Synthesis of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite as an efficient and magnetically recoverable catalyst for oxidative desulfurization of liquid fuels
Summary Here, we report on the preparation and characterization of a new organic/inorganic hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (abbreviated as (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The hybrid nanocomposite was successfully synthesized unde...
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| Veröffentlicht in: | International journal of energy research 2022-03, Vol.46 (3), p.2617-2632 |
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| creator | Rezvani, Mohammad Ali Khandan, Sahar Rahim, Masoumeh |
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Here, we report on the preparation and characterization of a new organic/inorganic hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (abbreviated as (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The hybrid nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by powder X‐ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, energy dispersive X‐ray, and vibrating sample magnetometer techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The experimental results revealed excellent catalytic activity of the hybrid nanocomposite in the removal of hazardous organosulfur compounds from model fuel oils (MFOs) and typical real gasoline. The sulfur removal from MFOs could reach up to 95% at the operating temperature of 35°C, the ambient pressure, and the contact time of 1 hour. Quite surprisingly, the total sulfur content of real gasoline was lowered from 0.4985 to 0.0198 wt% under the same reaction conditions. In addition, the (Gly)3PMo12O40@MnFe2O4 presented a brilliant magnetically reusability with slight diminution after seven consecutive Cat‐ODS cycles. These results encourage the further exploration of the application of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite in the production of clean diesel and jet fuels.
We report on the preparation of a new hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by PXRD, FT‐IR, FESEM, EDX, and VSM techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The sulfur removal of model fuel could reach up to 95% at 35 °C, the ambient pressure, and the contact time of 1 hour. |
| doi_str_mv | 10.1002/er.7332 |
| format | Article |
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Here, we report on the preparation and characterization of a new organic/inorganic hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (abbreviated as (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The hybrid nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by powder X‐ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, energy dispersive X‐ray, and vibrating sample magnetometer techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The experimental results revealed excellent catalytic activity of the hybrid nanocomposite in the removal of hazardous organosulfur compounds from model fuel oils (MFOs) and typical real gasoline. The sulfur removal from MFOs could reach up to 95% at the operating temperature of 35°C, the ambient pressure, and the contact time of 1 hour. Quite surprisingly, the total sulfur content of real gasoline was lowered from 0.4985 to 0.0198 wt% under the same reaction conditions. In addition, the (Gly)3PMo12O40@MnFe2O4 presented a brilliant magnetically reusability with slight diminution after seven consecutive Cat‐ODS cycles. These results encourage the further exploration of the application of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite in the production of clean diesel and jet fuels.
We report on the preparation of a new hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by PXRD, FT‐IR, FESEM, EDX, and VSM techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The sulfur removal of model fuel could reach up to 95% at 35 °C, the ambient pressure, and the contact time of 1 hour.</description><identifier>ISSN: 0363-907X</identifier><identifier>EISSN: 1099-114X</identifier><identifier>DOI: 10.1002/er.7332</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Inc</publisher><subject>Analytical methods ; Catalysts ; Catalytic activity ; Contact pressure ; Desulfurization ; Desulfurizing ; Diesel fuels ; Field emission microscopy ; Field emission spectroscopy ; Fourier transforms ; Fuel oils ; Fuels ; Gasoline ; Glycine ; Glycine (amino acid) ; Infrared spectroscopy ; Irradiation ; Jet engine fuels ; Keggin‐type polyoxomolybdate ; Liquid fuels ; Magnetometers ; Manganese ; Nanocomposites ; Nanoparticles ; Operating temperature ; organic/inorganic hybrid nanocomposite ; Organosulfur compounds ; oxidative desulfurization ; Pressure ; recoverable catalyst ; Removal ; Scanning electron microscopy ; Sulfur ; Sulfur content ; Sulfur removal ; Sulphur</subject><ispartof>International journal of energy research, 2022-03, Vol.46 (3), p.2617-2632</ispartof><rights>2021 John Wiley & Sons Ltd.</rights><rights>2022 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-6155-5147</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fer.7332$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fer.7332$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Rezvani, Mohammad Ali</creatorcontrib><creatorcontrib>Khandan, Sahar</creatorcontrib><creatorcontrib>Rahim, Masoumeh</creatorcontrib><title>Synthesis of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite as an efficient and magnetically recoverable catalyst for oxidative desulfurization of liquid fuels</title><title>International journal of energy research</title><description>Summary
Here, we report on the preparation and characterization of a new organic/inorganic hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (abbreviated as (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The hybrid nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by powder X‐ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, energy dispersive X‐ray, and vibrating sample magnetometer techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The experimental results revealed excellent catalytic activity of the hybrid nanocomposite in the removal of hazardous organosulfur compounds from model fuel oils (MFOs) and typical real gasoline. The sulfur removal from MFOs could reach up to 95% at the operating temperature of 35°C, the ambient pressure, and the contact time of 1 hour. Quite surprisingly, the total sulfur content of real gasoline was lowered from 0.4985 to 0.0198 wt% under the same reaction conditions. In addition, the (Gly)3PMo12O40@MnFe2O4 presented a brilliant magnetically reusability with slight diminution after seven consecutive Cat‐ODS cycles. These results encourage the further exploration of the application of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite in the production of clean diesel and jet fuels.
