Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures
We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region. Combinations containing 10-60 mol% creatine yield a deep eutectic solvent with a glass transition temperature at 270 K. Addition of up to 70 mol% water to the binary mixture aff...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-02, Vol.58 (17), p.2838-2841 |
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creator | Heaney, Matthew P Adhikari, Laxmi Siegel, Asher L Pekar, Kyle B Lefton, Jonathan B McGuire, Claire Rungthanaphatsophon, Pokpong Walensky, Justin R Baker, Gary A Run evski, Tom e |
description | We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region. Combinations containing 10-60 mol% creatine yield a deep eutectic solvent with a glass transition temperature at 270 K. Addition of up to 70 mol% water to the binary mixture affords retention of the eutectic nature and a handle to vary solvent viscosity and polarity.
We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region. |
doi_str_mv | 10.1039/d1cc06088k |
format | Article |
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We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region.</description><subject>Binary mixtures</subject><subject>Citric acid</subject><subject>Creatine</subject><subject>Eutectics</subject><subject>Glass transition temperature</subject><subject>Phase diagrams</subject><subject>Solvents</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkUtLw0AQgBdRbK1evCsBLyJE95HdbI7S-sKCFxVvIdmd2K1NUnc3Yv-924cVnMvMMB_D8A1CxwRfEsyyK02UwgJL-bGD-oSJJOaJfNtd1jyLU5bwHjpwbopDEC73UY9xktCUyz56HQHMI-g8KG9U5NrZFzTeRaqt59Y407xHykLhTQNR0ehIGW8DVyijV72fgLHRZKFt4UFHtfn2nQV3iPaqYubgaJMH6OX25nl4H4-f7h6G1-NYMZb6mPESy4QSUSoNlApZlhUVgEFwrbQuGSiMS5nIilMQBdGCYi4ryaoyy7IK2ACdr_fObfvZgfN5bZyC2axooO1cTgVNkzSTwdMAnf1Dp21nm3BdoBglMk0oDdTFmlK2dc5ClQcNdWEXOcH50nY-IsPhyvZjgE83K7uyBr1Ff_UG4GQNWKe20793sR9pOoRn</recordid><startdate>20220224</startdate><enddate>20220224</enddate><creator>Heaney, Matthew P</creator><creator>Adhikari, Laxmi</creator><creator>Siegel, Asher L</creator><creator>Pekar, Kyle B</creator><creator>Lefton, Jonathan B</creator><creator>McGuire, Claire</creator><creator>Rungthanaphatsophon, Pokpong</creator><creator>Walensky, Justin R</creator><creator>Baker, Gary A</creator><creator>Run evski, Tom e</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6565-9509</orcidid><orcidid>https://orcid.org/0000-0003-4768-0376</orcidid><orcidid>https://orcid.org/0000-0003-0521-1889</orcidid><orcidid>https://orcid.org/0000-0003-0221-2675</orcidid><orcidid>https://orcid.org/0000-0002-3052-7730</orcidid><orcidid>https://orcid.org/0000-0003-0886-8464</orcidid></search><sort><creationdate>20220224</creationdate><title>Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures</title><author>Heaney, Matthew P ; Adhikari, Laxmi ; Siegel, Asher L ; Pekar, Kyle B ; Lefton, Jonathan B ; McGuire, Claire ; Rungthanaphatsophon, Pokpong ; Walensky, Justin R ; Baker, Gary A ; Run evski, Tom e</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-35b084216bcde2268bbf26e0e65dcddb3ec00b848f52e6a1d62058f83fb999fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Binary mixtures</topic><topic>Citric acid</topic><topic>Creatine</topic><topic>Eutectics</topic><topic>Glass transition temperature</topic><topic>Phase diagrams</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Heaney, Matthew P</creatorcontrib><creatorcontrib>Adhikari, Laxmi</creatorcontrib><creatorcontrib>Siegel, Asher L</creatorcontrib><creatorcontrib>Pekar, Kyle B</creatorcontrib><creatorcontrib>Lefton, Jonathan B</creatorcontrib><creatorcontrib>McGuire, Claire</creatorcontrib><creatorcontrib>Rungthanaphatsophon, Pokpong</creatorcontrib><creatorcontrib>Walensky, Justin R</creatorcontrib><creatorcontrib>Baker, Gary A</creatorcontrib><creatorcontrib>Run evski, Tom e</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Heaney, Matthew P</au><au>Adhikari, Laxmi</au><au>Siegel, Asher L</au><au>Pekar, Kyle B</au><au>Lefton, Jonathan B</au><au>McGuire, Claire</au><au>Rungthanaphatsophon, Pokpong</au><au>Walensky, Justin R</au><au>Baker, Gary A</au><au>Run evski, Tom e</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2022-02-24</date><risdate>2022</risdate><volume>58</volume><issue>17</issue><spage>2838</spage><epage>2841</epage><pages>2838-2841</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region. Combinations containing 10-60 mol% creatine yield a deep eutectic solvent with a glass transition temperature at 270 K. Addition of up to 70 mol% water to the binary mixture affords retention of the eutectic nature and a handle to vary solvent viscosity and polarity.
We report the phase diagram for the binary creatine-citric acid mixture which features a stable and broad eutectic region.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35142758</pmid><doi>10.1039/d1cc06088k</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-6565-9509</orcidid><orcidid>https://orcid.org/0000-0003-4768-0376</orcidid><orcidid>https://orcid.org/0000-0003-0521-1889</orcidid><orcidid>https://orcid.org/0000-0003-0221-2675</orcidid><orcidid>https://orcid.org/0000-0002-3052-7730</orcidid><orcidid>https://orcid.org/0000-0003-0886-8464</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Binary mixtures Citric acid Creatine Eutectics Glass transition temperature Phase diagrams Solvents |
title | Deep eutectic solvents comprising creatine and citric acid and their hydrated mixtures |
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