Mechanical, Thermal and Antimicrobial Properties of LLDPE/EVA/MMT/Ag Nanocomposites Films Synthesized by Gamma Irradiation
The impact of bacterial diseases and the development of effective antimicrobial agents have drawn much consideration as a main healthcare challenge. The effects of montmorillonite/silver nanocomposites (MMT/Ag NCs) as a nanofiller on mechanical and thermal properties of linear low-density polyethyle...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2022-02, Vol.32 (2), p.631-645 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Bekhit, Mohamad El-Sabbagh, Salwa H. Mohamed, Rasha M. El-Sayyad, Gharieb S. Sokary, Rehab |
| description | The impact of bacterial diseases and the development of effective antimicrobial agents have drawn much consideration as a main healthcare challenge. The effects of montmorillonite/silver nanocomposites (MMT/Ag NCs) as a nanofiller on mechanical and thermal properties of linear low-density polyethylene/ethylene–vinyl acetate copolymers blend (LLDPE/EVA) had been investigated. The antimicrobial potential of the synthesized samples had been studied. The developed LLDPE/EVA/MMT/Ag nanocomposites films (NCFs) had been characterized by UV–Vis. spectroscopy, FTIR and XRD analysis. The mechanical, and thermal properties of LLDPE/EVA/MMT/Ag NCFs had been investigated. The results showed that incorporating the MMT/Ag NCs at lower phr (part per hundred resins) content resulted in both improvement in the mechanical properties and the thermal stability. The antimicrobial results demonstrated that LLDPE/EVA blend with 5 phr MMT/Ag NCs possesses the most powerful impact on the tested microbes. The SEM analysis of the treated cells showed, noticeable morphological abnormalities (the complete lysis of the outer surface followed by deformations of cells). Accordingly, the synthesized nanocomposites open the area of interest for possible application in a broad range of purposes like environmental and biomedical applications. |
| doi_str_mv | 10.1007/s10904-021-02137-4 |
| format | Article |
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The effects of montmorillonite/silver nanocomposites (MMT/Ag NCs) as a nanofiller on mechanical and thermal properties of linear low-density polyethylene/ethylene–vinyl acetate copolymers blend (LLDPE/EVA) had been investigated. The antimicrobial potential of the synthesized samples had been studied. The developed LLDPE/EVA/MMT/Ag nanocomposites films (NCFs) had been characterized by UV–Vis. spectroscopy, FTIR and XRD analysis. The mechanical, and thermal properties of LLDPE/EVA/MMT/Ag NCFs had been investigated. The results showed that incorporating the MMT/Ag NCs at lower phr (part per hundred resins) content resulted in both improvement in the mechanical properties and the thermal stability. The antimicrobial results demonstrated that LLDPE/EVA blend with 5 phr MMT/Ag NCs possesses the most powerful impact on the tested microbes. The SEM analysis of the treated cells showed, noticeable morphological abnormalities (the complete lysis of the outer surface followed by deformations of cells). Accordingly, the synthesized nanocomposites open the area of interest for possible application in a broad range of purposes like environmental and biomedical applications.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-021-02137-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Abnormalities ; Antiinfectives and antibacterials ; Antimicrobial agents ; Bacterial diseases ; Biomedical materials ; Chemistry ; Chemistry and Materials Science ; Copolymers ; Ethylene vinyl acetates ; Gamma irradiation ; Inorganic Chemistry ; Low density polyethylenes ; Mechanical properties ; Montmorillonite ; Nanocomposites ; Organic Chemistry ; Polymer Sciences ; Silver ; Synthesis ; Thermal stability ; Thermodynamic properties</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2022-02, Vol.32 (2), p.631-645</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-6d5758f38240712fba7f4c0c022eefdaa3289a631dad10b9d59c1f4c3db164e23</citedby><cites>FETCH-LOGICAL-c319t-6d5758f38240712fba7f4c0c022eefdaa3289a631dad10b9d59c1f4c3db164e23</cites><orcidid>0000-0002-6354-6348 ; 0000-0001-5410-7936</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-021-02137-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-021-02137-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Bekhit, Mohamad</creatorcontrib><creatorcontrib>El-Sabbagh, Salwa H.</creatorcontrib><creatorcontrib>Mohamed, Rasha M.</creatorcontrib><creatorcontrib>El-Sayyad, Gharieb S.