Thin and efficient EMI shielding materials from binary thermoplastic blend nanocomposites
EMI shielding materials and related research are of very relevance in this era of electronic gadgets. Here this report presents a binary thermoplastic blend nanocomposite system comprising poly‐(trimethylene terephthalate) and polyethene compatibilized with multiwalled carbon nanotubes, which are sh...
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Veröffentlicht in: | Polymers for advanced technologies 2022-03, Vol.33 (3), p.966-979 |
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creator | Kunjappan, Aswathi Madathinal Reghunadhan, Arunima Ramachandran, Ajitha A. Mathew, Lovely Padmanabhan, Moothetty Laroze, David Thomas, Sabu |
description | EMI shielding materials and related research are of very relevance in this era of electronic gadgets. Here this report presents a binary thermoplastic blend nanocomposite system comprising poly‐(trimethylene terephthalate) and polyethene compatibilized with multiwalled carbon nanotubes, which are showing superior electromagnetic interference (EMI) shielding compared to similar systems. The blend composition with a 90/10 ratio of PTT/PE was showing the optimum properties when a MWCNT concentration of 1 wt% was incorporated. The compatibilization efficacy was analyzed and confirmed through scanning and tunneling electron microscopes. The MWCNTs are preferably localized in the PTT phase. The blend system provides an electrical percolation threshold of 0.19 wt% due to the double percolating effect of the blend system and MWCNT in the PTT phase. It was observed that the EMI shielding value shows a corresponding increase with MWCNT loadings. The most favorable value obtained for EMI shielding effectiveness was ~32 dB and it was with 3 wt% MWCNT of film thickness 2 mm in range of frequency 2–4 GHz. The PTT/PE/MWCNT system was not considered for EMI applications anywhere else. The theoretical support of the experimental data was examined for DC conductivity employing different models such as Voet, Bueche, and Scarisbrick and the actual contribution of reflection, absorption, transmission loss to the total EMI shielding was done with Power balance. The present work is a facile and cost‐effective method to fabricate lightweight and materials with high EMI shielding properties for mobile phones. |
doi_str_mv | 10.1002/pat.5571 |
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Here this report presents a binary thermoplastic blend nanocomposite system comprising poly‐(trimethylene terephthalate) and polyethene compatibilized with multiwalled carbon nanotubes, which are showing superior electromagnetic interference (EMI) shielding compared to similar systems. The blend composition with a 90/10 ratio of PTT/PE was showing the optimum properties when a MWCNT concentration of 1 wt% was incorporated. The compatibilization efficacy was analyzed and confirmed through scanning and tunneling electron microscopes. The MWCNTs are preferably localized in the PTT phase. The blend system provides an electrical percolation threshold of 0.19 wt% due to the double percolating effect of the blend system and MWCNT in the PTT phase. It was observed that the EMI shielding value shows a corresponding increase with MWCNT loadings. The most favorable value obtained for EMI shielding effectiveness was ~32 dB and it was with 3 wt% MWCNT of film thickness 2 mm in range of frequency 2–4 GHz. The PTT/PE/MWCNT system was not considered for EMI applications anywhere else. The theoretical support of the experimental data was examined for DC conductivity employing different models such as Voet, Bueche, and Scarisbrick and the actual contribution of reflection, absorption, transmission loss to the total EMI shielding was done with Power balance. The present work is a facile and cost‐effective method to fabricate lightweight and materials with high EMI shielding properties for mobile phones.