Neutral Mo6Q8-clusters with terminal phosphane ligands – a route to water-soluble molecular units of Chevrel phases

Despite the numerous studies on Chevrel phases, their building blocks – molecular compounds containing the {Mo6Q8} cluster core – are hardly presented in the literature. Here we present rare examples of phosphane molybdenum chalcogenide clusters – [{Mo6Q8}(Ph2PC2H4COOH)6] (Q = S or Se) – which have...

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Veröffentlicht in:	New journal of chemistry 2022-02, Vol.46 (5), p.2218-2223
Hauptverfasser:	Novikova, Evgeniya D, Gassan, Alena D, Ivanov, Anton A, Vorotnikov, Yuri A, Shestopalov, Michael A
Format:	Artikel
Sprache:	eng
Schlagworte:	Clusters Crystal structure Ligands Optical properties Water chemistry
Online-Zugang:	Volltext
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