Hydrogen-Induced Martensitic Transformation and Twinning in Fe45Mn35Cr10Co10
Hydrogen embrittlement can occur in steels with metastable phases, due to activation of the hydrogen-enhanced decohesion mechanism upon transformation. Meanwhile, recent investigations suggest that alloys undergoing ε -martensite transformation may exhibit resistance to hydrogen embrittlement. To be...
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| Veröffentlicht in: | Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2022-02, Vol.53 (2), p.432-448 |
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| container_title | Metallurgical and materials transactions. A, Physical metallurgy and materials science |
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| creator | Ronchi, M. R. Yan, H. Tasan, C. C. |
| description | Hydrogen embrittlement can occur in steels with metastable phases, due to activation of the hydrogen-enhanced decohesion mechanism upon transformation. Meanwhile, recent investigations suggest that alloys undergoing
ε
-martensite transformation may exhibit resistance to hydrogen embrittlement. To better understand hydrogen effects in these alloys, we investigate the hydrogen-induced microstructural transformations in a metastable Fe
45
Mn
35
Co
10
Cr
10
alloy. To this end, we electrochemically charge unstrained samples, quantify the hydrogen evolution by thermal desorption spectroscopy, and observe microstructural transformations by scanning electron microscopy techniques. Through these analyses, we find that the hydrogen-induced
ε
-martensite formation is dependent on the crystallographic orientation of the austenite grains, and takes place preferentially along Σ3 boundaries. Further charging of hydrogen induces extension twinning within the martensite. We examine the microstructural factors influencing these transformations to better understand the hydrogen-microstructure interactions.
Graphical Abstract |
| doi_str_mv | 10.1007/s11661-021-06498-w |
| format | Article |
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ε
-martensite transformation may exhibit resistance to hydrogen embrittlement. To better understand hydrogen effects in these alloys, we investigate the hydrogen-induced microstructural transformations in a metastable Fe
45
Mn
35
Co
10
Cr
10
alloy. To this end, we electrochemically charge unstrained samples, quantify the hydrogen evolution by thermal desorption spectroscopy, and observe microstructural transformations by scanning electron microscopy techniques. Through these analyses, we find that the hydrogen-induced
ε
-martensite formation is dependent on the crystallographic orientation of the austenite grains, and takes place preferentially along Σ3 boundaries. Further charging of hydrogen induces extension twinning within the martensite. We examine the microstructural factors influencing these transformations to better understand the hydrogen-microstructure interactions.
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ε
-martensite transformation may exhibit resistance to hydrogen embrittlement. To better understand hydrogen effects in these alloys, we investigate the hydrogen-induced microstructural transformations in a metastable Fe
45
Mn
35
Co
10
Cr
10
alloy. To this end, we electrochemically charge unstrained samples, quantify the hydrogen evolution by thermal desorption spectroscopy, and observe microstructural transformations by scanning electron microscopy techniques. Through these analyses, we find that the hydrogen-induced
ε
-martensite formation is dependent on the crystallographic orientation of the austenite grains, and takes place preferentially along Σ3 boundaries. Further charging of hydrogen induces extension twinning within the martensite. We examine the microstructural factors influencing these transformations to better understand the hydrogen-microstructure interactions.
Graphical Abstract</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Crystallography</subject><subject>Heat treating</subject><subject>Hydrogen</subject><subject>Hydrogen embrittlement</subject><subject>Hydrogen evolution</subject><subject>Martensite</subject><subject>Martensitic transformations</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Metastable phases</subject><subject>Microstructure</subject><subject>Nanotechnology</subject><subject>Original Research Article</subject><subject>Structural Materials</subject><subject>Surfaces and Interfaces</subject><subject>Thermal desorption spectroscopy</subject><subject>Thin Films</subject><subject>Twinning</subject><issn>1073-5623</issn><issn>1543-1940</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wNOC5-jkY7PJURZrCy1e6jnEbFJSbLYmW0r_vbErePMwzDC873w8CN0TeCQAzVMmRAiCgZYQXEl8vEATUnOGieJwWWpoGK4FZdfoJuctABDFxAQt56cu9RsX8SJ2B-u6amXS4GIOQ7DVOpmYfZ92Zgh9rEzsqvUxxBjipgqxmjleryKr20Sg7QncoitvPrO7-81T9D57WbdzvHx7XbTPS2yZYANWSn2UawVtGgedlOCpFQKEsd4Ly5WVUNqey_KA9UQawrxTTNYdp9ZJy6boYZy7T_3XweVBb_tDimWlpoIoJTgVTVHRUWVTn3NyXu9T2Jl00gT0DzU9UtOFmj5T08diYqMpF3HcuPQ3-h_XN6z8bn0</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Ronchi, M. 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R. ; Yan, H. ; Tasan, C. C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-999b6616277e0d880f2c6606acff6c49c800d8f48154cf18a13fe9385d42ce8c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Crystallography</topic><topic>Heat treating</topic><topic>Hydrogen</topic><topic>Hydrogen embrittlement</topic><topic>Hydrogen evolution</topic><topic>Martensite</topic><topic>Martensitic transformations</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Metastable phases</topic><topic>Microstructure</topic><topic>Nanotechnology</topic><topic>Original Research Article</topic><topic>Structural Materials</topic><topic>Surfaces and Interfaces</topic><topic>Thermal desorption spectroscopy</topic><topic>Thin Films</topic><topic>Twinning</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ronchi, M. 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A, Physical metallurgy and materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ronchi, M. R.</au><au>Yan, H.</au><au>Tasan, C. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen-Induced Martensitic Transformation and Twinning in Fe45Mn35Cr10Co10</atitle><jtitle>Metallurgical and materials transactions. A, Physical metallurgy and materials science</jtitle><stitle>Metall Mater Trans A</stitle><date>2022-02-01</date><risdate>2022</risdate><volume>53</volume><issue>2</issue><spage>432</spage><epage>448</epage><pages>432-448</pages><issn>1073-5623</issn><eissn>1543-1940</eissn><abstract>Hydrogen embrittlement can occur in steels with metastable phases, due to activation of the hydrogen-enhanced decohesion mechanism upon transformation. Meanwhile, recent investigations suggest that alloys undergoing
ε
-martensite transformation may exhibit resistance to hydrogen embrittlement. To better understand hydrogen effects in these alloys, we investigate the hydrogen-induced microstructural transformations in a metastable Fe
45
Mn
35
Co
10
Cr
10
alloy. To this end, we electrochemically charge unstrained samples, quantify the hydrogen evolution by thermal desorption spectroscopy, and observe microstructural transformations by scanning electron microscopy techniques. Through these analyses, we find that the hydrogen-induced
ε
-martensite formation is dependent on the crystallographic orientation of the austenite grains, and takes place preferentially along Σ3 boundaries. Further charging of hydrogen induces extension twinning within the martensite. We examine the microstructural factors influencing these transformations to better understand the hydrogen-microstructure interactions.
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Crystallography Heat treating Hydrogen Hydrogen embrittlement Hydrogen evolution Martensite Martensitic transformations Materials Science Metallic Materials Metastable phases Microstructure Nanotechnology Original Research Article Structural Materials Surfaces and Interfaces Thermal desorption spectroscopy Thin Films Twinning |
| title | Hydrogen-Induced Martensitic Transformation and Twinning in Fe45Mn35Cr10Co10 |
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