Transient chronoamperometric current at rotating disc electrode for second-order ECE reactions

Dimensionless current versus potential for various values of parameters. [Display omitted] •Approximate analytical expression of the concentration profile.•Explicit closed formulation of the limiting current for a uniformly accessible rotating disc electrode (RDE).•Sensitivity analysis of parameters...

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Veröffentlicht in:	Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2021-12, Vol.902, p.115775, Article 115775
Hauptverfasser:	Manimegalai, B., Lyons, Michael E.G., Rajendran, L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Constraining Diffusion layers Diffusion rate Homotopy perturbation method Non-linear reaction-diffusion equation Nonlinear equations Parameter sensitivity Perturbation methods Physical properties Reaction-diffusion equations Rotating disk electrode Rotating disks Second-order ECE reaction Sensitivity analysis Thickness
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