Ultrasensitive luteolin electrochemical sensor based on zeolitic imidazolate frameworks-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode

The accurate determination of luteolin is of great significance for food and pharmaceutical industry. Herein, an ultrasensitive electrochemical sensor for luteolin based on zeolitic imidazolate frameworks (ZIF)-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene qu...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2022-01, Vol.351, p.130938, Article 130938
Hauptverfasser: Hu, Yang, Zhang, Li, Zhao, Pengcheng, Wang, Chenxi, Fei, Junjie, Xie, Yixi
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container_start_page 130938
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creator Hu, Yang
Zhang, Li
Zhao, Pengcheng
Wang, Chenxi
Fei, Junjie
Xie, Yixi
description The accurate determination of luteolin is of great significance for food and pharmaceutical industry. Herein, an ultrasensitive electrochemical sensor for luteolin based on zeolitic imidazolate frameworks (ZIF)-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode (Co3O4@N-CNTs/NH2-GQDs/GCE) was constructed. The Co3O4@N-CNTs composites were synthesized through direct pyrolysis of ZIF-67 in the N2 atmosphere, which exhibited outstanding electrochemical performance for luteolin due to the conductivity of N-CNTs and the catalytic action of Co3O4. Under optimized conditions, the Co3O4@N-CNTs /NH2-GQDs/GCE exhibited a linear range of 0.5–1000 nM for detecting luteolin, with a low detection limit (LOD) of 0.1 nM (S/N = 3). Furthermore, the sensor was successfully applied for the detection of luteolin in Chrysanthemum extracts. •The Co3O4@N-CNTs/NH2-GQDs nanocomposite was firstly prepared.•The electrochemical sensor based on the composite exhibited outstanding electrochemical performance for luteolin.•The sensor was successfully employed to detect luteolin in the chrysanthemum extracts.
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Herein, an ultrasensitive electrochemical sensor for luteolin based on zeolitic imidazolate frameworks (ZIF)-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode (Co3O4@N-CNTs/NH2-GQDs/GCE) was constructed. The Co3O4@N-CNTs composites were synthesized through direct pyrolysis of ZIF-67 in the N2 atmosphere, which exhibited outstanding electrochemical performance for luteolin due to the conductivity of N-CNTs and the catalytic action of Co3O4. Under optimized conditions, the Co3O4@N-CNTs /NH2-GQDs/GCE exhibited a linear range of 0.5–1000 nM for detecting luteolin, with a low detection limit (LOD) of 0.1 nM (S/N = 3). Furthermore, the sensor was successfully applied for the detection of luteolin in Chrysanthemum extracts. •The Co3O4@N-CNTs/NH2-GQDs nanocomposite was firstly prepared.•The electrochemical sensor based on the composite exhibited outstanding electrochemical performance for luteolin.•The sensor was successfully employed to detect luteolin in the chrysanthemum extracts.</description><identifier>ISSN: 0925-4005</identifier><identifier>EISSN: 1873-3077</identifier><identifier>DOI: 10.1016/j.snb.2021.130938</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Carbon ; Carbon nanotubes ; Chemical sensors ; Co3O4@N-CNTs ; Cobalt oxides ; Composite materials ; Electrochemical analysis ; Electrochemical sensors ; Electrons ; Graphene ; Luteolin ; Metal-organic frameworks ; NH2-GQD ; Nitrogen ; Pyrolysis ; Quantum dots ; Sensors ; Zeolites ; ZIF-derived material</subject><ispartof>Sensors and actuators. 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B, Chemical</title><description>The accurate determination of luteolin is of great significance for food and pharmaceutical industry. Herein, an ultrasensitive electrochemical sensor for luteolin based on zeolitic imidazolate frameworks (ZIF)-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode (Co3O4@N-CNTs/NH2-GQDs/GCE) was constructed. The Co3O4@N-CNTs composites were synthesized through direct pyrolysis of ZIF-67 in the N2 atmosphere, which exhibited outstanding electrochemical performance for luteolin due to the conductivity of N-CNTs and the catalytic action of Co3O4. Under optimized conditions, the Co3O4@N-CNTs /NH2-GQDs/GCE exhibited a linear range of 0.5–1000 nM for detecting luteolin, with a low detection limit (LOD) of 0.1 nM (S/N = 3). Furthermore, the sensor was successfully applied for the detection of luteolin in Chrysanthemum extracts. •The Co3O4@N-CNTs/NH2-GQDs nanocomposite was firstly prepared.•The electrochemical sensor based on the composite exhibited outstanding electrochemical performance for luteolin.•The sensor was successfully employed to detect luteolin in the chrysanthemum extracts.