Ultrahigh strengthening effect induced by element addition in nanostructural (TiVCr)100−xWx medium entropy alloy
•DC magnetron co-sputtering technology was performed to synthesize (TiVCr)100−xWx alloy films.•Doping W into TiVCr alloys film induces a phase transition from amorphous to quasicrystal and nanocrystal.•An ultrahigh strengthening effect where the strength is enhanced by two times was observed. In thi...
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Veröffentlicht in: | Journal of alloys and compounds 2022-04, Vol.899, p.163329, Article 163329 |
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container_title | Journal of alloys and compounds |
container_volume | 899 |
creator | Zhang, Z.J. Ma, Y.J. Han, X.T. Chen, J.H. Li, G.J. Shi, H.Q. Wang, L. Cao, Z.H. Meng, X.K. |
description | •DC magnetron co-sputtering technology was performed to synthesize (TiVCr)100−xWx alloy films.•Doping W into TiVCr alloys film induces a phase transition from amorphous to quasicrystal and nanocrystal.•An ultrahigh strengthening effect where the strength is enhanced by two times was observed.
In this work, we have investigated the effect of W addition on microstructure and mechanical properties of equiatomic TiVCr medium entropy alloy films. It is found that a transition from amorphous phase to quasicrystal and nanocrystal occurs with increasing content of W, showing an improved crystallinity of the films. Hardness drastically increases with increasing W addition and reaches the maximum value of 7.2 GPa at 16.0 at% W content, which is two times higher than that of the initial sample. Amorphous phase strengthening, solid solution and precipitation strengthening become the dominant mechanism, responsible for the ultrahigh strengthening effect. |
doi_str_mv | 10.1016/j.jallcom.2021.163329 |
format | Article |
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In this work, we have investigated the effect of W addition on microstructure and mechanical properties of equiatomic TiVCr medium entropy alloy films. It is found that a transition from amorphous phase to quasicrystal and nanocrystal occurs with increasing content of W, showing an improved crystallinity of the films. Hardness drastically increases with increasing W addition and reaches the maximum value of 7.2 GPa at 16.0 at% W content, which is two times higher than that of the initial sample. Amorphous phase strengthening, solid solution and precipitation strengthening become the dominant mechanism, responsible for the ultrahigh strengthening effect.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2021.163329</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Alloys ; Entropy ; High entropy alloys ; Mechanical properties ; Medium entropy alloys ; Nanocomposite ; Nanocrystals ; Precipitation hardening ; Solid solutions ; Strengthening ; Strengthening effects ; Thin films</subject><ispartof>Journal of alloys and compounds, 2022-04, Vol.899, p.163329, Article 163329</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Apr 5, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-61bc8a7b08f5754b6b6754d93dd2fca2e2227f7819dd498a4a8a27ca1ef9d02f3</citedby><cites>FETCH-LOGICAL-c337t-61bc8a7b08f5754b6b6754d93dd2fca2e2227f7819dd498a4a8a27ca1ef9d02f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2021.163329$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids></links><search><creatorcontrib>Zhang, Z.J.</creatorcontrib><creatorcontrib>Ma, Y.J.</creatorcontrib><creatorcontrib>Han, X.T.</creatorcontrib><creatorcontrib>Chen, J.H.</creatorcontrib><creatorcontrib>Li, G.J.</creatorcontrib><creatorcontrib>Shi, H.Q.</creatorcontrib><creatorcontrib>Wang, L.</creatorcontrib><creatorcontrib>Cao, Z.H.</creatorcontrib><creatorcontrib>Meng, X.K.</creatorcontrib><title>Ultrahigh strengthening effect induced by element addition in nanostructural (TiVCr)100−xWx medium entropy alloy</title><title>Journal of alloys and compounds</title><description>•DC magnetron co-sputtering technology was performed to synthesize (TiVCr)100−xWx alloy films.•Doping W into TiVCr alloys film induces a phase transition from amorphous to quasicrystal and nanocrystal.•An ultrahigh strengthening effect where the strength is enhanced by two times was observed.
