Proton-conducting phosphate glass: Recent development as an electrolyte in intermediate temperature fuel cells
Recently, it has been reported that phosphate glasses with high proton conductivity in the intermediate temperature range have been successfully developed using a proton carrier injection technique with a high concentration for electrochemical ion substitution. In this review, we summarize the chara...
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Veröffentlicht in: | Journal of the Ceramic Society of Japan 2022/01/01, Vol.130(1), pp.1-9 |
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description | Recently, it has been reported that phosphate glasses with high proton conductivity in the intermediate temperature range have been successfully developed using a proton carrier injection technique with a high concentration for electrochemical ion substitution. In this review, we summarize the characteristics of the bonding states between protons and oxygen in phosphates and the concepts of material design for achieving high proton conductivity in phosphate materials. This paper introduces a carrier proton injection technique called the alkali-proton substitution (APS) method, which was developed as a process for increasing the concentration of proton carriers and required a breakthrough in the conventional approach to the development of phosphate-glass-based proton conductors. Additionally, the knowledge obtained regarding the correlations between glass components, glass structure, and proton mobility is summarized. This paper also describes the characteristics of proton-conductive phosphate glasses prepared using the APS method, demonstrating that they have the unique property of being able to carry only protons as charge carriers in any atmosphere. In conclusion, future strategies for improving proton conductivity and the potential for developing new applications are discussed. |
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In this review, we summarize the characteristics of the bonding states between protons and oxygen in phosphates and the concepts of material design for achieving high proton conductivity in phosphate materials. This paper introduces a carrier proton injection technique called the alkali-proton substitution (APS) method, which was developed as a process for increasing the concentration of proton carriers and required a breakthrough in the conventional approach to the development of phosphate-glass-based proton conductors. Additionally, the knowledge obtained regarding the correlations between glass components, glass structure, and proton mobility is summarized. This paper also describes the characteristics of proton-conductive phosphate glasses prepared using the APS method, demonstrating that they have the unique property of being able to carry only protons as charge carriers in any atmosphere. In conclusion, future strategies for improving proton conductivity and the potential for developing new applications are discussed.</description><identifier>ISSN: 1882-0743</identifier><identifier>EISSN: 1348-6535</identifier><identifier>DOI: 10.2109/jcersj2.21110</identifier><language>eng</language><publisher>Tokyo: The Ceramic Society of Japan</publisher><subject>Alkali-proton substitution ; Carrier density ; Carrier injection ; Conduction ; Conductors ; Current carriers ; Electrolytic cells ; Fuel cell ; Fuel cells ; O–H bond ; Phosphate glass ; Phosphates ; Proton conductivity ; Protons ; Substitutes</subject><ispartof>Journal of the Ceramic Society of Japan, 2022/01/01, Vol.130(1), pp.1-9</ispartof><rights>2022 The Ceramic Society of Japan</rights><rights>2022. This work is published under https://creativecommons.org/licenses/by-nd/4.0/deed.ja (the “License”). 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Ceram. Soc. Japan</addtitle><description>Recently, it has been reported that phosphate glasses with high proton conductivity in the intermediate temperature range have been successfully developed using a proton carrier injection technique with a high concentration for electrochemical ion substitution. In this review, we summarize the characteristics of the bonding states between protons and oxygen in phosphates and the concepts of material design for achieving high proton conductivity in phosphate materials. This paper introduces a carrier proton injection technique called the alkali-proton substitution (APS) method, which was developed as a process for increasing the concentration of proton carriers and required a breakthrough in the conventional approach to the development of phosphate-glass-based proton conductors. Additionally, the knowledge obtained regarding the correlations between glass components, glass structure, and proton mobility is summarized. This paper also describes the characteristics of proton-conductive phosphate glasses prepared using the APS method, demonstrating that they have the unique property of being able to carry only protons as charge carriers in any atmosphere. In conclusion, future strategies for improving proton conductivity and the potential for developing new applications are discussed.