The influence of a non-isocyanate urethane monomer in the film formation and mechanical properties of homogeneous and core-shell latexes

A urethane methacrylate monomer, 2-((methylcarbamoyl)oxy)ethyl methacrylate, (MEM), was synthesized via a non-isocyanate pathway and incorporated into latexes using a semi-continuous emulsion polymerization. Homogeneous and core-shell latexes were prepared using MEM, methyl methacrylate (MMA) and bu...

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Veröffentlicht in:	Polymer (Guilford) 2021-02, Vol.214, p.123253, Article 123253
Hauptverfasser:	Cobaj, Anisa, Mehr, Hamideh S., Hu, Yongan, Soucek, Mark D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylate Acrylics Calorimetry Core-shell structure Differential scanning calorimetry Emulsion polymerization Ethyl carbamate Isocyanates Latexes Mechanical properties Modulus of elasticity Monomers Morphology Non-isocyanate Particle size distribution Polymethyl methacrylate Size distribution Storage modulus Tensile strength Thermal analysis Thermal properties Thermodynamic properties Transmission electron microscopy Urethane Viscoelasticity
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