Photo-sensitive hybrids constructed from diphenyliodonium and metal-thiocyanates: photo-induced structure and property transformations

Strong electron-poor cation diphenyliodonium was firstly incorporated with transition metal thiocyanates to obtain three new photo-sensitive hybrids, (DPI) 3 [Mn(SCN) 5 (H 2 O)]·0.25H 2 O ( α- 1 ), {(DPI) 2 [Ni(SCN) 4 ]} n ( α- 2 ) and {(DPI) 6 [Cd 3 (SCN) 12 ]} n ( α- 3 ) (DPI + = diphenyliodonium)...

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Veröffentlicht in:	CrystEngComm 2022-02, Vol.24 (6), p.1237-1247
Hauptverfasser:	Song, Kai-Yue, Yang, Zhen-Cong, Zhou, Pan-Ke, Zong, Lu-Lu, Li, Hao-Hong, Jiang, Rong, Chen, Zhi-Rong
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding strength Fluorescence Functional materials Hydrogen bonds Octahedrons Thiocyanates Transformations Transition metals
Online-Zugang:	Volltext
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