RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid
Developing highly efficient oxygen evolution reaction (OER) catalyst for the acidic corrosive operating conditions is a challenging task. Herein, we report the synthesis of uniform RuO 2 clusters with ∼ 2 nm in size via electrochemical leaching of Sr from SrRuO 3 ceramic in acid. The RuO 2 clusters...
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| Veröffentlicht in: | Nano research 2022-03, Vol.15 (3), p.1959-1965 |
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| container_end_page | 1965 |
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| container_issue | 3 |
| container_start_page | 1959 |
| container_title | Nano research |
| container_volume | 15 |
| creator | Ji, Muwei Yang, Xin Chang, Shengding Chen, Wenxing Wang, Jin He, Dongsheng Hu, Yao Deng, Qian Sun, You Li, Bo Xi, Jingyu Yamada, Tomoaki Zhang, Jiatao Xiao, Hai Zhu, Caizhen Li, Jia Li, Yadong |
| description | Developing highly efficient oxygen evolution reaction (OER) catalyst for the acidic corrosive operating conditions is a challenging task. Herein, we report the synthesis of uniform RuO
2
clusters with ∼ 2 nm in size via electrochemical leaching of Sr from SrRuO
3
ceramic in acid. The RuO
2
clusters exhibit ultrahigh OER activity with overpotential of ∼ 160 mV at 10 mA·cm
geo
−2
in 1.0 M HClO
4
solution for 30-h testing. The extended X-ray absorption fine structure measurement reveals enlarged Jahn-Teller distortion of RuO octahedra in the RuO
2
clusters compared to its bulk counterpart. Density function theory calculations show that the enhanced Jahn-Teller distortion can improve the intrinsic OER activity of RuO
2
. |
| doi_str_mv | 10.1007/s12274-021-3843-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2628406029</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2628406029</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-3a1c5694a5de90b234330acb091853a8f668a1aaf09d47a816388a71cafaabde3</originalsourceid><addsrcrecordid>eNp1kE1LxDAQhoMouK7-AG8Bz9V8NU28yeIXLCysepQwTdOla7dZk1bcf2_WKp6cy7yH552BB6FzSi4pIcVVpIwVIiOMZlwJnqkDNKFaq4ykOfzNlIljdBLjmhDJqFAT9LocFgzbdoi9CxFXLjQfrsJ18BtcDu0bfgqJ4Nd46cvEYAs9tLsUah-w_9ytXIfdh2-HvvEdDg7sd2g6DLapTtFRDW10Zz97il7ubp9nD9l8cf84u5lnlue6zzhQm0stIK-cJiXjgnMCtiSaqpyDqqVUQAFqoitRgKKSKwUFtVADlJXjU3Qx3t0G_z642Ju1H0KXXhommRJEEqYTRUfKBh9jcLXZhmYDYWcoMXuLZrRokkWzt2hU6rCxExPbrVz4u_x_6Qtfo3UH</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2628406029</pqid></control><display><type>article</type><title>RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid</title><source>SpringerLink Journals - AutoHoldings</source><creator>Ji, Muwei ; Yang, Xin ; Chang, Shengding ; Chen, Wenxing ; Wang, Jin ; He, Dongsheng ; Hu, Yao ; Deng, Qian ; Sun, You ; Li, Bo ; Xi, Jingyu ; Yamada, Tomoaki ; Zhang, Jiatao ; Xiao, Hai ; Zhu, Caizhen ; Li, Jia ; Li, Yadong</creator><creatorcontrib>Ji, Muwei ; Yang, Xin ; Chang, Shengding ; Chen, Wenxing ; Wang, Jin ; He, Dongsheng ; Hu, Yao ; Deng, Qian ; Sun, You ; Li, Bo ; Xi, Jingyu ; Yamada, Tomoaki ; Zhang, Jiatao ; Xiao, Hai ; Zhu, Caizhen ; Li, Jia ; Li, Yadong</creatorcontrib><description>Developing highly efficient oxygen evolution reaction (OER) catalyst for the acidic corrosive operating conditions is a challenging task. Herein, we report the synthesis of uniform RuO
2
clusters with ∼ 2 nm in size via electrochemical leaching of Sr from SrRuO
3
ceramic in acid. The RuO
2
clusters exhibit ultrahigh OER activity with overpotential of ∼ 160 mV at 10 mA·cm
geo
−2
in 1.0 M HClO
4
solution for 30-h testing. The extended X-ray absorption fine structure measurement reveals enlarged Jahn-Teller distortion of RuO octahedra in the RuO
2
clusters compared to its bulk counterpart. Density function theory calculations show that the enhanced Jahn-Teller distortion can improve the intrinsic OER activity of RuO
2
