fabrication. Herein, we design a dynamic joule heating system for continuous synthesis of graphene fibers with ultrashort high‐temperature (≈2000 °C), treating time (≈20 min), and low electric energy consumption (≈2000 kJ m−1). During the joule heating fabrication, the current flowing through the fibers can manipulate the configuration of graphene sheets, the basic component units of fiber, and induce their alignment. Theoretical simulations reveal that graphene sheets tend to rotate towards the current direction under the current induced electric field for the highest stability with the lowest electric free energy and zero rotation torque. Therefore, the electrical and mechanical performances of as‐fabricated graphene fibers can be further improved in comparison with thermally annealed graphene fibers without applying current. A dynamic joule heating system is designed, enabling the ultrafast and continuous fabrication of graphene fibers with a high‐temperature treating time of ≈20 min. Innovatively, the current‐induced electric field is first utilized to adjust the conformation order of graphene sheets and thus improves the electrical and mechanical properties of as‐fabricated graphene fibers.
doi_str_mv 10.1002/adfm.202103493
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subjects component units
conformation order
Continuous fibers
electric current aligning
Electric fields
Energy consumption
Free energy
Graphene
graphene fibers
joule heating
Materials science
Ohmic dissipation
Resistance heating
Sheets
title Electric Current Aligning Component Units during Graphene Fiber Joule Heating
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