Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions

An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2022-01, Vol.51 (1), p.38-40
Hauptverfasser: Asako, Sobi, Takahashi, Ikko, Kurogi, Takashi, Murakami, Yoshiaki, Ilies, Laurean, Takai, Kazuhiko
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 40
container_issue 1
container_start_page 38
container_title Chemistry letters
container_volume 51
creator Asako, Sobi
Takahashi, Ikko
Kurogi, Takashi
Murakami, Yoshiaki
Ilies, Laurean
Takai, Kazuhiko
description An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.
doi_str_mv 10.1246/cl.210546
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2615755733</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2615755733</sourcerecordid><originalsourceid>FETCH-LOGICAL-c460t-8ed9a7fb72c2fc1a6baa53f13e4e7d0c54884a32ac642180c6fe39fcf58d983e3</originalsourceid><addsrcrecordid>eNplkMtOAjEARRujiYgu_IMmrlwM9j2dJYIPEgiJynpS-pCSoR1bZsHfOwQSF67u5txzkwvAPUYjTJh40s2IYMSZuAADTJksUIn5JRggKkRRIkKuwU3OW4SQrCgZgOWzT3oDP6zp9N7HAKOD42SDzXCVffiGn9H4bgenPrc25SOhgoHTxQx2wdgEF74xcBKD8cd6vgVXTjXZ3p1zCFavL1-T92K-fJtNxvNCM4H2hbSmUqVbl0QTp7ESa6U4dZhaZkuDNGdSMkWJ0oIRLJEWztLKacelqSS1dAgeTt42xZ_O5n29jV0K_WRNBOYl5yWlPfV4onSKOSfr6jb5nUqHGqP6-Fetm_r0V8-KM7uxO697U9Te7g9b1arwZ_9f_AUjG2-B</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2615755733</pqid></control><display><type>article</type><title>Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Asako, Sobi ; Takahashi, Ikko ; Kurogi, Takashi ; Murakami, Yoshiaki ; Ilies, Laurean ; Takai, Kazuhiko</creator><creatorcontrib>Asako, Sobi ; Takahashi, Ikko ; Kurogi, Takashi ; Murakami, Yoshiaki ; Ilies, Laurean ; Takai, Kazuhiko</creatorcontrib><description>An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.210546</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Aromatic compounds ; Carboxylic acids ; Dispersion ; Paraffins ; Reduction ; Selectivity ; Sodium</subject><ispartof>Chemistry letters, 2022-01, Vol.51 (1), p.38-40</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Chemical Society of Japan 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c460t-8ed9a7fb72c2fc1a6baa53f13e4e7d0c54884a32ac642180c6fe39fcf58d983e3</citedby><cites>FETCH-LOGICAL-c460t-8ed9a7fb72c2fc1a6baa53f13e4e7d0c54884a32ac642180c6fe39fcf58d983e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Asako, Sobi</creatorcontrib><creatorcontrib>Takahashi, Ikko</creatorcontrib><creatorcontrib>Kurogi, Takashi</creatorcontrib><creatorcontrib>Murakami, Yoshiaki</creatorcontrib><creatorcontrib>Ilies, Laurean</creatorcontrib><creatorcontrib>Takai, Kazuhiko</creatorcontrib><title>Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions</title><title>Chemistry letters</title><description>An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.</description><subject>Aromatic compounds</subject><subject>Carboxylic acids</subject><subject>Dispersion</subject><subject>Paraffins</subject><subject>Reduction</subject><subject>Selectivity</subject><subject>Sodium</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNplkMtOAjEARRujiYgu_IMmrlwM9j2dJYIPEgiJynpS-pCSoR1bZsHfOwQSF67u5txzkwvAPUYjTJh40s2IYMSZuAADTJksUIn5JRggKkRRIkKuwU3OW4SQrCgZgOWzT3oDP6zp9N7HAKOD42SDzXCVffiGn9H4bgenPrc25SOhgoHTxQx2wdgEF74xcBKD8cd6vgVXTjXZ3p1zCFavL1-T92K-fJtNxvNCM4H2hbSmUqVbl0QTp7ESa6U4dZhaZkuDNGdSMkWJ0oIRLJEWztLKacelqSS1dAgeTt42xZ_O5n29jV0K_WRNBOYl5yWlPfV4onSKOSfr6jb5nUqHGqP6-Fetm_r0V8-KM7uxO697U9Te7g9b1arwZ_9f_AUjG2-B</recordid><startdate>20220101</startdate><enddate>20220101</enddate><creator>Asako, Sobi</creator><creator>Takahashi, Ikko</creator><creator>Kurogi, Takashi</creator><creator>Murakami, Yoshiaki</creator><creator>Ilies, Laurean</creator><creator>Takai, Kazuhiko</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220101</creationdate><title>Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions</title><author>Asako, Sobi ; Takahashi, Ikko ; Kurogi, Takashi ; Murakami, Yoshiaki ; Ilies, Laurean ; Takai, Kazuhiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c460t-8ed9a7fb72c2fc1a6baa53f13e4e7d0c54884a32ac642180c6fe39fcf58d983e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aromatic compounds</topic><topic>Carboxylic acids</topic><topic>Dispersion</topic><topic>Paraffins</topic><topic>Reduction</topic><topic>Selectivity</topic><topic>Sodium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Asako, Sobi</creatorcontrib><creatorcontrib>Takahashi, Ikko</creatorcontrib><creatorcontrib>Kurogi, Takashi</creatorcontrib><creatorcontrib>Murakami, Yoshiaki</creatorcontrib><creatorcontrib>Ilies, Laurean</creatorcontrib><creatorcontrib>Takai, Kazuhiko</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Asako, Sobi</au><au>Takahashi, Ikko</au><au>Kurogi, Takashi</au><au>Murakami, Yoshiaki</au><au>Ilies, Laurean</au><au>Takai, Kazuhiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions</atitle><jtitle>Chemistry letters</jtitle><date>2022-01-01</date><risdate>2022</risdate><volume>51</volume><issue>1</issue><spage>38</spage><epage>40</epage><pages>38-40</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.210546</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2022-01, Vol.51 (1), p.38-40
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_journals_2615755733
source Oxford University Press Journals All Titles (1996-Current)
subjects Aromatic compounds
Carboxylic acids
Dispersion
Paraffins
Reduction
Selectivity
Sodium
title Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T20%3A49%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Birch%20Reduction%20of%20Arenes%20Using%20Sodium%20Dispersion%20and%20DMI%20under%20Mild%20Conditions&rft.jtitle=Chemistry%20letters&rft.au=Asako,%20Sobi&rft.date=2022-01-01&rft.volume=51&rft.issue=1&rft.spage=38&rft.epage=40&rft.pages=38-40&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.210546&rft_dat=%3Cproquest_cross%3E2615755733%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2615755733&rft_id=info:pmid/&rfr_iscdi=true