High dielectric constant poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) for capacitive pressure and bending sensors

Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene), P(VDF-TrFE-CFE), samples were prepared by solvent casting by varying polymer concentration and solvent evaporation temperature. Different sample morphologies were obtained depending on the processing conditions, as well as different p...

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Veröffentlicht in:Polymer (Guilford) 2021-02, Vol.214, p.123349, Article 123349
Hauptverfasser: Pereira, N., Gonçalves, S., Barbosa, J.C., Gonçalves, R., Tubio, C.R., Vilas-Vilela, J.L., Costa, C.M., Lanceros-Mendez, S.
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container_issue
container_start_page 123349
container_title Polymer (Guilford)
container_volume 214
creator Pereira, N.
Gonçalves, S.
Barbosa, J.C.
Gonçalves, R.
Tubio, C.R.
Vilas-Vilela, J.L.
Costa, C.M.
Lanceros-Mendez, S.
description Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene), P(VDF-TrFE-CFE), samples were prepared by solvent casting by varying polymer concentration and solvent evaporation temperature. Different sample morphologies were obtained depending on the processing conditions, as well as different physical-chemical properties such as degree of crystallinity, mechanical and dielectric properties. On the other hand, the electroactive β-phase content and the degradation temperature of the P(VDF-TrFE-CFE) samples are independent of the processing conditions. At 1 kHz, the highest dielectric constant, ε’ = 40, was obtained for the samples prepared with 15 wt% polymer concentration in solutions and processing conditions based on solvent evaporation and polymer melting at 210 °C. Taking into account the high dielectric response, pressure and bending capacitive sensors were developed with excellent response and high sensibility (0.03 kPa−1). The developed materials were evaluated for bending and force detection applications. Thus, it is concluded that the developed P(VDF-TrFE-CFE) films are suitable for a new generation of multifunctional materials for capacitive sensing applications, including both force and deformation sensors and touchpads. [Display omitted] •Poly (vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) has been processed by solvent casting.•Varying processing conditions include polymer concentration in solution and processing temperature.•A high dielectric constant of 40 at 1 kHz has been obtained.•The material shows high performance for capacitive pressure and bending sensor applications.
doi_str_mv 10.1016/j.polymer.2020.123349
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Different sample morphologies were obtained depending on the processing conditions, as well as different physical-chemical properties such as degree of crystallinity, mechanical and dielectric properties. On the other hand, the electroactive β-phase content and the degradation temperature of the P(VDF-TrFE-CFE) samples are independent of the processing conditions. At 1 kHz, the highest dielectric constant, ε’ = 40, was obtained for the samples prepared with 15 wt% polymer concentration in solutions and processing conditions based on solvent evaporation and polymer melting at 210 °C. Taking into account the high dielectric response, pressure and bending capacitive sensors were developed with excellent response and high sensibility (0.03 kPa−1). The developed materials were evaluated for bending and force detection applications. Thus, it is concluded that the developed P(VDF-TrFE-CFE) films are suitable for a new generation of multifunctional materials for capacitive sensing applications, including both force and deformation sensors and touchpads. [Display omitted] •Poly (vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) has been processed by solvent casting.•Varying processing conditions include polymer concentration in solution and processing temperature.•A high dielectric constant of 40 at 1 kHz has been obtained.•The material shows high performance for capacitive pressure and bending sensor applications.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2020.123349</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Bending sensors ; Beta phase ; Capacitive sensors ; Chemical properties ; Degree of crystallinity ; Dielectric constant ; Dielectric properties ; Electrical properties ; Evaporation ; Fluorides ; Fluorinated polymers ; Morphology ; Multifunctional materials ; Permittivity ; Polymers ; Sensors ; Solvent casting ; Solvents ; Temperature ; Touch control panels ; Vinylidene ; Vinylidene fluoride</subject><ispartof>Polymer (Guilford), 2021-02, Vol.214, p.123349, Article 123349</ispartof><rights>2020 Elsevier Ltd</rights><rights>Copyright Elsevier BV Feb 1, 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c362t-40e9ec5b7c103e519cf586fa462532f795ececc6fd441621ff3000111b2e54353</citedby><cites>FETCH-LOGICAL-c362t-40e9ec5b7c103e519cf586fa462532f795ececc6fd441621ff3000111b2e54353</cites><orcidid>0000-0002-6988-8242</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymer.2020.123349$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids></links><search><creatorcontrib>Pereira, N.</creatorcontrib><creatorcontrib>Gonçalves, S.</creatorcontrib><creatorcontrib>Barbosa, J.C.</creatorcontrib><creatorcontrib>Gonçalves, R.</creatorcontrib><creatorcontrib>Tubio, C.R.</creatorcontrib><creatorcontrib>Vilas-Vilela, J.L.</creatorcontrib><creatorcontrib>Costa, C.M.</creatorcontrib><creatorcontrib>Lanceros-Mendez, S.</creatorcontrib><title>High dielectric constant poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) for capacitive pressure and bending sensors</title><title>Polymer (Guilford)</title><description>Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene), P(VDF-TrFE-CFE), samples were prepared by solvent casting by varying polymer concentration and solvent evaporation temperature. 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Different sample morphologies were obtained depending on the processing conditions, as well as different physical-chemical properties such as degree of crystallinity, mechanical and dielectric properties. On the other hand, the electroactive β-phase content and the degradation temperature of the P(VDF-TrFE-CFE) samples are independent of the processing conditions. At 1 kHz, the highest dielectric constant, ε’ = 40, was obtained for the samples prepared with 15 wt% polymer concentration in solutions and processing conditions based on solvent evaporation and polymer melting at 210 °C. Taking into account the high dielectric response, pressure and bending capacitive sensors were developed with excellent response and high sensibility (0.03 kPa−1). The developed materials were evaluated for bending and force detection applications. Thus, it is concluded that the developed P(VDF-TrFE-CFE) films are suitable for a new generation of multifunctional materials for capacitive sensing applications, including both force and deformation sensors and touchpads. [Display omitted] •Poly (vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) has been processed by solvent casting.•Varying processing conditions include polymer concentration in solution and processing temperature.•A high dielectric constant of 40 at 1 kHz has been obtained.•The material shows high performance for capacitive pressure and bending sensor applications.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2020.123349</doi><orcidid>https://orcid.org/0000-0002-6988-8242</orcidid><oa>free_for_read</oa></addata></record>
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source Elsevier ScienceDirect Journals
subjects Bending sensors
Beta phase
Capacitive sensors
Chemical properties
Degree of crystallinity
Dielectric constant
Dielectric properties
Electrical properties
Evaporation
Fluorides
Fluorinated polymers
Morphology
Multifunctional materials
Permittivity
Polymers
Sensors
Solvent casting
Solvents
Temperature
Touch control panels
Vinylidene
Vinylidene fluoride
title High dielectric constant poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) for capacitive pressure and bending sensors
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