Novel hydroxyl‐containing and thermo‐dehydrocyclizable polycondensation polymers for multifunctional materials: Synthesis, properties, application
Novel poly(amide‐imide)s and poly(amide‐o‐hydroxy‐imide)s were synthesized in the process of low‐temperature polycondensation of diacid chloride of 2‐(4‐carboxyphenyl)‐1,3‐dioxoisoindoline‐5‐carboxylic acid with a single diamine of 5,5′‐methylenebis(2‐aminophenol (DADHyDPhM) or of 4,4′‐methylenebis(...
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| Veröffentlicht in: | Journal of applied polymer science 2022-04, Vol.139 (16), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Lebedeva, Galina Kononova, Svetlana Kruchinina, Elena Vlasova, Elena Gofman, Iosif Bol'shakov, Maxim Romashkova, Kira |
| description | Novel poly(amide‐imide)s and poly(amide‐o‐hydroxy‐imide)s were synthesized in the process of low‐temperature polycondensation of diacid chloride of 2‐(4‐carboxyphenyl)‐1,3‐dioxoisoindoline‐5‐carboxylic acid with a single diamine of 5,5′‐methylenebis(2‐aminophenol (DADHyDPhM) or of 4,4′‐methylenebis(benzeneamine) (DADPhМ), and also with a mixture of named diamines (molar ratios of DADHyDPhM to DADPhМ being equal to 7:3, 1:1, and 3:7). The influence of hydroxy‐imide modifying units (fragments) introduced into the basic poly(amide‐imide) on its thermal stability (the processes of polymers destruction proceed intensively in the temperature range from 400 to 600°C and has a complex character); parameters of pervaporation through heat‐resistant films prepared from polymer solutions were analyzed. Polymer films are rigid materials (modulus of elasticity–3 to 4 GPa) with a strength above 100 MPa. Heating up to 300°C leads for all three compositions to a noticeable increase in the elastic modulus and to a pronounced tendency to increase the strength characteristics. |
| doi_str_mv | 10.1002/app.51978 |
| format | Article |
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The influence of hydroxy‐imide modifying units (fragments) introduced into the basic poly(amide‐imide) on its thermal stability (the processes of polymers destruction proceed intensively in the temperature range from 400 to 600°C and has a complex character); parameters of pervaporation through heat‐resistant films prepared from polymer solutions were analyzed. Polymer films are rigid materials (modulus of elasticity–3 to 4 GPa) with a strength above 100 MPa. Heating up to 300°C leads for all three compositions to a noticeable increase in the elastic modulus and to a pronounced tendency to increase the strength characteristics.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.51978</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Aminophenol ; Carboxylic acids ; Chemical synthesis ; copolymers ; Diamines ; hydrophilic polymers ; Materials science ; Modulus of elasticity ; Multifunctional materials ; Pervaporation ; polycondensation ; Polymer films ; Polymers ; spectroscopy ; Thermal stability ; thermogravimetric analysis</subject><ispartof>Journal of applied polymer science, 2022-04, Vol.139 (16), p.n/a</ispartof><rights>2021 Wiley Periodicals LLC.</rights><rights>2022 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2978-61cedc9516986627d3d6b4cd67fe1ff13f7c59eacd60f77364490398ee3c10b53</citedby><cites>FETCH-LOGICAL-c2978-61cedc9516986627d3d6b4cd67fe1ff13f7c59eacd60f77364490398ee3c10b53</cites><orcidid>0000-0002-4596-5530 ; 0000-0001-5468-3909 ; 0000-0002-6921-9516 ; 0000-0002-4644-0445 ; 0000-0002-3628-0863 ; 0000-0002-1939-2660</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.51978$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.51978$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Lebedeva, Galina</creatorcontrib><creatorcontrib>Kononova, Svetlana</creatorcontrib><creatorcontrib>Kruchinina, Elena</creatorcontrib><creatorcontrib>Vlasova, Elena</creatorcontrib><creatorcontrib>Gofman, Iosif</creatorcontrib><creatorcontrib>Bol'shakov, Maxim</creatorcontrib><creatorcontrib>Romashkova, Kira</creatorcontrib><title>Novel hydroxyl‐containing and thermo‐dehydrocyclizable polycondensation polymers for multifunctional materials: