Catalytic Oxidation of Ethylene in Solutions of Palladium(II) Cationic Complexes in Binary and Ternary Aqueous Organic Solvents
The effect of organic solvents on the rate of ethylene oxidation with p -benzoquinone to acetaldehyde in aqueous organic solutions of palladium cationic complexes has been studied. It was found that the reaction rate increased when the acceptor number of the solvent increased and the donor number de...
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| Veröffentlicht in: | Kinetics and catalysis 2021-11, Vol.62 (6), p.734-743 |
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| container_title | Kinetics and catalysis |
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| creator | Oshanina, I. V. Podtyagina, A. V. Pestunova, U. V. Rusnak, I. N. Temkin, O. N. |
| description | The effect of organic solvents on the rate of ethylene oxidation with
p
-benzoquinone to acetaldehyde in aqueous organic solutions of palladium cationic complexes has been studied. It was found that the reaction rate increased when the acceptor number of the solvent increased and the donor number decreased. The oxidation of ethylene and cyclohexene in binary (
N
-methylpyrrolidone–H
2
O) and ternary (acetonitrile–
N
-methylpyrrolidone–H
2
O) solvents was studied in more detail. In contrast to the acetonitrile–Н
2
О system, in the
N
-methylpyrrolidone–Н
2
О binary solvent hydrogen peroxide oxidizes ethylene to acetaldehyde in the presence of Pd(II) cationic complexes. The use of a solvent
N
-methylpyrrolidone acceptable for cyclohexene (CH) oxidation technology leads to a decrease in the rate and selectivity of cyclohexanone synthesis. |
| doi_str_mv | 10.1134/S0023158421060148 |
| format | Article |
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p
-benzoquinone to acetaldehyde in aqueous organic solutions of palladium cationic complexes has been studied. It was found that the reaction rate increased when the acceptor number of the solvent increased and the donor number decreased. The oxidation of ethylene and cyclohexene in binary (
N
-methylpyrrolidone–H
2
O) and ternary (acetonitrile–
N
-methylpyrrolidone–H
2
O) solvents was studied in more detail. In contrast to the acetonitrile–Н
2
О system, in the
N
-methylpyrrolidone–Н
2
О binary solvent hydrogen peroxide oxidizes ethylene to acetaldehyde in the presence of Pd(II) cationic complexes. The use of a solvent
N
-methylpyrrolidone acceptable for cyclohexene (CH) oxidation technology leads to a decrease in the rate and selectivity of cyclohexanone synthesis.</description><identifier>ISSN: 0023-1584</identifier><identifier>EISSN: 1608-3210</identifier><identifier>DOI: 10.1134/S0023158421060148</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acetaldehyde ; Acetonitrile ; Benzoquinone ; Catalysis ; Catalytic oxidation ; Cations ; Chemistry ; Chemistry and Materials Science ; Cyclohexanone ; Cyclohexene ; Ethylene ; Hydrogen peroxide ; Oxidation ; Palladium ; Physical Chemistry ; Selectivity ; Solvents</subject><ispartof>Kinetics and catalysis, 2021-11, Vol.62 (6), p.734-743</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0023-1584, Kinetics and Catalysis, 2021, Vol. 62, No. 6, pp. 734–743. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Kinetika i Kataliz, 2021, Vol. 62, No. 6, pp. 694–705.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-51e9c3464f5b4d9575ca463633e9b8b7def57c8ac4bff7f9dbd40ba88da68753</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0023158421060148$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0023158421060148$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Oshanina, I. V.</creatorcontrib><creatorcontrib>Podtyagina, A. V.</creatorcontrib><creatorcontrib>Pestunova, U. V.</creatorcontrib><creatorcontrib>Rusnak, I. N.</creatorcontrib><creatorcontrib>Temkin, O. N.</creatorcontrib><title>Catalytic Oxidation of Ethylene in Solutions of Palladium(II) Cationic Complexes in Binary and Ternary Aqueous Organic Solvents</title><title>Kinetics and catalysis</title><addtitle>Kinet Catal</addtitle><description>The effect of organic solvents on the rate of ethylene oxidation with
p
-benzoquinone to acetaldehyde in aqueous organic solutions of palladium cationic complexes has been studied. It was found that the reaction rate increased when the acceptor number of the solvent increased and the donor number decreased. The oxidation of ethylene and cyclohexene in binary (
N
-methylpyrrolidone–H
2
O) and ternary (acetonitrile–
N
-methylpyrrolidone–H
2
O) solvents was studied in more detail. In contrast to the acetonitrile–Н
2
О system, in the
