An experimental and computational study of the reaction between 2-methylallyl radicals and oxygen molecules: optimizing master equation parameters with trace fitting

We have investigated the reaction between 2-methylallyl radicals and oxygen molecules with experimental and computational methods. Kinetic experiments were conducted in a tubular laminar flow reactor using laser photolysis for radical production and photoionization mass spectrometry for detection. T...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2022-02, Vol.24 (8), p.4729-4742
Hauptverfasser:	Pekkanen, Timo T, Timonen, Raimo S, Robertson, Struan H, Lendvay, György, Joshi, Satya P, Reijonen, Timo T, Eskola, Arkke J
Format:	Artikel
Sprache:	eng
Schlagworte:	Laminar flow Low temperature Mass spectrometry Mathematical models Optimization Parameters Photoionization Photolysis Radicals Simulation Spontaneous combustion
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!