Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis
In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis disclosed the production formation mechanism. The impregnation of acid could reduce the activation energy and lower...
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| Veröffentlicht in: | Cellulose (London) 2022-02, Vol.29 (3), p.1463-1472 |
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| creator | Xu, Feixiang Luo, Jiangchen Jiang, Liqun Zhao, Zengli |
| description | In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis disclosed the production formation mechanism. The impregnation of acid could reduce the activation energy and lower the reaction temperature. Furthermore, the yield of LG from H
3
PO
4
- and H
2
SO
4
-impregnated cellulose increased significantly (26.4–35.8 wt%) compared with that of pure cellulose (7.5 wt%) pyrolysis at 300 °C. At 350 °C, 0.1 wt% H
3
PO
4
-impregnated cellulose gave a maximum LGO yield (18.3 wt%) via pyrolysis, which increased 36 times concerning that of cellulose without acid impregnation (0.5 wt%). This study exhibited great potential for industrial LG and LGO production from cellulose at low temperatures. |
| doi_str_mv | 10.1007/s10570-021-04387-4 |
| format | Article |
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3
PO
4
- and H
2
SO
4
-impregnated cellulose increased significantly (26.4–35.8 wt%) compared with that of pure cellulose (7.5 wt%) pyrolysis at 300 °C. At 350 °C, 0.1 wt% H
3
PO
4
-impregnated cellulose gave a maximum LGO yield (18.3 wt%) via pyrolysis, which increased 36 times concerning that of cellulose without acid impregnation (0.5 wt%). This study exhibited great potential for industrial LG and LGO production from cellulose at low temperatures.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-04387-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Acids ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Glass ; Impregnation ; Low temperature ; Natural Materials ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Pyrolysis ; Sulfuric acid ; Sustainable Development</subject><ispartof>Cellulose (London), 2022-02, Vol.29 (3), p.1463-1472</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-3b79da19f71181ed38b40c5492d5a5d7a86b2da38413fc4f56e83bccc7056253</citedby><cites>FETCH-LOGICAL-c319t-3b79da19f71181ed38b40c5492d5a5d7a86b2da38413fc4f56e83bccc7056253</cites><orcidid>0000-0002-8541-7539</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-04387-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-04387-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Xu, Feixiang</creatorcontrib><creatorcontrib>Luo, Jiangchen</creatorcontrib><creatorcontrib>Jiang, Liqun</creatorcontrib><creatorcontrib>Zhao, Zengli</creatorcontrib><title>Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis disclosed the production formation mechanism. The impregnation of acid could reduce the activation energy and lower the reaction temperature. Furthermore, the yield of LG from H
3
PO
4
- and H
2
SO
4
-impregnated cellulose increased significantly (26.4–35.8 wt%) compared with that of pure cellulose (7.5 wt%) pyrolysis at 300 °C. At 350 °C, 0.1 wt% H
3
PO
4
-impregnated cellulose gave a maximum LGO yield (18.3 wt%) via pyrolysis, which increased 36 times concerning that of cellulose without acid impregnation (0.5 wt%). This study exhibited great potential for industrial LG and LGO production from cellulose at low temperatures.</description><subject>Acids</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Glass</subject><subject>Impregnation</subject><subject>Low temperature</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Pyrolysis</subject><subject>Sulfuric acid</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdTTPSbKU4qMguOnCXcjkUaZMJzWZKfTfm1pBV64O3Pudc7kHgFuC7wnG8qEQLCRGmBKEOVMS8TMwI0JSpBT9OAczrBtd10xfgqtSNhhjLSmZgc1yu8tpHzys4ic3dmmAKcI-7NO6n1wqdoB28H8GYUhDgDGnLbSu86irCWE92LGGuND3U18ZuO8sjLaMcHfIqT-UrlyDi2j7Em5-dA5Wz0-rxSt6e39ZLh7fkGNEj4i1UntLdJSEKBI8Uy3HTnBNvbDCS6ualnrLFCcsOh5FExRrnXMSi4YKNgd3p9j60OcUymg2acpDvWhowzAnWmleKXqiXE6l5BDNLndbmw-GYHOs1JwqNbVS812pOZrYyVQqPKxD_o3-x_UFyf575w</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Xu, Feixiang</creator><creator>Luo, Jiangchen</creator><creator>Jiang, Liqun</creator><creator>Zhao, Zengli</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-8541-7539</orcidid></search><sort><creationdate>20220201</creationdate><title>Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis</title><author>Xu, Feixiang ; Luo, Jiangchen ; Jiang, Liqun ; Zhao, Zengli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-3b79da19f71181ed38b40c5492d5a5d7a86b2da38413fc4f56e83bccc7056253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acids</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Glass</topic><topic>Impregnation</topic><topic>Low temperature</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Pyrolysis</topic><topic>Sulfuric acid</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Feixiang</creatorcontrib><creatorcontrib>Luo, Jiangchen</creatorcontrib><creatorcontrib>Jiang, Liqun</creatorcontrib><creatorcontrib>Zhao, Zengli</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Feixiang</au><au>Luo, Jiangchen</au><au>Jiang, Liqun</au><au>Zhao, Zengli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2022-02-01</date><risdate>2022</risdate><volume>29</volume><issue>3</issue><spage>1463</spage><epage>1472</epage><pages>1463-1472</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>In this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis disclosed the production formation mechanism. The impregnation of acid could reduce the activation energy and lower the reaction temperature. Furthermore, the yield of LG from H
3
PO
4
- and H
2
SO
4
-impregnated cellulose increased significantly (26.4–35.8 wt%) compared with that of pure cellulose (7.5 wt%) pyrolysis at 300 °C. At 350 °C, 0.1 wt% H
3
PO
4
-impregnated cellulose gave a maximum LGO yield (18.3 wt%) via pyrolysis, which increased 36 times concerning that of cellulose without acid impregnation (0.5 wt%). This study exhibited great potential for industrial LG and LGO production from cellulose at low temperatures.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-04387-4</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-8541-7539</orcidid></addata></record> |
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| subjects | Acids Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composites Glass Impregnation Low temperature Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Pyrolysis Sulfuric acid Sustainable Development |
| title | Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis |
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