</description><identifier>ISSN: 1042-7147</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.5571</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>blend nanocomposite ; DC conductivity ; dielectric studies ; Electromagnetic shielding ; Electronic devices ; EMI shielding ; Film thickness ; Microscopes ; morphology ; Multi wall carbon nanotubes ; Nanocomposites ; Percolation ; Transmission loss</subject><ispartof>Polymers for advanced technologies, 2022-03, Vol.33 (3), p.966-979</ispartof><rights>2022 John Wiley & Sons Ltd.</rights><rights>2022 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2931-37813680be2eb6fb82a3d891df0e0afce7306bcc7d6fe68ef1aad2066bbb307f3</citedby><cites>FETCH-LOGICAL-c2931-37813680be2eb6fb82a3d891df0e0afce7306bcc7d6fe68ef1aad2066bbb307f3</cites><orcidid>0000-0003-4726-5746</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpat.5571$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpat.5571$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Kunjappan, Aswathi Madathinal</creatorcontrib><creatorcontrib>Reghunadhan, Arunima</creatorcontrib><creatorcontrib>Ramachandran, Ajitha A.</creatorcontrib><creatorcontrib>Mathew, Lovely</creatorcontrib><creatorcontrib>Padmanabhan, Moothetty</creatorcontrib><creatorcontrib>Laroze, David</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><title>Thin and efficient EMI shielding materials from binary thermoplastic blend nanocomposites</title><title>Polymers for advanced technologies</title><description>EMI shielding materials and related research are of very relevance in this era of electronic gadgets. Here this report presents a binary thermoplastic blend nanocomposite system comprising poly‐(trimethylene terephthalate) and polyethene compatibilized with multiwalled carbon nanotubes, which are showing superior electromagnetic interference (EMI) shielding compared to similar systems. The blend composition with a 90/10 ratio of PTT/PE was showing the optimum properties when a MWCNT concentration of 1 wt% was incorporated. The compatibilization efficacy was analyzed and confirmed through scanning and tunneling electron microscopes. The MWCNTs are preferably localized in the PTT phase. The blend system provides an electrical percolation threshold of 0.19 wt% due to the double percolating effect of the blend system and MWCNT in the PTT phase. It was observed that the EMI shielding value shows a corresponding increase with MWCNT loadings. The most favorable value obtained for EMI shielding effectiveness was ~32 dB and it was with 3 wt% MWCNT of film thickness 2 mm in range of frequency 2–4 GHz. The PTT/PE/MWCNT system was not considered for EMI applications anywhere else. The theoretical support of the experimental data was examined for DC conductivity employing different models such as Voet, Bueche, and Scarisbrick and the actual contribution of reflection, absorption, transmission loss to the total EMI shielding was done with Power balance. The present work is a facile and cost‐effective method to fabricate lightweight and materials with high EMI shielding properties for mobile phones.</description><subject>blend nanocomposite</subject><subject>DC conductivity</subject><subject>dielectric studies</subject><subject>Electromagnetic shielding</subject><subject>Electronic devices</subject><subject>EMI shielding</subject><subject>Film thickness</subject><subject>Microscopes</subject><subject>morphology</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Percolation</subject><subject>Transmission loss</subject><issn>1042-7147</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLAzEQhYMoWKvgTwh48bI1ybbJ7rGUqoWKHurBU0iyE5uym6zJFum_N7VePc3AfO8N7yF0S8mEEsIeejVMZjNBz9CIkrou6Kyi58d9ygpBp-ISXaW0IyTfajFCH5ut81j5BoO1zjjwA16-rHDaOmgb5z9xpwaITrUJ2xg6rJ1X8YCHLcQu9K1KgzNYt5AdvPLBhK4PyQ2QrtGFzSq4-Ztj9P643Cyei_Xr02oxXxeG1SUtSlHRkldEAwPNra6YKpuqpo0lQJQ1IErCtTGi4RZ4BZYq1TDCuda6JMKWY3R38u1j-NpDGuQu7KPPLyXjbMqznNJM3Z8oE0NKEazso-tyEkmJPBYnc3HyWFxGixP67Vo4_MvJt_nml_8BQn5wdw</recordid><startdate>202203</startdate><enddate>202203</enddate><creator>Kunjappan, Aswathi Madathinal</creator><creator>Reghunadhan, Arunima</creator><creator>Ramachandran, Ajitha A.