We report on the preparation of a new hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by PXRD, FT‐IR, FESEM, EDX, and VSM techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The sulfur removal of model fuel could reach up to 95% at 35 °C, the ambient pressure, and the contact time of 1 hour.</description><subject>Analytical methods</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Contact pressure</subject><subject>Desulfurization</subject><subject>Desulfurizing</subject><subject>Diesel fuels</subject><subject>Field emission microscopy</subject><subject>Field emission spectroscopy</subject><subject>Fourier transforms</subject><subject>Fuel oils</subject><subject>Fuels</subject><subject>Gasoline</subject><subject>Glycine</subject><subject>Glycine (amino acid)</subject><subject>Infrared spectroscopy</subject><subject>Irradiation</subject><subject>Jet engine fuels</subject><subject>Keggin‐type polyoxomolybdate</subject><subject>Liquid fuels</subject><subject>Magnetometers</subject><subject>Manganese</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Operating temperature</subject><subject>organic/inorganic hybrid nanocomposite</subject><subject>Organosulfur compounds</subject><subject>oxidative desulfurization</subject><subject>Pressure</subject><subject>recoverable catalyst</subject><subject>Removal</subject><subject>Scanning electron microscopy</subject><subject>Sulfur</subject><subject>Sulfur content</subject><subject>Sulfur removal</subject><subject>Sulphur</subject><issn>0363-907X</issn><issn>1099-114X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNotUdtKxDAUDKLgesFfCPiiSDWXbtu8KeKqoChewLdymp5oJJusSbtaP8pvtIs-zQxnODMwhOxxdswZEycYj0spxRqZcKZUxnn-sk4mTBYyU6x82SRbKb0zNt54OSE_j4Pv3jDZRIOhB5duOJT3t4GLu5yd3voZjoSG-Are6hPr_xl9G5poW-rBBx3mi5BshxQSBU_RGKst-m4ULZ3Dq8fOanBuoBF1WGKExiHV0IEbUkdNiDR82RY6u0TaYuqd6aP9HnXwq1LOfvRjlunRpR2yYcAl3P3HbfI8u3g6v8pu7i6vz89usgWXucgKaSrDFfCpUiBFaZqGY26ELFhboJmChqYyuW5UoSRTlWItL6q21MArLo2W22T_7-8iho8eU1e_hz76MbIWhVCimrKCj66jP9endTjUi2jnEIeas3q1RI2xXi1RXzysQP4C6xSAHQ</recordid><startdate>20220310</startdate><enddate>20220310</enddate><creator>Rezvani, Mohammad Ali</creator><creator>Khandan, Sahar</creator><creator>Rahim, Masoumeh</creator><general>John Wiley & Sons, Inc</general><general>Hindawi Limited</general><scope>7SP</scope><scope>7ST</scope><scope>7TB</scope><scope>7TN</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>H96</scope><scope>KR7</scope><scope>L.G</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0001-6155-5147</orcidid></search><sort><creationdate>20220310</creationdate><title>Synthesis of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite as an efficient and magnetically recoverable catalyst for oxidative desulfurization of liquid fuels</title><author>Rezvani, Mohammad Ali ; Khandan, Sahar ; Rahim, Masoumeh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1342-63f8f19a1599a327fbb1e4f2360d6ef5acab8f4cb969309890d168d7ca1813fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analytical methods</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Contact pressure</topic><topic>Desulfurization</topic><topic>Desulfurizing</topic><topic>Diesel fuels</topic><topic>Field emission microscopy</topic><topic>Field emission spectroscopy</topic><topic>Fourier transforms</topic><topic>Fuel oils</topic><topic>Fuels</topic><topic>Gasoline</topic><topic>Glycine</topic><topic>Glycine (amino acid)</topic><topic>Infrared spectroscopy</topic><topic>Irradiation</topic><topic>Jet engine fuels</topic><topic>Keggin‐type polyoxomolybdate</topic><topic>Liquid fuels</topic><topic>Magnetometers</topic><topic>Manganese</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Operating temperature</topic><topic>organic/inorganic hybrid nanocomposite</topic><topic>Organosulfur compounds</topic><topic>oxidative desulfurization</topic><topic>Pressure</topic><topic>recoverable catalyst</topic><topic>Removal</topic><topic>Scanning