Novel Application of Tagua Shell (Phytelephas aequatorialis) as Adsorbent Material for the Removal of Pb(II) Ions: Kinetics, Equilibrium, and Thermodynamics of the Process

Tagua shell is a material generated in the handcrafted jewelry industry, which is discarded since it does not have a specific use. The present study evaluates this material as an adsorbent for the removal of lead (II) in aqueous media. The adsorbent was characterized through the point of zero charge...

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Veröffentlicht in:Sustainability 2022-02, Vol.14 (3), p.1309
Hauptverfasser: Chávez-Prado, Gino Alexander, Benavides-García, Adams Brayan, Zambrano-Intriago, Luis Angel, Maddela, Naga Raju, Quiroz-Fernández, Luis Santiago, Baquerizo-Crespo, Ricardo José, Rodríguez-Díaz, Joan Manuel
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container_issue 3
container_start_page 1309
container_title Sustainability
container_volume 14
creator Chávez-Prado, Gino Alexander
Benavides-García, Adams Brayan
Zambrano-Intriago, Luis Angel
Maddela, Naga Raju
Quiroz-Fernández, Luis Santiago
Baquerizo-Crespo, Ricardo José
Rodríguez-Díaz, Joan Manuel
description Tagua shell is a material generated in the handcrafted jewelry industry, which is discarded since it does not have a specific use. The present study evaluates this material as an adsorbent for the removal of lead (II) in aqueous media. The adsorbent was characterized through the point of zero charge technique, X-ray microanalysis, scanning electron microscopy, and Fourier-transform infrared spectroscopy. Tests were carried out in a static system using a lead (II) solution of 100 mg·L−1 to establish the process conditions, setting a pH of 5, an adsorbent dose of 1.8 g/100 mL, and a contact time of 60 min. The kinetic study performed showed that the experimental data had a better fit with the pseudo-second order model. The experimental equilibrium data were correlated using the Langmuir, Freundlich, Toth, Redlich–Peterson, and Sips models, of which the Langmuir and Sips models proved to be the best to represent the adsorption process due to the high coefficient of determination they presented at the different temperatures, being between 0.9629–0.9899 and 0.9819–0.9900, respectively. The maximum amount of lead adsorbed was 22.0348 mg·g−1 at a temperature of 298 K. Finally, the thermodynamics study indicated that the process is endothermic, spontaneous, and thermodynamically stable.
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subjects Adsorbents
Adsorption
Aqueous solutions
Endothermic reactions
Environmental impact
Equilibrium
Experiments
Infrared spectroscopy
Jewelry
Kinetics
Lead content
Metals
Scanning electron microscopy
Sustainability
Thermodynamics
title Novel Application of Tagua Shell (Phytelephas aequatorialis) as Adsorbent Material for the Removal of Pb(II) Ions: Kinetics, Equilibrium, and Thermodynamics of the Process
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