Synthesis, properties, application</title><title>Journal of applied polymer science</title><description>Novel poly(amide‐imide)s and poly(amide‐o‐hydroxy‐imide)s were synthesized in the process of low‐temperature polycondensation of diacid chloride of 2‐(4‐carboxyphenyl)‐1,3‐dioxoisoindoline‐5‐carboxylic acid with a single diamine of 5,5′‐methylenebis(2‐aminophenol (DADHyDPhM) or of 4,4′‐methylenebis(benzeneamine) (DADPhМ), and also with a mixture of named diamines (molar ratios of DADHyDPhM to DADPhМ being equal to 7:3, 1:1, and 3:7). The influence of hydroxy‐imide modifying units (fragments) introduced into the basic poly(amide‐imide) on its thermal stability (the processes of polymers destruction proceed intensively in the temperature range from 400 to 600°C and has a complex character); parameters of pervaporation through heat‐resistant films prepared from polymer solutions were analyzed. Polymer films are rigid materials (modulus of elasticity–3 to 4 GPa) with a strength above 100 MPa. Heating up to 300°C leads for all three compositions to a noticeable increase in the elastic modulus and to a pronounced tendency to increase the strength characteristics.</description><subject>Aminophenol</subject><subject>Carboxylic acids</subject><subject>Chemical synthesis</subject><subject>copolymers</subject><subject>Diamines</subject><subject>hydrophilic polymers</subject><subject>Materials science</subject><subject>Modulus of elasticity</subject><subject>Multifunctional materials</subject><subject>Pervaporation</subject><subject>polycondensation</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>spectroscopy</subject><subject>Thermal stability</subject><subject>thermogravimetric analysis</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqWw4AaWWCGR1s6PE7OrKv6kCpCAdeQ6Y-rKiYOdAmHFEVhxQE6C27JFs_DozTdPz4PQMSUjSkg8Fm07yijPix00oITnUcriYhcNwoxGBefZPjrwfkkIpRlhA_R9a1_B4EVfOfvem5_PL2mbTuhGN89YNBXuFuBqG_QKNpDspdEfYm4At9b0ga6g8aLTttkINTiPlXW4XplOq1Uj1yNhcC06cFoYf44f-ibYeu3PcOtsC67TEPqQ3Wi5sTpEeyqgcPT3DtHT5cXj9Dqa3V3dTCezSMbhjxGjEirJM8p4wVicV0nF5qmsWK6AKkUTlcuMgwgKUXmesDTlJOEFQCIpmWfJEJ1sfUOOlxX4rlzalQtxfRmzUBlPw9oQnW4p6az3DlTZOl0L15eUlOuzlyF6uTl7YMdb9k0b6P8Hy8n9_XbjF8Nmi60</recordid><startdate>20220420</startdate><enddate>20220420</enddate><creator>Lebedeva, Galina</creator><creator>Kononova, Svetlana</creator><creator>Kruchinina, Elena</creator><creator>Vlasova, Elena</creator><creator>Gofman, Iosif</creator><creator>Bol'shakov, Maxim</creator><creator>Romashkova, Kira</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-4596-5530</orcidid><orcidid>https://orcid.org/0000-0001-5468-3909</orcidid><orcidid>https://orcid.org/0000-0002-6921-9516</orcidid><orcidid>https://orcid.org/0000-0002-4644-0445</orcidid><orcidid>https://orcid.org/0000-0002-3628-0863</orcidid><orcidid>https://orcid.org/0000-0002-1939-2660</orcidid></search><sort><creationdate>20220420</creationdate><title>Novel hydroxyl‐containing and thermo‐dehydrocyclizable polycondensation polymers for multifunctional materials: Synthesis, properties, application</title><author>Lebedeva, Galina ; 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The influence of hydroxy‐imide modifying units (fragments) introduced into the basic poly(amide‐imide) on its thermal stability (the processes of polymers destruction proceed intensively in the temperature range from 400 to 600°C and has a complex character); parameters of pervaporation through heat‐resistant films prepared from polymer solutions were analyzed. Polymer films are rigid materials (modulus of elasticity–3 to 4 GPa) with a strength above 100 MPa. 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| subjects | Aminophenol Carboxylic acids Chemical synthesis copolymers Diamines hydrophilic polymers Materials science Modulus of elasticity Multifunctional materials Pervaporation polycondensation Polymer films Polymers spectroscopy Thermal stability thermogravimetric analysis |
| title | Novel hydroxyl‐containing and thermo‐dehydrocyclizable polycondensation polymers for multifunctional materials: Synthesis, properties, application |
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