Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides
A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities has been prepared by using deep eutectic solvent (DES) as green media. The as‐synthesized COF was employed as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF nanoparticles...
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| Veröffentlicht in: | Applied organometallic chemistry 2022-01, Vol.36 (1), p.n/a |
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| container_title | Applied organometallic chemistry |
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| creator | Chen, Yu‐Xuan Zhang, Shuo Xue, Yu‐Jie Mo, Li‐Ping Zhang, Zhan‐Hui |
| description | A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities has been prepared by using deep eutectic solvent (DES) as green media. The as‐synthesized COF was employed as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF nanoparticles catalyst (defined as Pd/TFPT‐Azine‐COF) was found to be an efficient heterogeneous catalyst for the Hirao reaction of aryl halides and dialkyl phosphites or diphenylphosphine oxide with excellent recyclability, reusability, and retention of crystallinity.
A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities was prepared and as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF was found to be an efficient heterogeneous catalyst for phosphorylation of aryl bromides with excellent recyclability, reusability, and retention of crystallinity. |
| doi_str_mv | 10.1002/aoc.6480 |
| format | Article |
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A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities was prepared and as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF was found to be an efficient heterogeneous catalyst for phosphorylation of aryl bromides with excellent recyclability, reusability, and retention of crystallinity.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.6480</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>Aromatic compounds ; Bromides ; Catalysts ; Chemistry ; covalent organic framework ; deep eutectic solvent ; Halides ; heterogeneous ligand ; Hirao reaction ; Inorganic salts ; Nanoparticles ; Palladium ; Phosphorylation ; Recyclability</subject><ispartof>Applied organometallic chemistry, 2022-01, Vol.36 (1), p.n/a</ispartof><rights>2021 John Wiley & Sons, Ltd.</rights><rights>2022 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2930-d207b692d2000c65753890a9cc536dafeaa7620bbdc6f2311827c2e24b8b91a13</citedby><cites>FETCH-LOGICAL-c2930-d207b692d2000c65753890a9cc536dafeaa7620bbdc6f2311827c2e24b8b91a13</cites><orcidid>0000-0002-1252-0375 ; 0000-0002-1082-5773 ; 0000-0003-0966-5116 ; 0000-0001-8149-8987 ; 0000-0002-0663-1984</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.6480$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.6480$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Chen, Yu‐Xuan</creatorcontrib><creatorcontrib>Zhang, Shuo</creatorcontrib><creatorcontrib>Xue, Yu‐Jie</creatorcontrib><creatorcontrib>Mo, Li‐Ping</creatorcontrib><creatorcontrib>Zhang, Zhan‐Hui</creatorcontrib><title>Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides</title><title>Applied organometallic chemistry</title><description>A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities has been prepared by using deep eutectic solvent (DES) as green media. The as‐synthesized COF was employed as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF nanoparticles catalyst (defined as Pd/TFPT‐Azine‐COF) was found to be an efficient heterogeneous catalyst for the Hirao reaction of aryl halides and dialkyl phosphites or diphenylphosphine oxide with excellent recyclability, reusability, and retention of crystallinity.
