Toward On-Line Slag Composition Analysis: Optical Emissions from Laboratory Electric Arc
Electric arc furnaces and ladle furnaces have an important role in the future of steelmaking where CO 2 emissions have to be mitigated to an acceptable level. One way to address this goal is to optimize and improve the current practices by adjusting the chemistry and reactions with material addition...
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Veröffentlicht in: | Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2022-02, Vol.53 (1), p.454-465 |
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creator | Pauna, H. Tuomela, A. Aula, M. Turunen, P. Pankratov, V. Huttula, M. Fabritius, T. |
description | Electric arc furnaces and ladle furnaces have an important role in the future of steelmaking where
CO
2
emissions have to be mitigated to an acceptable level. One way to address this goal is to optimize and improve the current practices by adjusting the chemistry and reactions with material additions or gas injections. These procedures would greatly benefit from on-line slag composition analysis. Since the electric arcs radiate throughout the melting, optical emission spectroscopy is a potential method for such analysis. In this study, optical emissions from the electric arc are measured in a laboratory environment. Dozens of atomic emission lines were correlated with
Cr
2
O
3
,
Fe
2
O
3
,
Al
2
O
3
,
SiO
2
, MnO, MgO, CaO,
CaF
2
,
V
2
O
5
, and Ni content of the slag together with correlation between
CaF
2
and molecular optical emission bands of CaF. Optimal spectral resolution for industrial applications was deducted to be between 0.022 and 0.179 nm. |
doi_str_mv | 10.1007/s11663-021-02382-5 |
format | Article |
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CO
2
emissions have to be mitigated to an acceptable level. One way to address this goal is to optimize and improve the current practices by adjusting the chemistry and reactions with material additions or gas injections. These procedures would greatly benefit from on-line slag composition analysis. Since the electric arcs radiate throughout the melting, optical emission spectroscopy is a potential method for such analysis. In this study, optical emissions from the electric arc are measured in a laboratory environment. Dozens of atomic emission lines were correlated with
Cr
2
O
3
,
Fe
2
O
3
,
Al
2
O
3
,
SiO
2
, MnO, MgO, CaO,
CaF
2
,
V
2
O
5
, and Ni content of the slag together with correlation between
CaF
2
and molecular optical emission bands of CaF. Optimal spectral resolution for industrial applications was deducted to be between 0.022 and 0.179 nm.</description><identifier>ISSN: 1073-5615</identifier><identifier>EISSN: 1543-1916</identifier><identifier>DOI: 10.1007/s11663-021-02382-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; Calcium fluoride ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composition ; Electric arc furnaces ; Electric arcs ; Emission analysis ; Industrial applications ; Laboratories ; Ladle furnaces ; Ladle metallurgy ; Materials Science ; Metallic Materials ; Nanotechnology ; Optical emission spectroscopy ; Optimization ; Original Research Article ; Silicon dioxide ; Slag ; Spectral resolution ; Steel making ; Structural Materials ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Metallurgical and materials transactions. B, Process metallurgy and materials processing science, 2022-02, Vol.53 (1), p.454-465</ispartof><rights>The Author(s) 2021</rights><rights>The Author(s) 2021. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c314t-38ccdf0417674a735dfc1bdc2074ec4f116b81cda3d9920e19c31ecefb72f3c23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11663-021-02382-5$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11663-021-02382-5$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Pauna, H.</creatorcontrib><creatorcontrib>Tuomela, A.</creatorcontrib><creatorcontrib>Aula, M.</creatorcontrib><creatorcontrib>Turunen, P.</creatorcontrib><creatorcontrib>Pankratov, V.</creatorcontrib><creatorcontrib>Huttula, M.</creatorcontrib><creatorcontrib>Fabritius, T.</creatorcontrib><title>Toward On-Line Slag Composition Analysis: Optical Emissions from Laboratory Electric Arc</title><title>Metallurgical and materials transactions. B, Process metallurgy and materials processing science</title><addtitle>Metall Mater Trans B</addtitle><description>Electric arc furnaces and ladle furnaces have an important role in the future of steelmaking where
CO
2
emissions have to be mitigated to an acceptable level. One way to address this goal is to optimize and improve the current practices by adjusting the chemistry and reactions with material additions or gas injections. These procedures would greatly benefit from on-line slag composition analysis. Since the electric arcs radiate throughout the melting, optical emission spectroscopy is a potential method for such analysis. In this study, optical emissions from the electric arc are measured in a laboratory environment. Dozens of atomic emission lines were correlated with
Cr
2
O
3
,
Fe
2
O
3
,
Al
2
O
3
,
SiO
2
, MnO, MgO, CaO,
CaF
2
,
V
2
O
5
, and Ni content of the slag together with correlation between
CaF
2
