Determining the best flame retardant for rigid polyurethane foam—Tris(2‐chloroisopropyl) phosphate, expandable graphite, or silica aerogel
Although rigid polyurethane foams (RPUFs) have great thermal insulating properties such as its low density, low thermal conductivity, and high compressive strength, they have limited usage because pristine PU foams are highly flammable. Therefore, in order to have widespread applications, much atten...
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| Veröffentlicht in: | Journal of applied polymer science 2022-04, Vol.139 (14), p.n/a |
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| container_title | Journal of applied polymer science |
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| creator | Thong, Ya Xuan Li, Xiaodong Yin, Xi Jiang |
| description | Although rigid polyurethane foams (RPUFs) have great thermal insulating properties such as its low density, low thermal conductivity, and high compressive strength, they have limited usage because pristine PU foams are highly flammable. Therefore, in order to have widespread applications, much attention has been invested in the discovery and study of a vast number of flame retardants. In this work, analysis on the physical, chemical, mechanical, and thermal properties of RPUF composites prepared with industrially‐used flame retardants, namely tris(2‐chloroisopropyl) phosphate (also known as TMCP or TCPP) and expandable graphite (EG), together with the highly promoted silica aerogel, was performed. Taking into account the overall performance, it was found that EG was the best among the three flame retardants investigated. |
| doi_str_mv | 10.1002/app.51888 |
| format | Article |
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Therefore, in order to have widespread applications, much attention has been invested in the discovery and study of a vast number of flame retardants. In this work, analysis on the physical, chemical, mechanical, and thermal properties of RPUF composites prepared with industrially‐used flame retardants, namely tris(2‐chloroisopropyl) phosphate (also known as TMCP or TCPP) and expandable graphite (EG), together with the highly promoted silica aerogel, was performed. Taking into account the overall performance, it was found that EG was the best among the three flame retardants investigated.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.51888</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Compressive strength ; flame retardance ; Flame retardants ; Flammability ; Graphite ; Materials science ; nanoparticles ; nanowires and nanocrystals ; Plastic foam ; Polymers ; Polyurethane foam ; Silica aerogels ; Silicon dioxide ; Thermal conductivity ; thermal properties ; Thermodynamic properties</subject><ispartof>Journal of applied polymer science, 2022-04, Vol.139 (14), p.n/a</ispartof><rights>2021 Wiley Periodicals LLC.</rights><rights>2022 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2978-2b5a874f821c718f7f4a282d0948c831ca3093e3772076297e66f22ead8e38793</citedby><cites>FETCH-LOGICAL-c2978-2b5a874f821c718f7f4a282d0948c831ca3093e3772076297e66f22ead8e38793</cites><orcidid>0000-0002-2253-3241</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.51888$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.51888$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Thong, Ya Xuan</creatorcontrib><creatorcontrib>Li, Xiaodong</creatorcontrib><creatorcontrib>Yin, Xi Jiang</creatorcontrib><title>Determining the best flame retardant for rigid polyurethane foam—Tris(2‐chloroisopropyl) phosphate, expandable graphite, or silica aerogel</title><title>Journal of applied polymer science</title><description>Although rigid polyurethane foams (RPUFs) have great thermal insulating properties such as its low density, low thermal conductivity, and high compressive strength, they have limited usage because pristine PU foams are highly flammable. 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Taking into account the overall performance, it was found that EG was the best among the three flame retardants investigated.</description><subject>Compressive strength</subject><subject>flame retardance</subject><subject>Flame retardants</subject><subject>Flammability</subject><subject>Graphite</subject><subject>Materials science</subject><subject>nanoparticles</subject><subject>nanowires and nanocrystals</subject><subject>Plastic foam</subject><subject>Polymers</subject><subject>Polyurethane foam</subject><subject>Silica aerogels</subject><subject>Silicon dioxide</subject><subject>Thermal conductivity</subject><subject>thermal properties</subject><subject>Thermodynamic properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEtOwzAQQC0EEuWz4AaW2IBEqO20sbOsyleqRBdlHU2TSWPkxsZOBd31BIgFJ-QkuJQtK8szb36PkDPOrjljog_OXQ-5UmqP9DjLZTLIhNonvZjjicrz4SE5CuGFMc6HLOuRjxvs0C91q9sF7RqkcwwdrQ0skXrswFfQxr_11OuFrqizZr2KiQZajGFYfm--Zl6HC_G9-SwbY73VwTpv3dpcUtfY4Bro8Iriu4O2grlBuvDgGr0NxrZBG10CBfR2geaEHNRgAp7-vcfk-e52Nn5IJk_3j-PRJClFLlUi5kNQclArwUvJVS3rAQglKpYPVKlSXkLK8hRTKQWTWSzBLKuFQKgUpkrm6TE53_WNm76u4snFi135No4sRCa2dqK8SF3uqNLbEDzWhfN6CX5dcFZsdRdRd_GrO7L9HfumDa7_B4vRdLqr-AHMU4UI</recordid><startdate>20220410</startdate><enddate>20220410</enddate><creator>Thong, Ya Xuan</creator><creator>Li, Xiaodong</creator><creator>Yin, Xi Jiang</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-2253-3241</orcidid></search><sort><creationdate>20220410</creationdate><title>Determining the best flame retardant for rigid polyurethane foam—Tris(2‐chloroisopropyl) phosphate, expandable graphite, or silica aerogel</title><author>Thong, Ya Xuan ; Li, Xiaodong ; Yin, Xi Jiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2978-2b5a874f821c718f7f4a282d0948c831ca3093e3772076297e66f22ead8e38793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Compressive strength</topic><topic>flame retardance</topic><topic>Flame retardants</topic><topic>Flammability</topic><topic>Graphite</topic><topic>Materials science</topic><topic>nanoparticles</topic><topic>nanowires and nanocrystals</topic><topic>Plastic foam</topic><topic>Polymers</topic><topic>Polyurethane foam</topic><topic>Silica aerogels</topic><topic>Silicon dioxide</topic><topic>Thermal conductivity</topic><topic>thermal properties</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thong, Ya Xuan</creatorcontrib><creatorcontrib>Li, Xiaodong</creatorcontrib><creatorcontrib>Yin, Xi Jiang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thong, Ya Xuan</au><au>Li, Xiaodong</au><au>Yin, Xi Jiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determining the best flame retardant for rigid polyurethane foam—Tris(2‐chloroisopropyl) phosphate, expandable graphite, or silica aerogel</atitle><jtitle>Journal of applied polymer science</jtitle><date>2022-04-10</date><risdate>2022</risdate><volume>139</volume><issue>14</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>Although rigid polyurethane foams (RPUFs) have great thermal insulating properties such as its low density, low thermal conductivity, and high compressive strength, they have limited usage because pristine PU foams are highly flammable. 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| subjects | Compressive strength flame retardance Flame retardants Flammability Graphite Materials science nanoparticles nanowires and nanocrystals Plastic foam Polymers Polyurethane foam Silica aerogels Silicon dioxide Thermal conductivity thermal properties Thermodynamic properties |
| title | Determining the best flame retardant for rigid polyurethane foam—Tris(2‐chloroisopropyl) phosphate, expandable graphite, or silica aerogel |
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