A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities was prepared and as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF was found to be an efficient heterogeneous catalyst for phosphorylation of aryl bromides with excellent recyclability, reusability, and retention of crystallinity.</description><subject>Aromatic compounds</subject><subject>Bromides</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>covalent organic framework</subject><subject>deep eutectic solvent</subject><subject>Halides</subject><subject>heterogeneous ligand</subject><subject>Hirao reaction</subject><subject>Inorganic salts</subject><subject>Nanoparticles</subject><subject>Palladium</subject><subject>Phosphorylation</subject><subject>Recyclability</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFbBj7DgxUvq7KbZZI-l-A8K9aDnZbLZtKlppu4mln57t9arh-ExzI83j8fYrYCJAJAPSHaipgWcsZEArRPIU33ORiBVkUgF2SW7CmEDAFqJ6YiFN2xbrJphy7Gza_Ku4tRx5Ja-sXVdz8mvsGssrz1u3Z78J8cQ72vXO08r1zkaArfYY3sIPa_J892aQhx_aLFvohnVHOPCS0_bpnLhml3U2AZ386dj9vH0-D5_SRbL59f5bJFYqVNIKgl5qbSMCmBVlmdpoQG1tVmqKqwdYq4klGVlVS1TIQqZW-nktCxKLVCkY3Z38t15-hpc6M2GBt_Fl0YqKUSqRQaRuj9R1lMI3tVm55ttDGwEmGOlJlZqjpVGNDmh-6Z1h385M1vOf_kfoHZ44w</recordid><startdate>202201</startdate><enddate>202201</enddate><creator>Chen, Yu‐Xuan</creator><creator>Zhang, Shuo</creator><creator>Xue, Yu‐Jie</creator><creator>Mo, Li‐Ping</creator><creator>Zhang, Zhan‐Hui</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-1252-0375</orcidid><orcidid>https://orcid.org/0000-0002-1082-5773</orcidid><orcidid>https://orcid.org/0000-0003-0966-5116</orcidid><orcidid>https://orcid.org/0000-0001-8149-8987</orcidid><orcidid>https://orcid.org/0000-0002-0663-1984</orcidid></search><sort><creationdate>202201</creationdate><title>Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides</title><author>Chen, Yu‐Xuan ; Zhang, Shuo ; Xue, Yu‐Jie ; Mo, Li‐Ping ; Zhang, Zhan‐Hui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2930-d207b692d2000c65753890a9cc536dafeaa7620bbdc6f2311827c2e24b8b91a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aromatic compounds</topic><topic>Bromides</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>covalent organic framework</topic><topic>deep eutectic solvent</topic><topic>Halides</topic><topic>heterogeneous ligand</topic><topic>Hirao reaction</topic><topic>Inorganic salts</topic><topic>Nanoparticles</topic><topic>Palladium</topic><topic>Phosphorylation</topic><topic>Recyclability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yu‐Xuan</creatorcontrib><creatorcontrib>Zhang, Shuo</creatorcontrib><creatorcontrib>Xue, Yu‐Jie</creatorcontrib><creatorcontrib>Mo, Li‐Ping</creatorcontrib><creatorcontrib>Zhang, Zhan‐Hui</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yu‐Xuan</au><au>Zhang, Shuo</au><au>Xue, Yu‐Jie</au><au>Mo, Li‐Ping</au><au>Zhang, Zhan‐Hui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2022-01</date><risdate>2022</risdate><volume>36</volume><issue>1</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities has been prepared by using deep eutectic solvent (DES) as green media. The as‐synthesized COF was employed as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF nanoparticles catalyst (defined as Pd/TFPT‐Azine‐COF) was found to be an efficient heterogeneous catalyst for the Hirao reaction of aryl halides and dialkyl phosphites or diphenylphosphine oxide with excellent recyclability, reusability, and retention of crystallinity.
A simple azine‐linked covalent organic framework (COF) with high thermal and chemical stabilities was prepared and as heterogeneous ligand for immobilization of PdII. The obtained Pd‐supported COF was found to be an efficient heterogeneous catalyst for phosphorylation of aryl bromides with excellent recyclability, reusability, and retention of crystallinity.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.6480</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0002-1252-0375</orcidid><orcidid>https://orcid.org/0000-0002-1082-5773</orcidid><orcidid>https://orcid.org/0000-0003-0966-5116</orcidid><orcidid>https://orcid.org/0000-0001-8149-8987</orcidid><orcidid>https://orcid.org/0000-0002-0663-1984</orcidid></addata></record> |
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| ispartof | Applied organometallic chemistry, 2022-01, Vol.36 (1), p.n/a |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aromatic compounds Bromides Catalysts Chemistry covalent organic framework deep eutectic solvent Halides heterogeneous ligand Hirao reaction Inorganic salts Nanoparticles Palladium Phosphorylation Recyclability |
| title | Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides |
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