and molecular optical emission bands of CaF. Optimal spectral resolution for industrial applications was deducted to be between 0.022 and 0.179 nm.</description><subject>Aluminum oxide</subject><subject>Calcium fluoride</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composition</subject><subject>Electric arc furnaces</subject><subject>Electric arcs</subject><subject>Emission analysis</subject><subject>Industrial applications</subject><subject>Laboratories</subject><subject>Ladle furnaces</subject><subject>Ladle metallurgy</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanotechnology</subject><subject>Optical emission spectroscopy</subject><subject>Optimization</subject><subject>Original Research Article</subject><subject>Silicon dioxide</subject><subject>Slag</subject><subject>Spectral resolution</subject><subject>Steel making</subject><subject>Structural Materials</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><issn>1073-5615</issn><issn>1543-1916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kE1LxDAQhoMouH78AU8Bz9FM0qatt2VZP6CwB1fwFtI0WbK0TU26yP57oxW8eRhmYN7nZeZF6AboHVBa3EcAITihDFLxkpH8BC0gzziBCsRpmmnBSS4gP0cXMe4ppaKq-AK9b_2nCi3eDKR2g8Gvndrhle9HH93k_ICXg-qO0cUHvBknp1WH172LMa0itsH3uFaND2ry4YjXndFTcBovg75CZ1Z10Vz_9kv09rjerp5JvXl6WS1rojlkE-Gl1q2lGRSiyFTB89ZqaFrNaJEZndn0V1OCbhVvq4pRA1XijDa2KZjlmvFLdDv7jsF_HEyc5N4fQjo6SiYYo5UogSYVm1U6-BiDsXIMrlfhKIHK7wTlnKBMCcqfBGWeID5DMYmHnQl_1v9QXwMVc-c</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Pauna, H.</creator><creator>Tuomela, A.</creator><creator>Aula, M.</creator><creator>Turunen, P.</creator><creator>Pankratov, V.</creator><creator>Huttula, M.</creator><creator>Fabritius, T.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>4U-</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>M2P</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>20220201</creationdate><title>Toward On-Line Slag Composition Analysis: Optical Emissions from Laboratory Electric Arc</title><author>Pauna, H. ; Tuomela, A. ; Aula, M. ; Turunen, P. ; Pankratov, V. ; Huttula, M. ; Fabritius, T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-38ccdf0417674a735dfc1bdc2074ec4f116b81cda3d9920e19c31ecefb72f3c23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aluminum oxide</topic><topic>Calcium fluoride</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Composition</topic><topic>Electric arc furnaces</topic><topic>Electric arcs</topic><topic>Emission analysis</topic><topic>Industrial applications</topic><topic>Laboratories</topic><topic>Ladle furnaces</topic><topic>Ladle metallurgy</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Nanotechnology</topic><topic>Optical emission spectroscopy</topic><topic>Optimization</topic><topic>Original Research Article</topic><topic>Silicon dioxide</topic><topic>Slag</topic><topic>Spectral resolution</topic><topic>Steel making</topic><topic>Structural Materials</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pauna, H.</creatorcontrib><creatorcontrib>Tuomela, A.</creatorcontrib><creatorcontrib>Aula, M.</creatorcontrib><creatorcontrib>Turunen, P.</creatorcontrib><creatorcontrib>Pankratov, V.</creatorcontrib><creatorcontrib>Huttula, M.</creatorcontrib><creatorcontrib>Fabritius, T.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>University Readers</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Metallurgical and materials transactions. B, Process metallurgy and materials processing science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pauna, H.</au><au>Tuomela, A.</au><au>Aula, M.</au><au>Turunen, P.</au><au>Pankratov, V.</au><au>Huttula, M.</au><au>Fabritius, T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Toward On-Line Slag Composition Analysis: Optical Emissions from Laboratory Electric Arc</atitle><jtitle>Metallurgical and materials transactions. B, Process metallurgy and materials processing science</jtitle><stitle>Metall Mater Trans B</stitle><date>2022-02-01</date><risdate>2022</risdate><volume>53</volume><issue>1</issue><spage>454</spage><epage>465</epage><pages>454-465</pages><issn>1073-5615</issn><eissn>1543-1916</eissn><abstract>Electric arc furnaces and ladle furnaces have an important role in the future of steelmaking where
CO
2
emissions have to be mitigated to an acceptable level. One way to address this goal is to optimize and improve the current practices by adjusting the chemistry and reactions with material additions or gas injections. These procedures would greatly benefit from on-line slag composition analysis. Since the electric arcs radiate throughout the melting, optical emission spectroscopy is a potential method for such analysis. In this study, optical emissions from the electric arc are measured in a laboratory environment. Dozens of atomic emission lines were correlated with
Cr
2
O
3
,
Fe
2
O
3
,
Al
2
O
3
,
SiO
2
, MnO, MgO, CaO,
CaF
2
,
V
2
O
5
, and Ni content of the slag together with correlation between
CaF
2
and molecular optical emission bands of CaF. Optimal spectral resolution for industrial applications was deducted to be between 0.022 and 0.179 nm.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11663-021-02382-5</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
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language | eng |
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source | SpringerNature Journals |
subjects | Aluminum oxide Calcium fluoride Characterization and Evaluation of Materials Chemistry and Materials Science Composition Electric arc furnaces Electric arcs Emission analysis Industrial applications Laboratories Ladle furnaces Ladle metallurgy Materials Science Metallic Materials Nanotechnology Optical emission spectroscopy Optimization Original Research Article Silicon dioxide Slag Spectral resolution Steel making Structural Materials Surfaces and Interfaces Thin Films |
title | Toward On-Line Slag Composition Analysis: Optical Emissions from Laboratory Electric Arc |
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