Spin crossover in iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine

Iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine possessing a high-temperature 1A1 ↔ 5T2 spin crossover were obtained. [Display omitted] •Fe(II) complexes with 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine are studied.•Fe(II) complexes exhibit high-temperature 1A1...

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Veröffentlicht in:	Inorganica Chimica Acta 2022-03, Vol.532, p.120746, Article 120746
Hauptverfasser:	Ivanova, Alina D., Korotaev, Evgeniy V., Komarov, Vladislav Yu, Sukhikh, Taisiya S., Trubina, Svetlana V., Sheludyakova, Liliya A., Petrov, Sergey A., Tikhonov, Alexsei Ya, Lavrenova, Lyudmila G.
Format:	Artikel
Sprache:	eng
Schlagworte:	2,6-bis(4,5-dimethyl-1H-imidazol-2-yl)pyridine Composition Coordination compounds Crossovers Crystal structure Dehydration EXAFS spectroscopy Fine structure High temperature Imidazole Iron Iron(II) complexes Ligands Magnetic permeability Mössbauer spectroscopy Pyridines Spin crossover Temperature dependence X ray absorption
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