N
-methylpyrrolidone–Н
2
О binary solvent hydrogen peroxide oxidizes ethylene to acetaldehyde in the presence of Pd(II) cationic complexes. The use of a solvent
N
-methylpyrrolidone acceptable for cyclohexene (CH) oxidation technology leads to a decrease in the rate and selectivity of cyclohexanone synthesis.</description><subject>Acetaldehyde</subject><subject>Acetonitrile</subject><subject>Benzoquinone</subject><subject>Catalysis</subject><subject>Catalytic oxidation</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cyclohexanone</subject><subject>Cyclohexene</subject><subject>Ethylene</subject><subject>Hydrogen peroxide</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Solvents</subject><issn>0023-1584</issn><issn>1608-3210</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kF9LwzAUxYMoOKcfwLeAL_pQTZo_TR9nmToQJmzvJW2S2ZE1M2lle_Krm26CD-LTvdxzfofDBeAao3uMCX1YIJQSzARNMeIIU3ECRpgjkZB4OAWjQU4G_RxchLBGCFFM8xH4KmQn7b5rajjfNUp2jWuhM3Dave-tbjVsWrhwth_uYRDepLVSNf3mdja7g8UBiHDhNlurdzoMwGPTSr-HslVwqf1hn3z02vUBzv1KDv6Y-anbLlyCMyNt0Fc_cwyWT9Nl8ZK8zp9nxeQ1qVMuuoRhndeEcmpYRVXOMlZLygknROeVqDKlDctqIWtaGZOZXFWKokoKoSQXGSNjcHOM3XoXm4SuXLs-NrOhTDkWjBDC8ujCR1ftXQhem3Lrm02sX2JUDm8u_7w5MumRCdHbrrT_Tf4f-gbB8oAa</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Oshanina, I. V.</creator><creator>Podtyagina, A. V.</creator><creator>Pestunova, U. V.</creator><creator>Rusnak, I. N.</creator><creator>Temkin, O. N.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211101</creationdate><title>Catalytic Oxidation of Ethylene in Solutions of Palladium(II) Cationic Complexes in Binary and Ternary Aqueous Organic Solvents</title><author>Oshanina, I. V. ; Podtyagina, A. V. ; Pestunova, U. V. ; Rusnak, I. N. ; Temkin, O. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-51e9c3464f5b4d9575ca463633e9b8b7def57c8ac4bff7f9dbd40ba88da68753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetaldehyde</topic><topic>Acetonitrile</topic><topic>Benzoquinone</topic><topic>Catalysis</topic><topic>Catalytic oxidation</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cyclohexanone</topic><topic>Cyclohexene</topic><topic>Ethylene</topic><topic>Hydrogen peroxide</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oshanina, I. V.</creatorcontrib><creatorcontrib>Podtyagina, A. V.</creatorcontrib><creatorcontrib>Pestunova, U. V.</creatorcontrib><creatorcontrib>Rusnak, I. N.</creatorcontrib><creatorcontrib>Temkin, O. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Kinetics and catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oshanina, I. V.</au><au>Podtyagina, A. V.</au><au>Pestunova, U. V.</au><au>Rusnak, I. N.</au><au>Temkin, O. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Oxidation of Ethylene in Solutions of Palladium(II) Cationic Complexes in Binary and Ternary Aqueous Organic Solvents</atitle><jtitle>Kinetics and catalysis</jtitle><stitle>Kinet Catal</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>62</volume><issue>6</issue><spage>734</spage><epage>743</epage><pages>734-743</pages><issn>0023-1584</issn><eissn>1608-3210</eissn><abstract>The effect of organic solvents on the rate of ethylene oxidation with
p
-benzoquinone to acetaldehyde in aqueous organic solutions of palladium cationic complexes has been studied. It was found that the reaction rate increased when the acceptor number of the solvent increased and the donor number decreased. The oxidation of ethylene and cyclohexene in binary (
N
-methylpyrrolidone–H
2
O) and ternary (acetonitrile–
N
-methylpyrrolidone–H
2
O) solvents was studied in more detail. In contrast to the acetonitrile–Н
2
О system, in the
N
-methylpyrrolidone–Н
2
О binary solvent hydrogen peroxide oxidizes ethylene to acetaldehyde in the presence of Pd(II) cationic complexes. The use of a solvent
N
-methylpyrrolidone acceptable for cyclohexene (CH) oxidation technology leads to a decrease in the rate and selectivity of cyclohexanone synthesis.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0023158421060148</doi><tpages>10</tpages></addata></record> |
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| language | eng |
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| subjects | Acetaldehyde Acetonitrile Benzoquinone Catalysis Catalytic oxidation Cations Chemistry Chemistry and Materials Science Cyclohexanone Cyclohexene Ethylene Hydrogen peroxide Oxidation Palladium Physical Chemistry Selectivity Solvents |
| title | Catalytic Oxidation of Ethylene in Solutions of Palladium(II) Cationic Complexes in Binary and Ternary Aqueous Organic Solvents |
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