</creatorcontrib><creatorcontrib>Sokary, Rehab</creatorcontrib><title>Mechanical, Thermal and Antimicrobial Properties of LLDPE/EVA/MMT/Ag Nanocomposites Films Synthesized by Gamma Irradiation</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>The impact of bacterial diseases and the development of effective antimicrobial agents have drawn much consideration as a main healthcare challenge. The effects of montmorillonite/silver nanocomposites (MMT/Ag NCs) as a nanofiller on mechanical and thermal properties of linear low-density polyethylene/ethylene–vinyl acetate copolymers blend (LLDPE/EVA) had been investigated. The antimicrobial potential of the synthesized samples had been studied. The developed LLDPE/EVA/MMT/Ag nanocomposites films (NCFs) had been characterized by UV–Vis. spectroscopy, FTIR and XRD analysis. The mechanical, and thermal properties of LLDPE/EVA/MMT/Ag NCFs had been investigated. The results showed that incorporating the MMT/Ag NCs at lower phr (part per hundred resins) content resulted in both improvement in the mechanical properties and the thermal stability. The antimicrobial results demonstrated that LLDPE/EVA blend with 5 phr MMT/Ag NCs possesses the most powerful impact on the tested microbes. The SEM analysis of the treated cells showed, noticeable morphological abnormalities (the complete lysis of the outer surface followed by deformations of cells). Accordingly, the synthesized nanocomposites open the area of interest for possible application in a broad range of purposes like environmental and biomedical applications.</description><subject>Abnormalities</subject><subject>Antiinfectives and antibacterials</subject><subject>Antimicrobial agents</subject><subject>Bacterial diseases</subject><subject>Biomedical materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Ethylene vinyl acetates</subject><subject>Gamma irradiation</subject><subject>Inorganic Chemistry</subject><subject>Low density polyethylenes</subject><subject>Mechanical properties</subject><subject>Montmorillonite</subject><subject>Nanocomposites</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Silver</subject><subject>Synthesis</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEqXwA6wssSXEr7yWEbSlUgqVKGwtJ3ZaV0lc7HTRfj0uQbBjMZrR6N47mgPALUYPGKEkdBhliAWI4FPRJGBnYISjhAWYRfj8d2b0Elw5t0WIpijCI3BcqGojOl2J5h6uNsq2ooGikzDvet3qyppS-83Smp2yvVYOmhoWxdNyEk4-8nCxWIX5Gr6IzlSm3Rmney-Z6qZ18O3Q9Rvl9FFJWB7gTLStgHNrhdSi16a7Bhe1aJy6-elj8D6drB6fg-J1Nn_Mi6CiOOuDWEZJlNY0JQwlmNSlSGpWoQoRolQthaAkzURMsRQSozKTUVZhr6CyxDFThI7B3ZC7s-Zzr1zPt2ZvO3-Sk5iwLKXE1xiQQeVfds6qmu-sboU9cIz4iTEfGHPPl38z5syb6GByXtytlf2L_sf1BY7vfyQ</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Bekhit, Mohamad</creator><creator>El-Sabbagh, Salwa H.</creator><creator>Mohamed, Rasha M.</creator><creator>El-Sayyad, Gharieb S.</creator><creator>Sokary, Rehab</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6354-6348</orcidid><orcidid>https://orcid.org/0000-0001-5410-7936</orcidid></search><sort><creationdate>20220201</creationdate><title>Mechanical, Thermal and Antimicrobial Properties of LLDPE/EVA/MMT/Ag Nanocomposites Films Synthesized by Gamma Irradiation</title><author>Bekhit, Mohamad ; El-Sabbagh, Salwa H. ; Mohamed, Rasha M. ; El-Sayyad, Gharieb S. ; Sokary, Rehab</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-6d5758f38240712fba7f4c0c022eefdaa3289a631dad10b9d59c1f4c3db164e23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Abnormalities</topic><topic>Antiinfectives and antibacterials</topic><topic>Antimicrobial agents</topic><topic>Bacterial diseases</topic><topic>Biomedical materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Ethylene vinyl acetates</topic><topic>Gamma irradiation</topic><topic>Inorganic Chemistry</topic><topic>Low density polyethylenes</topic><topic>Mechanical properties</topic><topic>Montmorillonite</topic><topic>Nanocomposites</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Silver</topic><topic>Synthesis</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bekhit, Mohamad</creatorcontrib><creatorcontrib>El-Sabbagh, Salwa H.</creatorcontrib><creatorcontrib>Mohamed, Rasha M.</creatorcontrib><creatorcontrib>El-Sayyad, Gharieb S.</creatorcontrib><creatorcontrib>Sokary, Rehab</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bekhit, Mohamad</au><au>El-Sabbagh, Salwa H.</au><au>Mohamed, Rasha M.</au><au>El-Sayyad, Gharieb S.</au><au>Sokary, Rehab</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical, Thermal and Antimicrobial Properties of LLDPE/EVA/MMT/Ag Nanocomposites Films Synthesized by Gamma Irradiation</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2022-02-01</date><risdate>2022</risdate><volume>32</volume><issue>2</issue><spage>631</spage><epage>645</epage><pages>631-645</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>The impact of bacterial diseases and the development of effective antimicrobial agents have drawn much consideration as a main healthcare challenge. 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| subjects | Abnormalities Antiinfectives and antibacterials Antimicrobial agents Bacterial diseases Biomedical materials Chemistry Chemistry and Materials Science Copolymers Ethylene vinyl acetates Gamma irradiation Inorganic Chemistry Low density polyethylenes Mechanical properties Montmorillonite Nanocomposites Organic Chemistry Polymer Sciences Silver Synthesis Thermal stability Thermodynamic properties |
| title | Mechanical, Thermal and Antimicrobial Properties of LLDPE/EVA/MMT/Ag Nanocomposites Films Synthesized by Gamma Irradiation |
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