Bicyclic (alkyl)(amino)carbene (BICAAC) as a metal-free catalyst for reduction of nitriles to amines

Bicyclic (alkyl)(amino)carbene (BICAAC) is introduced as a metal-free catalyst for the reduction of various nitriles to the corresponding amine hydrochloride salts in the presence of pinacolborane. Mechanistic investigations combining experiments and DFT calculations suggest a B-H addition to the ca...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (18), p.347-35
Hauptverfasser:	Gautam, Nimisha, Logdi, Ratan, Sreejyothi, Rajendran, N. M, Tiwari, Ashwani K, Mandal, Swadhin K
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Catalysts Nitriles Reduction (metal working)
Online-Zugang:	Volltext
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