</creator><creator>Mathew, Lovely</creator><creator>Padmanabhan, Moothetty</creator><creator>Laroze, David</creator><creator>Thomas, Sabu</creator><general>John Wiley & Sons, Ltd</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4726-5746</orcidid></search><sort><creationdate>202203</creationdate><title>Thin and efficient EMI shielding materials from binary thermoplastic blend nanocomposites</title><author>Kunjappan, Aswathi Madathinal ; Reghunadhan, Arunima ; Ramachandran, Ajitha A. ; Mathew, Lovely ; Padmanabhan, Moothetty ; Laroze, David ; Thomas, Sabu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2931-37813680be2eb6fb82a3d891df0e0afce7306bcc7d6fe68ef1aad2066bbb307f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>blend nanocomposite</topic><topic>DC conductivity</topic><topic>dielectric studies</topic><topic>Electromagnetic shielding</topic><topic>Electronic devices</topic><topic>EMI shielding</topic><topic>Film thickness</topic><topic>Microscopes</topic><topic>morphology</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Percolation</topic><topic>Transmission loss</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kunjappan, Aswathi Madathinal</creatorcontrib><creatorcontrib>Reghunadhan, Arunima</creatorcontrib><creatorcontrib>Ramachandran, Ajitha A.</creatorcontrib><creatorcontrib>Mathew, Lovely</creatorcontrib><creatorcontrib>Padmanabhan, Moothetty</creatorcontrib><creatorcontrib>Laroze, David</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kunjappan, Aswathi Madathinal</au><au>Reghunadhan, Arunima</au><au>Ramachandran, Ajitha A.</au><au>Mathew, Lovely</au><au>Padmanabhan, Moothetty</au><au>Laroze, David</au><au>Thomas, Sabu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thin and efficient EMI shielding materials from binary thermoplastic blend nanocomposites</atitle><jtitle>Polymers for advanced technologies</jtitle><date>2022-03</date><risdate>2022</risdate><volume>33</volume><issue>3</issue><spage>966</spage><epage>979</epage><pages>966-979</pages><issn>1042-7147</issn><eissn>1099-1581</eissn><abstract>EMI shielding materials and related research are of very relevance in this era of electronic gadgets. Here this report presents a binary thermoplastic blend nanocomposite system comprising poly‐(trimethylene terephthalate) and polyethene compatibilized with multiwalled carbon nanotubes, which are showing superior electromagnetic interference (EMI) shielding compared to similar systems. The blend composition with a 90/10 ratio of PTT/PE was showing the optimum properties when a MWCNT concentration of 1 wt% was incorporated. The compatibilization efficacy was analyzed and confirmed through scanning and tunneling electron microscopes. The MWCNTs are preferably localized in the PTT phase. The blend system provides an electrical percolation threshold of 0.19 wt% due to the double percolating effect of the blend system and MWCNT in the PTT phase. It was observed that the EMI shielding value shows a corresponding increase with MWCNT loadings. The most favorable value obtained for EMI shielding effectiveness was ~32 dB and it was with 3 wt% MWCNT of film thickness 2 mm in range of frequency 2–4 GHz. The PTT/PE/MWCNT system was not considered for EMI applications anywhere else. The theoretical support of the experimental data was examined for DC conductivity employing different models such as Voet, Bueche, and Scarisbrick and the actual contribution of reflection, absorption, transmission loss to the total EMI shielding was done with Power balance. The present work is a facile and cost‐effective method to fabricate lightweight and materials with high EMI shielding properties for mobile phones.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pat.5571</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0003-4726-5746</orcidid></addata></record> |
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subjects | blend nanocomposite DC conductivity dielectric studies Electromagnetic shielding Electronic devices EMI shielding Film thickness Microscopes morphology Multi wall carbon nanotubes Nanocomposites Percolation Transmission loss |
title | Thin and efficient EMI shielding materials from binary thermoplastic blend nanocomposites |
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