.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-021-3843-8</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Acids ; Alcohol ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Bulk density ; Carbon black ; Catalysts ; Chemistry and Materials Science ; Clusters ; Condensed Matter Physics ; Density functional theory ; Distortion ; Electrochemistry ; Electrodes ; Electrolytes ; Engineering ; Fine structure ; Jahn-Teller effect ; Leaching ; Materials Science ; Nanotechnology ; Oxygen ; Oxygen evolution reactions ; Radiation ; Research Article ; Ruthenium oxide ; Thin films ; Ultrastructure ; X ray absorption</subject><ispartof>Nano research, 2022-03, Vol.15 (3), p.1959-1965</ispartof><rights>Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-3a1c5694a5de90b234330acb091853a8f668a1aaf09d47a816388a71cafaabde3</citedby><cites>FETCH-LOGICAL-c359t-3a1c5694a5de90b234330acb091853a8f668a1aaf09d47a816388a71cafaabde3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-021-3843-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-021-3843-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Ji, Muwei</creatorcontrib><creatorcontrib>Yang, Xin</creatorcontrib><creatorcontrib>Chang, Shengding</creatorcontrib><creatorcontrib>Chen, Wenxing</creatorcontrib><creatorcontrib>Wang, Jin</creatorcontrib><creatorcontrib>He, Dongsheng</creatorcontrib><creatorcontrib>Hu, Yao</creatorcontrib><creatorcontrib>Deng, Qian</creatorcontrib><creatorcontrib>Sun, You</creatorcontrib><creatorcontrib>Li, Bo</creatorcontrib><creatorcontrib>Xi, Jingyu</creatorcontrib><creatorcontrib>Yamada, Tomoaki</creatorcontrib><creatorcontrib>Zhang, Jiatao</creatorcontrib><creatorcontrib>Xiao, Hai</creatorcontrib><creatorcontrib>Zhu, Caizhen</creatorcontrib><creatorcontrib>Li, Jia</creatorcontrib><creatorcontrib>Li, Yadong</creatorcontrib><title>RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>Developing highly efficient oxygen evolution reaction (OER) catalyst for the acidic corrosive operating conditions is a challenging task. Herein, we report the synthesis of uniform RuO
2
clusters with ∼ 2 nm in size via electrochemical leaching of Sr from SrRuO
3
ceramic in acid. The RuO
2
clusters exhibit ultrahigh OER activity with overpotential of ∼ 160 mV at 10 mA·cm
geo
−2
in 1.0 M HClO
4
solution for 30-h testing. The extended X-ray absorption fine structure measurement reveals enlarged Jahn-Teller distortion of RuO octahedra in the RuO
2
clusters compared to its bulk counterpart. Density function theory calculations show that the enhanced Jahn-Teller distortion can improve the intrinsic OER activity of RuO
2
.</description><subject>Acids</subject><subject>Alcohol</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Bulk density</subject><subject>Carbon black</subject><subject>Catalysts</subject><subject>Chemistry and Materials Science</subject><subject>Clusters</subject><subject>Condensed Matter Physics</subject><subject>Density functional theory</subject><subject>Distortion</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Engineering</subject><subject>Fine structure</subject><subject>Jahn-Teller effect</subject><subject>Leaching</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Oxygen</subject><subject>Oxygen evolution reactions</subject><subject>Radiation</subject><subject>Research Article</subject><subject>Ruthenium oxide</subject><subject>Thin films</subject><subject>Ultrastructure</subject><subject>X ray absorption</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE1LxDAQhoMouK7-AG8Bz9V8NU28yeIXLCysepQwTdOla7dZk1bcf2_WKp6cy7yH552BB6FzSi4pIcVVpIwVIiOMZlwJnqkDNKFaq4ykOfzNlIljdBLjmhDJqFAT9LocFgzbdoi9CxFXLjQfrsJ18BtcDu0bfgqJ4Nd46cvEYAs9tLsUah-w_9ytXIfdh2-HvvEdDg7sd2g6DLapTtFRDW10Zz97il7ubp9nD9l8cf84u5lnlue6zzhQm0stIK-cJiXjgnMCtiSaqpyDqqVUQAFqoitRgKKSKwUFtVADlJXjU3Qx3t0G_z642Ju1H0KXXhommRJEEqYTRUfKBh9jcLXZhmYDYWcoMXuLZrRokkWzt2hU6rCxExPbrVz4u_x_6Qtfo3UH</recordid><startdate>20220301</startdate><enddate>20220301</enddate><creator>Ji, Muwei</creator><creator>Yang, Xin</creator><creator>Chang, Shengding</creator><creator>Chen, Wenxing</creator><creator>Wang, 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B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>7X7</scope><scope>7XB</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H8G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K9.