electron microscopy</topic><topic>Sulfur</topic><topic>Sulfur content</topic><topic>Sulfur removal</topic><topic>Sulphur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rezvani, Mohammad Ali</creatorcontrib><creatorcontrib>Khandan, Sahar</creatorcontrib><creatorcontrib>Rahim, Masoumeh</creatorcontrib><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Oceanic Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>International journal of energy research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rezvani, Mohammad Ali</au><au>Khandan, Sahar</au><au>Rahim, Masoumeh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite as an efficient and magnetically recoverable catalyst for oxidative desulfurization of liquid fuels</atitle><jtitle>International journal of energy research</jtitle><date>2022-03-10</date><risdate>2022</risdate><volume>46</volume><issue>3</issue><spage>2617</spage><epage>2632</epage><pages>2617-2632</pages><issn>0363-907X</issn><eissn>1099-114X</eissn><abstract>Summary
Here, we report on the preparation and characterization of a new organic/inorganic hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (abbreviated as (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The hybrid nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by powder X‐ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, energy dispersive X‐ray, and vibrating sample magnetometer techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The experimental results revealed excellent catalytic activity of the hybrid nanocomposite in the removal of hazardous organosulfur compounds from model fuel oils (MFOs) and typical real gasoline. The sulfur removal from MFOs could reach up to 95% at the operating temperature of 35°C, the ambient pressure, and the contact time of 1 hour. Quite surprisingly, the total sulfur content of real gasoline was lowered from 0.4985 to 0.0198 wt% under the same reaction conditions. In addition, the (Gly)3PMo12O40@MnFe2O4 presented a brilliant magnetically reusability with slight diminution after seven consecutive Cat‐ODS cycles. These results encourage the further exploration of the application of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite in the production of clean diesel and jet fuels.
We report on the preparation of a new hybrid nanocomposite comprised of the glycine‐modified polyoxomolybdate (Gly)3PMo12O40) and manganese ferrite (MnFe2O4) nanoparticles. The nanocomposite was successfully synthesized under mild ultrasound irradiation and characterized by PXRD, FT‐IR, FESEM, EDX, and VSM techniques. To explore the (Gly)3PMo12O40@MnFe2O4 applicability, it was used in catalytic oxidative desulfurization (Cat‐ODS) reactions. The sulfur removal of model fuel could reach up to 95% at 35 °C, the ambient pressure, and the contact time of 1 hour.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/er.7332</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0001-6155-5147</orcidid></addata></record> |
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| subjects | Analytical methods Catalysts Catalytic activity Contact pressure Desulfurization Desulfurizing Diesel fuels Field emission microscopy Field emission spectroscopy Fourier transforms Fuel oils Fuels Gasoline Glycine Glycine (amino acid) Infrared spectroscopy Irradiation Jet engine fuels Keggin‐type polyoxomolybdate Liquid fuels Magnetometers Manganese Nanocomposites Nanoparticles Operating temperature organic/inorganic hybrid nanocomposite Organosulfur compounds oxidative desulfurization Pressure recoverable catalyst Removal Scanning electron microscopy Sulfur Sulfur content Sulfur removal Sulphur |
| title | Synthesis of (Gly)3PMo12O40@MnFe2O4 organic/inorganic hybrid nanocomposite as an efficient and magnetically recoverable catalyst for oxidative desulfurization of liquid fuels |
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