</description><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Chemical sensors</subject><subject>Co3O4@N-CNTs</subject><subject>Cobalt oxides</subject><subject>Composite materials</subject><subject>Electrochemical analysis</subject><subject>Electrochemical sensors</subject><subject>Electrons</subject><subject>Graphene</subject><subject>Luteolin</subject><subject>Metal-organic frameworks</subject><subject>NH2-GQD</subject><subject>Nitrogen</subject><subject>Pyrolysis</subject><subject>Quantum dots</subject><subject>Sensors</subject><subject>Zeolites</subject><subject>ZIF-derived material</subject><issn>0925-4005</issn><issn>1873-3077</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kc2KFDEUhYMo2LY-gLuA6-rJT9cfbpTB0YEBN8463CS3ZtKmkp4kNY79wD6HKXrcCoFsvvNxD4eQ95ztOOPdxWGXg94JJviOSzbK4QXZ8KGXjWR9_5Js2CjaZs9Y-5q8yfnAGNvLjm3In1tfEmQM2RX3iNQvBaN3gaJHU1I09zg7A56uSExUV9bSGOhpxYoz1M3Owil6KEinBDP-iulnbiym6rPURA2-0JJcfHIW6ScaXPXeYaA2HlcAkq6-ACGWReMFzC7EZlqCKS4G8O5UobsEx3sMSB8WCGWZa7bk6p6PsR6Omc7RusmtpIec_0mfS1h8S15N4DO-e_635Pbqy4_Lb83N96_Xl59vGiNFWxo0XYesbVFPmmmAcd_3fLTTgB23o20ZcBAMxrYDMWgQ7X7QTIhh0oC6Aym35MPZe0zxYcFc1CEuqbbISnRCMjnK-raEnymTYs4JJ3VMbob0W3Gm1jnVQdU51TqnOs9ZMx_PGaznPzpMKhuHwaB1qZZUNrr_pP8COFGxfQ</recordid><startdate>20220115</startdate><enddate>20220115</enddate><creator>Hu, Yang</creator><creator>Zhang, Li</creator><creator>Zhao, Pengcheng</creator><creator>Wang, Chenxi</creator><creator>Fei, Junjie</creator><creator>Xie, Yixi</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20220115</creationdate><title>Ultrasensitive luteolin electrochemical sensor based on zeolitic imidazolate frameworks-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode</title><author>Hu, Yang ; Zhang, Li ; Zhao, Pengcheng ; Wang, Chenxi ; Fei, Junjie ; Xie, Yixi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-ec66e055ebfb0baa947719df8e61d9d50a1a20a956a28ba2548b0228fbaeb6a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon</topic><topic>Carbon nanotubes</topic><topic>Chemical sensors</topic><topic>Co3O4@N-CNTs</topic><topic>Cobalt oxides</topic><topic>Composite materials</topic><topic>Electrochemical analysis</topic><topic>Electrochemical sensors</topic><topic>Electrons</topic><topic>Graphene</topic><topic>Luteolin</topic><topic>Metal-organic frameworks</topic><topic>NH2-GQD</topic><topic>Nitrogen</topic><topic>Pyrolysis</topic><topic>Quantum dots</topic><topic>Sensors</topic><topic>Zeolites</topic><topic>ZIF-derived material</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Yang</creatorcontrib><creatorcontrib>Zhang, Li</creatorcontrib><creatorcontrib>Zhao, Pengcheng</creatorcontrib><creatorcontrib>Wang, Chenxi</creatorcontrib><creatorcontrib>Fei, Junjie</creatorcontrib><creatorcontrib>Xie, Yixi</creatorcontrib><collection>CrossRef</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Sensors and actuators. B, Chemical</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Yang</au><au>Zhang, Li</au><au>Zhao, Pengcheng</au><au>Wang, Chenxi</au><au>Fei, Junjie</au><au>Xie, Yixi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrasensitive luteolin electrochemical sensor based on zeolitic imidazolate frameworks-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode</atitle><jtitle>Sensors and actuators. B, Chemical</jtitle><date>2022-01-15</date><risdate>2022</risdate><volume>351</volume><spage>130938</spage><pages>130938-</pages><artnum>130938</artnum><issn>0925-4005</issn><eissn>1873-3077</eissn><abstract>The accurate determination of luteolin is of great significance for food and pharmaceutical industry. Herein, an ultrasensitive electrochemical sensor for luteolin based on zeolitic imidazolate frameworks (ZIF)-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode (Co3O4@N-CNTs/NH2-GQDs/GCE) was constructed. The Co3O4@N-CNTs composites were synthesized through direct pyrolysis of ZIF-67 in the N2 atmosphere, which exhibited outstanding electrochemical performance for luteolin due to the conductivity of N-CNTs and the catalytic action of Co3O4. Under optimized conditions, the Co3O4@N-CNTs /NH2-GQDs/GCE exhibited a linear range of 0.5–1000 nM for detecting luteolin, with a low detection limit (LOD) of 0.1 nM (S/N = 3). Furthermore, the sensor was successfully applied for the detection of luteolin in Chrysanthemum extracts. •The Co3O4@N-CNTs/NH2-GQDs nanocomposite was firstly prepared.•The electrochemical sensor based on the composite exhibited outstanding electrochemical performance for luteolin.•The sensor was successfully employed to detect luteolin in the chrysanthemum extracts.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.snb.2021.130938</doi></addata></record>
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subjects Carbon
Carbon nanotubes
Chemical sensors
Co3O4@N-CNTs
Cobalt oxides
Composite materials
Electrochemical analysis
Electrochemical sensors
Electrons
Graphene
Luteolin
Metal-organic frameworks
NH2-GQD
Nitrogen
Pyrolysis
Quantum dots
Sensors
Zeolites
ZIF-derived material
title Ultrasensitive luteolin electrochemical sensor based on zeolitic imidazolate frameworks-derived cobalt trioxide @ nitrogen doped carbon nanotube/amino-functionalized graphene quantum dots composites modified glass carbon electrode
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