</scope><scope>KB.</scope><scope>L7M</scope><scope>LK8</scope><scope>M0S</scope><scope>M7P</scope><scope>P64</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20220301</creationdate><title>RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid</title><author>Ji, Muwei ; Yang, Xin ; Chang, Shengding ; Chen, Wenxing ; Wang, Jin ; He, Dongsheng ; Hu, Yao ; Deng, Qian ; Sun, You ; Li, Bo ; Xi, Jingyu ; Yamada, Tomoaki ; Zhang, Jiatao ; Xiao, Hai ; Zhu, Caizhen ; Li, Jia ; Li, Yadong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-3a1c5694a5de90b234330acb091853a8f668a1aaf09d47a816388a71cafaabde3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acids</topic><topic>Alcohol</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Bulk density</topic><topic>Carbon black</topic><topic>Catalysts</topic><topic>Chemistry and Materials Science</topic><topic>Clusters</topic><topic>Condensed Matter Physics</topic><topic>Density functional theory</topic><topic>Distortion</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Engineering</topic><topic>Fine structure</topic><topic>Jahn-Teller effect</topic><topic>Leaching</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Oxygen</topic><topic>Oxygen evolution reactions</topic><topic>Radiation</topic><topic>Research Article</topic><topic>Ruthenium oxide</topic><topic>Thin films</topic><topic>Ultrastructure</topic><topic>X ray absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ji, Muwei</creatorcontrib><creatorcontrib>Yang, Xin</creatorcontrib><creatorcontrib>Chang, Shengding</creatorcontrib><creatorcontrib>Chen, Wenxing</creatorcontrib><creatorcontrib>Wang, Jin</creatorcontrib><creatorcontrib>He, Dongsheng</creatorcontrib><creatorcontrib>Hu, Yao</creatorcontrib><creatorcontrib>Deng, Qian</creatorcontrib><creatorcontrib>Sun, 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Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ji, Muwei</au><au>Yang, Xin</au><au>Chang, Shengding</au><au>Chen, Wenxing</au><au>Wang, Jin</au><au>He, Dongsheng</au><au>Hu, Yao</au><au>Deng, Qian</au><au>Sun, You</au><au>Li, Bo</au><au>Xi, Jingyu</au><au>Yamada, Tomoaki</au><au>Zhang, Jiatao</au><au>Xiao, Hai</au><au>Zhu, Caizhen</au><au>Li, Jia</au><au>Li, Yadong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><date>2022-03-01</date><risdate>2022</risdate><volume>15</volume><issue>3</issue><spage>1959</spage><epage>1965</epage><pages>1959-1965</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>Developing highly efficient oxygen evolution reaction (OER) catalyst for the acidic corrosive operating conditions is a challenging task. Herein, we report the synthesis of uniform RuO
2
clusters with ∼ 2 nm in size via electrochemical leaching of Sr from SrRuO
3
ceramic in acid. The RuO
2
clusters exhibit ultrahigh OER activity with overpotential of ∼ 160 mV at 10 mA·cm
geo
−2
in 1.0 M HClO
4
solution for 30-h testing. The extended X-ray absorption fine structure measurement reveals enlarged Jahn-Teller distortion of RuO octahedra in the RuO
2
clusters compared to its bulk counterpart. Density function theory calculations show that the enhanced Jahn-Teller distortion can improve the intrinsic OER activity of RuO
2
.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-021-3843-8</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2022-03, Vol.15 (3), p.1959-1965 |
| issn | 1998-0124 1998-0000 |
| language | eng |
| recordid | cdi_proquest_journals_2628406029 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acids Alcohol Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Bulk density Carbon black Catalysts Chemistry and Materials Science Clusters Condensed Matter Physics Density functional theory Distortion Electrochemistry Electrodes Electrolytes Engineering Fine structure Jahn-Teller effect Leaching Materials Science Nanotechnology Oxygen Oxygen evolution reactions Radiation Research Article Ruthenium oxide Thin films Ultrastructure X ray absorption |
| title | RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid |
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