Enhanced trimethylamine gas-sensing performance of CeO2 nanoparticles-decorated MoO3 nanorods

The MoO 3 nanorods decorated with CeO 2 were successfully synthesized by a two-step hydrothermal method, and the microstructure and morphology of CeO 2 /MoO 3 were determined by XRD, XPS, SEM, and TEM. It can be confirmed by SEM that the CeO 2 nanoparticles of uniform size were successfully compound...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2022-03, Vol.33 (7), p.3453-3464
Hauptverfasser: Zhang, Shuai, Zheng, Yukun, Song, Peng, Sun, Jing, Wang, Qi
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container_issue 7
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container_title Journal of materials science. Materials in electronics
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creator Zhang, Shuai
Zheng, Yukun
Song, Peng
Sun, Jing
Wang, Qi
description The MoO 3 nanorods decorated with CeO 2 were successfully synthesized by a two-step hydrothermal method, and the microstructure and morphology of CeO 2 /MoO 3 were determined by XRD, XPS, SEM, and TEM. It can be confirmed by SEM that the CeO 2 nanoparticles of uniform size were successfully compounded with MoO 3 nanorods. According to the gas sensitivity test results, the response value of the CeO 2 /MoO 3 sensors to trimethylamine gas has been enhanced by about 20 times, and the excellent catalytic performance of CeO 2 and the conversion of the oxidation state of Ce ions have played a vital role. The analysis of XPS spectrum reveals the effect of the conversion of Ce 3+ ions and Ce 4+ ions on the enhancement of gas sensitivity. In addition, the gas-sensing mechanism of CeO 2 /MoO 3 is discussed based on the change of resistance value, which shows the great potential of CeO 2 in the field of gas sensing.
doi_str_mv 10.1007/s10854-021-07539-1
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subjects Catalytic converters
Cerium oxides
Characterization and Evaluation of Materials
Chemistry and Materials Science
Conversion
Gas sensors
Materials Science
Nanoparticles
Nanorods
Optical and Electronic Materials
Oxidation
Sensitivity enhancement
Trimethylamine
Valence
X ray photoelectron spectroscopy
title Enhanced trimethylamine gas-sensing performance of CeO2 nanoparticles-decorated MoO3 nanorods
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