The power of model-fitting kinetic analysis applied to complex thermal decomposition of explosives: reconciling the kinetics of bicyclo-HMX thermolysis in solid state and solution

Thermal decomposition of cis -1,3,4,6-tetranitrooctahydroimidazo-[4,5-d]imidazole (Bicyclo-HMX) both in solid state and in solution has been studied with a set of thermal analysis methods. Differential scanning calorimetry data obtained at several heating rates were analyzed using the model-fitting...

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Veröffentlicht in:	Journal of thermal analysis and calorimetry 2022-02, Vol.147 (4), p.3195-3206
Hauptverfasser:	Muravyev, Nikita V., Melnikov, Igor N., Monogarov, Konstantin A., Kuchurov, Ilya V., Pivkina, Alla N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Analytical Chemistry Calorimetry Chemical bonds Chemistry Chemistry and Materials Science Decomposition Differential scanning calorimetry Energetic materials Explosives Freeware Growth models Heating HMX Imidazole Inorganic Chemistry Measurement Science and Instrumentation Nitrogen dioxide Nucleation Physical Chemistry Polymer Sciences Pyrolysis Solid state Thermal decomposition Thermodynamic properties
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