In this work, we have investigated the effect of W addition on microstructure and mechanical properties of equiatomic TiVCr medium entropy alloy films. It is found that a transition from amorphous phase to quasicrystal and nanocrystal occurs with increasing content of W, showing an improved crystallinity of the films. Hardness drastically increases with increasing W addition and reaches the maximum value of 7.2 GPa at 16.0 at% W content, which is two times higher than that of the initial sample. Amorphous phase strengthening, solid solution and precipitation strengthening become the dominant mechanism, responsible for the ultrahigh strengthening effect.</description><subject>Alloys</subject><subject>Entropy</subject><subject>High entropy alloys</subject><subject>Mechanical properties</subject><subject>Medium entropy alloys</subject><subject>Nanocomposite</subject><subject>Nanocrystals</subject><subject>Precipitation hardening</subject><subject>Solid solutions</subject><subject>Strengthening</subject><subject>Strengthening effects</subject><subject>Thin films</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkM1O3DAUha2KSh0oj4BkiQ0sMvgnk9grhEZAKyGxgXZpOfb1jKPEHhynYt6AdR-xT4LRsO_qLO455977IXRGyZIS2lz1y14Pg4njkhFGl7ThnMkvaEFFy6u6aeQRWhDJVpXgQnxDx9PUE0Ko5HSB0vOQk976zRZPOUHY5C0EHzYYnAOTsQ92NmBxt8cwwAghY22tzz6GMsNBh1hys8lz0gO-ePK_1umSEvLv7e_r71c8gvXziEssxd0elzPj_jv66vQwwemnnqDnu9un9Y_q4fH-5_rmoTKct7lqaGeEbjsi3Kpd1V3TNUWs5NYyZzQDxljrWkGltbUUutZCs9ZoCk5awhw_QeeH3l2KLzNMWfVxTqGsVKzhdQEguSiu1cFlUpymBE7tkh912itK1Ade1atPvOoDrzrgLbnrQw7KC388JDUZD6Gw8qmAUzb6_zS8AzH6iLk</recordid><startdate>20220405</startdate><enddate>20220405</enddate><creator>Zhang, Z.J.</creator><creator>Ma, Y.J.</creator><creator>Han, X.T.</creator><creator>Chen, J.H.</creator><creator>Li, G.J.</creator><creator>Shi, H.Q.</creator><creator>Wang, L.</creator><creator>Cao, Z.H.</creator><creator>Meng, X.K.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220405</creationdate><title>Ultrahigh strengthening effect induced by element addition in nanostructural (TiVCr)100−xWx medium entropy alloy</title><author>Zhang, Z.J. ; Ma, Y.J. ; Han, X.T. ; Chen, J.H. ; Li, G.J. ; Shi, H.Q. ; Wang, L. ; Cao, Z.H. ; Meng, X.K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-61bc8a7b08f5754b6b6754d93dd2fca2e2227f7819dd498a4a8a27ca1ef9d02f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alloys</topic><topic>Entropy</topic><topic>High entropy alloys</topic><topic>Mechanical properties</topic><topic>Medium entropy alloys</topic><topic>Nanocomposite</topic><topic>Nanocrystals</topic><topic>Precipitation hardening</topic><topic>Solid solutions</topic><topic>Strengthening</topic><topic>Strengthening effects</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Z.J.</creatorcontrib><creatorcontrib>Ma, Y.J.</creatorcontrib><creatorcontrib>Han, X.T.</creatorcontrib><creatorcontrib>Chen, J.H.</creatorcontrib><creatorcontrib>Li, G.J.</creatorcontrib><creatorcontrib>Shi, H.Q.</creatorcontrib><creatorcontrib>Wang, L.</creatorcontrib><creatorcontrib>Cao, Z.H.</creatorcontrib><creatorcontrib>Meng, X.K.</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Z.J.</au><au>Ma, Y.J.</au><au>Han, X.T.</au><au>Chen, J.H.</au><au>Li, G.J.</au><au>Shi, H.Q.</au><au>Wang, L.</au><au>Cao, Z.H.</au><au>Meng, X.K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrahigh strengthening effect induced by element addition in nanostructural (TiVCr)100−xWx medium entropy alloy</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-04-05</date><risdate>2022</risdate><volume>899</volume><spage>163329</spage><pages>163329-</pages><artnum>163329</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>•DC magnetron co-sputtering technology was performed to synthesize (TiVCr)100−xWx alloy films.•Doping W into TiVCr alloys film induces a phase transition from amorphous to quasicrystal and nanocrystal.•An ultrahigh strengthening effect where the strength is enhanced by two times was observed.
In this work, we have investigated the effect of W addition on microstructure and mechanical properties of equiatomic TiVCr medium entropy alloy films. It is found that a transition from amorphous phase to quasicrystal and nanocrystal occurs with increasing content of W, showing an improved crystallinity of the films. Hardness drastically increases with increasing W addition and reaches the maximum value of 7.2 GPa at 16.0 at% W content, which is two times higher than that of the initial sample. Amorphous phase strengthening, solid solution and precipitation strengthening become the dominant mechanism, responsible for the ultrahigh strengthening effect.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2021.163329</doi></addata></record> |
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subjects | Alloys Entropy High entropy alloys Mechanical properties Medium entropy alloys Nanocomposite Nanocrystals Precipitation hardening Solid solutions Strengthening Strengthening effects Thin films |
title | Ultrahigh strengthening effect induced by element addition in nanostructural (TiVCr)100−xWx medium entropy alloy |
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