Efficient UV–visible photodetector based on single CuO/Cu2O core-shell nanowire

•CuO/Cu2O core-shell is prepared by deposition of Cu2O nanoparticles over the surface of CuO nanowires.•The influence of type-II heterojunction and metal-semiconductor junction on the performance of photodetectors are explored.•FESEM, HRTEM, UV-visible absorption, Raman, and XRD data are used to val...

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Veröffentlicht in:Journal of alloys and compounds 2022-02, Vol.895, p.162546, Article 162546
Hauptverfasser: Kajli, Sourav Kumar, Ray, Debdutta, Roy, Somnath C.
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Sprache:eng
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Zusammenfassung:•CuO/Cu2O core-shell is prepared by deposition of Cu2O nanoparticles over the surface of CuO nanowires.•The influence of type-II heterojunction and metal-semiconductor junction on the performance of photodetectors are explored.•FESEM, HRTEM, UV-visible absorption, Raman, and XRD data are used to validate the formation of core-shell architecture.•Individual nanowire device is fabricated by one-step photolithography, metallization, and lift-off process.•CuO/Cu2O core-shell nanowire shows better performance as a UV–visible photodetector compared to the bare CuO nanowire. [Display omitted] One-dimensional nanostructures such as nanowires show better photoresponse than that of their bulk counterparts because of unidirectional transport that significantly reduces recombination and scattering of photo-generated charge carriers. CuO and Cu2O are relatively abundant transition metal oxides with optical band gaps suitable for efficient detection of UV and visible radiation. In addition, they form type-II heterojunction for efficient charge separation. Here, we report the fabrication of CuO/Cu2O core-shell nanowire arrays by chemical bath deposited Cu2O layer over thermally grown CuO nanowires. Photodetector devices based on individual CuO and CuO/Cu2O core-shell nanowire are fabricated through photolithography using Pd metal contact for studying response under UV and visible light illumination. Core-shell nanostructures show better performance in terms of responsivity, detectivity, external quantum efficiency, faster response, and recovery times over that of bare CuO nanowires. This is attributed to the Ohmic junction formed at the Pd-Cu2O interface that ensures barrierless hole transport for the core-shell photodetector. Further, the type-II heterojunction formed at CuO/Cu2O interface enhances hole concentration in the Cu2O shell layer, which is responsible for better photoresponse in core-shell nanostructures. The results establish that CuO/Cu2O core-shell nanowires offer simplified design and highly efficient photodetectors that can be used in several optoelectronic devices.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2021.162546