</description><subject>Alkali-proton substitution</subject><subject>Carrier density</subject><subject>Carrier injection</subject><subject>Conduction</subject><subject>Conductors</subject><subject>Current carriers</subject><subject>Electrolytic cells</subject><subject>Fuel cell</subject><subject>Fuel cells</subject><subject>O–H bond</subject><subject>Phosphate glass</subject><subject>Phosphates</subject><subject>Proton conductivity</subject><subject>Protons</subject><subject>Substitutes</subject><issn>1882-0743</issn><issn>1348-6535</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNo9kMtLxDAQxoMouK4evQc8V_Nom9SbLOsDFhTRc0jT6W5LNqlJKvjf232wMMyD-X0z8CF0S8k9o6R66A2E2LNpoJScoRnluczKghfnUy8ly4jI-SW6irEnpGQ5lzPkPoJP3mXGu2Y0qXNrPGx8HDY6AV5bHeMj_gQDLuEGfsH6YbvrdcTaYbBgUvD2b2I7N0WCsIWm22kTbAcIOo0BcDuCxQasjdfootU2ws2xztH38_Jr8Zqt3l_eFk-rzOSySlnLjSHCQFk2OSs5yU0BraxrLqEGLmhlRFuTSleGN7WuBK1F3VLBKs4Yg0bzObo73B2C_xkhJtX7MbjppWIlLURRlrmcqOxAmeBjDNCqIXRbHf4UJWpnqTpaqvaWTvzywPcx6TWcaB1SZyycaMqJovu81532ZqODAsf_AaXzhlY</recordid><startdate>20220101</startdate><enddate>20220101</enddate><creator>ISHIYAMA, Tomohiro</creator><creator>YAMAGUCHI, Takuya</creator><creator>OMATA, Takahisa</creator><general>The Ceramic Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220101</creationdate><title>Proton-conducting phosphate glass: Recent development as an electrolyte in intermediate temperature fuel cells</title><author>ISHIYAMA, Tomohiro ; YAMAGUCHI, Takuya ; OMATA, Takahisa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c489t-f3cc07ce66d426304c5ef8bb38ebe3719c7fb09a9c3dba971b7bf17293222eda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkali-proton substitution</topic><topic>Carrier density</topic><topic>Carrier injection</topic><topic>Conduction</topic><topic>Conductors</topic><topic>Current carriers</topic><topic>Electrolytic cells</topic><topic>Fuel cell</topic><topic>Fuel cells</topic><topic>O–H bond</topic><topic>Phosphate glass</topic><topic>Phosphates</topic><topic>Proton conductivity</topic><topic>Protons</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ISHIYAMA, Tomohiro</creatorcontrib><creatorcontrib>YAMAGUCHI, Takuya</creatorcontrib><creatorcontrib>OMATA, Takahisa</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Ceramic Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ISHIYAMA, Tomohiro</au><au>YAMAGUCHI, Takuya</au><au>OMATA, Takahisa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Proton-conducting phosphate glass: Recent development as an electrolyte in intermediate temperature fuel cells</atitle><jtitle>Journal of the Ceramic Society of Japan</jtitle><addtitle>J. Ceram. Soc. Japan</addtitle><date>2022-01-01</date><risdate>2022</risdate><volume>130</volume><issue>1</issue><spage>1</spage><epage>9</epage><pages>1-9</pages><artnum>21110</artnum><issn>1882-0743</issn><eissn>1348-6535</eissn><abstract>Recently, it has been reported that phosphate glasses with high proton conductivity in the intermediate temperature range have been successfully developed using a proton carrier injection technique with a high concentration for electrochemical ion substitution. In this review, we summarize the characteristics of the bonding states between protons and oxygen in phosphates and the concepts of material design for achieving high proton conductivity in phosphate materials. This paper introduces a carrier proton injection technique called the alkali-proton substitution (APS) method, which was developed as a process for increasing the concentration of proton carriers and required a breakthrough in the conventional approach to the development of phosphate-glass-based proton conductors. Additionally, the knowledge obtained regarding the correlations between glass components, glass structure, and proton mobility is summarized. This paper also describes the characteristics of proton-conductive phosphate glasses prepared using the APS method, demonstrating that they have the unique property of being able to carry only protons as charge carriers in any atmosphere. In conclusion, future strategies for improving proton conductivity and the potential for developing new applications are discussed.</abstract><cop>Tokyo</cop><pub>The Ceramic Society of Japan</pub><doi>10.2109/jcersj2.21110</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Alkali-proton substitution Carrier density Carrier injection Conduction Conductors Current carriers Electrolytic cells Fuel cell Fuel cells O–H bond Phosphate glass Phosphates Proton conductivity Protons Substitutes |
title | Proton-conducting phosphate glass: Recent development as an electrolyte in intermediate temperature fuel cells |
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