Effect of radical copolymerization of the (oxa)norbornene end-group of RAFT-prepared macromonomers on bottlebrush copolymer synthesis via ROMP

Bottlebrush polymers are attractive for use in a variety of different applications. Here we report the synthesis of two novel trithiocarbonate RAFT agents bearing either an oxanorbornenyl or norbornenyl moiety for bottlebrush synthesis via ROMP grafting-through polymerization. RAFT polymerization ki...

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Veröffentlicht in:	Polymer chemistry 2022-03, Vol.13 (10), p.1401-1410
Hauptverfasser:	Naguib, Mohamed, Nixon, Kate L., Keddie, Daniel J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylics Addition polymerization Chemical synthesis Copolymerization Copolymers Degree of polymerization Grafting Mass distribution Monomers Polymer chemistry Polymerization Polymers Propagation (polymerization)
Online-Zugang:	Volltext
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