The effect of ethylene glycol post-treatment on the electrical conductivity of PEDOT: PSS thin films
The application of organic conducting polymers such as poly (3,4-ethylene dioxythiophene): poly (4-styrene sulfonate) (PEDOT: PSS) is vastly expanding for the development of advanced and flexible organic electronic devices, such as solar cells, light-emitting diodes, and organic electrochemical tran...
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description | The application of organic conducting polymers such as poly (3,4-ethylene dioxythiophene): poly (4-styrene sulfonate) (PEDOT: PSS) is vastly expanding for the development of advanced and flexible organic electronic devices, such as solar cells, light-emitting diodes, and organic electrochemical transistors (OECTs). Also, PEDOT: PSS can perfectly replace high-cost Indium tin oxide (ITO) thin films. In this study, PEDOT: PSS was synthesized
via
the chemical oxidative polymerization method. The film formation was carried out through a feasible drop-casting method onto a cleaned glass substrate. To further enhance the conductivity of pristine PEDOT: PSS, the PEDOT: PSS thin films were post-treated with different concentrations (3, 5, and 7% v/v) of ethylene glycol (EG). Based on the electrochemical impedance spectroscopy (EIS) analysis, it was revealed that the post-treated sample had a higher conductivity value compared to the untreated sample (2.48 × 10
-4
S/cm), with the highest recorded conductivity value of 2.67 ×10
-3
S/cm at 5% v/v of EG. This result corresponds to the previous study, which highlighted that the optimum concentration of EG is 5% v/v to achieve the optimum conductivity value for thin film application. Furthermore, the structural properties of the thin films were characterized using Fourier transform infrared (FTIR) spectroscopy to confirm the presence of PEDOT: PSS and EG in the samples. |
doi_str_mv | 10.1088/1742-6596/2169/1/012036 |
format | Article |
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via
the chemical oxidative polymerization method. The film formation was carried out through a feasible drop-casting method onto a cleaned glass substrate. To further enhance the conductivity of pristine PEDOT: PSS, the PEDOT: PSS thin films were post-treated with different concentrations (3, 5, and 7% v/v) of ethylene glycol (EG). Based on the electrochemical impedance spectroscopy (EIS) analysis, it was revealed that the post-treated sample had a higher conductivity value compared to the untreated sample (2.48 × 10
-4
S/cm), with the highest recorded conductivity value of 2.67 ×10
-3
S/cm at 5% v/v of EG. This result corresponds to the previous study, which highlighted that the optimum concentration of EG is 5% v/v to achieve the optimum conductivity value for thin film application. Furthermore, the structural properties of the thin films were characterized using Fourier transform infrared (FTIR) spectroscopy to confirm the presence of PEDOT: PSS and EG in the samples.</description><identifier>ISSN: 1742-6588</identifier><identifier>EISSN: 1742-6596</identifier><identifier>DOI: 10.1088/1742-6596/2169/1/012036</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Chemical synthesis ; Conducting polymers ; Electrical resistivity ; Electrochemical impedance spectroscopy ; Electronic devices ; Ethylene glycol ; Fourier transforms ; Glass substrates ; Indium tin oxides ; Infrared spectroscopy ; Light emitting diodes ; Photovoltaic cells ; Physics ; Solar cells ; Spectrum analysis ; Thin films ; Transistors</subject><ispartof>Journal of physics. Conference series, 2022-01, Vol.2169 (1), p.12036</ispartof><rights>Published under licence by IOP Publishing Ltd</rights><rights>Published under licence by IOP Publishing Ltd. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3286-ed162953d730653012183fd535dac4632c4b3f0fd9c7239a214627c463f136d33</citedby><cites>FETCH-LOGICAL-c3286-ed162953d730653012183fd535dac4632c4b3f0fd9c7239a214627c463f136d33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/1742-6596/2169/1/012036/pdf$$EPDF$$P50$$Giop$$Hfree_for_read</linktopdf><link.rule.ids>314,776,780,27903,27904,38847,38869,53819,53846</link.rule.ids></links><search><creatorcontrib>Asri, Nurul Ain Najihah</creatorcontrib><creatorcontrib>Amir, Baharin</creatorcontrib><creatorcontrib>Ramli, Anis Syahirah</creatorcontrib><creatorcontrib>Safian, Muhd Fauzi</creatorcontrib><creatorcontrib>Zakaria, Azlan</creatorcontrib><creatorcontrib>Jani, Nur Aimi</creatorcontrib><creatorcontrib>Mahat, Mohd Muzamir</creatorcontrib><title>The effect of ethylene glycol post-treatment on the electrical conductivity of PEDOT: PSS thin films</title><title>Journal of physics. Conference series</title><addtitle>J. Phys.: Conf. Ser</addtitle><description>The application of organic conducting polymers such as poly (3,4-ethylene dioxythiophene): poly (4-styrene sulfonate) (PEDOT: PSS) is vastly expanding for the development of advanced and flexible organic electronic devices, such as solar cells, light-emitting diodes, and organic electrochemical transistors (OECTs). Also, PEDOT: PSS can perfectly replace high-cost Indium tin oxide (ITO) thin films. In this study, PEDOT: PSS was synthesized
via
the chemical oxidative polymerization method. The film formation was carried out through a feasible drop-casting method onto a cleaned glass substrate. To further enhance the conductivity of pristine PEDOT: PSS, the PEDOT: PSS thin films were post-treated with different concentrations (3, 5, and 7% v/v) of ethylene glycol (EG). Based on the electrochemical impedance spectroscopy (EIS) analysis, it was revealed that the post-treated sample had a higher conductivity value compared to the untreated sample (2.48 × 10
-4
S/cm), with the highest recorded conductivity value of 2.67 ×10
-3
S/cm at 5% v/v of EG. This result corresponds to the previous study, which highlighted that the optimum concentration of EG is 5% v/v to achieve the optimum conductivity value for thin film application. Furthermore, the structural properties of the thin films were characterized using Fourier transform infrared (FTIR) spectroscopy to confirm the presence of PEDOT: PSS and EG in the samples.</description><subject>Chemical synthesis</subject><subject>Conducting polymers</subject><subject>Electrical resistivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electronic devices</subject><subject>Ethylene glycol</subject><subject>Fourier transforms</subject><subject>Glass substrates</subject><subject>Indium tin oxides</subject><subject>Infrared spectroscopy</subject><subject>Light emitting diodes</subject><subject>Photovoltaic cells</subject><subject>Physics</subject><subject>Solar cells</subject><subject>Spectrum analysis</subject><subject>Thin films</subject><subject>Transistors</subject><issn>1742-6588</issn><issn>1742-6596</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFkF1LwzAUhoMoOKe_wYB3Ql0-2jT1Tub8YrDB5nWo-XAdXVOTTOi_N6UyEQTPTQ6c57yHPABcYnSDEecTnKckYVnBJgSzYoInCBNE2REYHSbHh57zU3Dm_RYhGisfAbXeaKiN0TJAa6AOm67WjYbvdSdtDVvrQxKcLsNON5FoYOj5OuKukmUNpW3UXobqswpdH7Cc3S_Wt3C5WkWyaqCp6p0_ByemrL2--H7H4PVhtp4-JfPF4_P0bp5ISjhLtMKMFBlVOUUso_EfmFOjMpqpUqaMEpm-UYOMKmROaFESnDKS9xODKVOUjsHVkNs6-7HXPoit3bsmnhSE0YwzVnASqXygpLPeO21E66pd6TqBkeiVil6W6MWJXqnAYlAaN6-Hzcq2P9Evy-nqNyhaZSJM_4D_O_EF-umEcw</recordid><startdate>20220101</startdate><enddate>20220101</enddate><creator>Asri, Nurul Ain Najihah</creator><creator>Amir, Baharin</creator><creator>Ramli, Anis Syahirah</creator><creator>Safian, Muhd Fauzi</creator><creator>Zakaria, Azlan</creator><creator>Jani, Nur Aimi</creator><creator>Mahat, Mohd Muzamir</creator><general>IOP Publishing</general><scope>O3W</scope><scope>TSCCA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>H8D</scope><scope>HCIFZ</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20220101</creationdate><title>The effect of ethylene glycol post-treatment on the electrical conductivity of PEDOT: PSS thin films</title><author>Asri, Nurul Ain Najihah ; Amir, Baharin ; Ramli, Anis Syahirah ; Safian, Muhd Fauzi ; Zakaria, Azlan ; Jani, Nur Aimi ; Mahat, Mohd Muzamir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3286-ed162953d730653012183fd535dac4632c4b3f0fd9c7239a214627c463f136d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical synthesis</topic><topic>Conducting polymers</topic><topic>Electrical resistivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electronic devices</topic><topic>Ethylene glycol</topic><topic>Fourier transforms</topic><topic>Glass substrates</topic><topic>Indium tin oxides</topic><topic>Infrared spectroscopy</topic><topic>Light emitting diodes</topic><topic>Photovoltaic cells</topic><topic>Physics</topic><topic>Solar cells</topic><topic>Spectrum analysis</topic><topic>Thin films</topic><topic>Transistors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Asri, Nurul Ain Najihah</creatorcontrib><creatorcontrib>Amir, Baharin</creatorcontrib><creatorcontrib>Ramli, Anis Syahirah</creatorcontrib><creatorcontrib>Safian, Muhd Fauzi</creatorcontrib><creatorcontrib>Zakaria, Azlan</creatorcontrib><creatorcontrib>Jani, Nur Aimi</creatorcontrib><creatorcontrib>Mahat, Mohd Muzamir</creatorcontrib><collection>IOP Publishing</collection><collection>IOPscience (Open Access)</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>Advanced Technologies & Aerospace Database (1962 - current)</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Aerospace Database</collection><collection>SciTech Premium Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest advanced technologies & aerospace journals</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of physics. Conference series</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Asri, Nurul Ain Najihah</au><au>Amir, Baharin</au><au>Ramli, Anis Syahirah</au><au>Safian, Muhd Fauzi</au><au>Zakaria, Azlan</au><au>Jani, Nur Aimi</au><au>Mahat, Mohd Muzamir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of ethylene glycol post-treatment on the electrical conductivity of PEDOT: PSS thin films</atitle><jtitle>Journal of physics. Conference series</jtitle><addtitle>J. Phys.: Conf. Ser</addtitle><date>2022-01-01</date><risdate>2022</risdate><volume>2169</volume><issue>1</issue><spage>12036</spage><pages>12036-</pages><issn>1742-6588</issn><eissn>1742-6596</eissn><abstract>The application of organic conducting polymers such as poly (3,4-ethylene dioxythiophene): poly (4-styrene sulfonate) (PEDOT: PSS) is vastly expanding for the development of advanced and flexible organic electronic devices, such as solar cells, light-emitting diodes, and organic electrochemical transistors (OECTs). Also, PEDOT: PSS can perfectly replace high-cost Indium tin oxide (ITO) thin films. In this study, PEDOT: PSS was synthesized
via
the chemical oxidative polymerization method. The film formation was carried out through a feasible drop-casting method onto a cleaned glass substrate. To further enhance the conductivity of pristine PEDOT: PSS, the PEDOT: PSS thin films were post-treated with different concentrations (3, 5, and 7% v/v) of ethylene glycol (EG). Based on the electrochemical impedance spectroscopy (EIS) analysis, it was revealed that the post-treated sample had a higher conductivity value compared to the untreated sample (2.48 × 10
-4
S/cm), with the highest recorded conductivity value of 2.67 ×10
-3
S/cm at 5% v/v of EG. This result corresponds to the previous study, which highlighted that the optimum concentration of EG is 5% v/v to achieve the optimum conductivity value for thin film application. Furthermore, the structural properties of the thin films were characterized using Fourier transform infrared (FTIR) spectroscopy to confirm the presence of PEDOT: PSS and EG in the samples.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/1742-6596/2169/1/012036</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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source | Full-Text Journals in Chemistry (Open access); Institute of Physics; IOP Publishing; Alma/SFX Local Collection; EZB Electronic Journals Library |
subjects | Chemical synthesis Conducting polymers Electrical resistivity Electrochemical impedance spectroscopy Electronic devices Ethylene glycol Fourier transforms Glass substrates Indium tin oxides Infrared spectroscopy Light emitting diodes Photovoltaic cells Physics Solar cells Spectrum analysis Thin films Transistors |
title | The effect of ethylene glycol post-treatment on the electrical conductivity of PEDOT: PSS thin films |
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