Effects of soil components, solution chemical properties, and temperature on Cu(II) adsorption by alluvial acid soil: a case study in Southwest China

Soil components, solution chemical properties, and temperature are important factors that affect Cu(II) adsorption in soil. However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, an...

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Veröffentlicht in:Arabian journal of geosciences 2022, Vol.15 (1), Article 70
Hauptverfasser: Ren, Bangzheng, Wu, Yong, Li, Hongtao, Chen, Zailin, Xu, Junlong
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Chen, Zailin
Xu, Junlong
description Soil components, solution chemical properties, and temperature are important factors that affect Cu(II) adsorption in soil. However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, and Mn oxides were selectively removed by washing the bulk soil and the clay fraction with H 2 O 2 , Na 3 C 6 H 5 O 7 ·2H 2 O + NaHCO 3  + Na 2 S 2 O 4 , and HONH 3 Cl. Adsorption experiment results indicate that Cu(II) adsorption decreased for bulk soil and clay fractions after removing organic matter and Mn oxides. However, after free Fe oxides were removed, the Cu(II) adsorption increased for bulk soil and clay fractions. The adsorption capacity of the clay fraction for Cu(II) was higher than that of the bulk soil irrespective of the selective chemical extraction treatment. When the initial pH increased from 2 to 3.5, the adsorption capacity increased rapidly; when the pH > 6, the adsorption capacity did not change significantly. When the pH was greater than 6, increased Cu(II) adsorption may occur due to the precipitation of Cu(II). Increased ionic strength can inhibit Cu(II) adsorption. The effects of foreign ions on Cu(II) adsorption were in the order Na +  
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However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, and Mn oxides were selectively removed by washing the bulk soil and the clay fraction with H 2 O 2 , Na 3 C 6 H 5 O 7 ·2H 2 O + NaHCO 3  + Na 2 S 2 O 4 , and HONH 3 Cl. Adsorption experiment results indicate that Cu(II) adsorption decreased for bulk soil and clay fractions after removing organic matter and Mn oxides. However, after free Fe oxides were removed, the Cu(II) adsorption increased for bulk soil and clay fractions. The adsorption capacity of the clay fraction for Cu(II) was higher than that of the bulk soil irrespective of the selective chemical extraction treatment. When the initial pH increased from 2 to 3.5, the adsorption capacity increased rapidly; when the pH &gt; 6, the adsorption capacity did not change significantly. When the pH was greater than 6, increased Cu(II) adsorption may occur due to the precipitation of Cu(II). Increased ionic strength can inhibit Cu(II) adsorption. The effects of foreign ions on Cu(II) adsorption were in the order Na +  &lt; K +  &lt; Mg 2+  &lt; Ca 2+ for cations and NO 3 −  &lt; SO 4 2− ≈ Cl − for anions. 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However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, and Mn oxides were selectively removed by washing the bulk soil and the clay fraction with H 2 O 2 , Na 3 C 6 H 5 O 7 ·2H 2 O + NaHCO 3  + Na 2 S 2 O 4 , and HONH 3 Cl. Adsorption experiment results indicate that Cu(II) adsorption decreased for bulk soil and clay fractions after removing organic matter and Mn oxides. However, after free Fe oxides were removed, the Cu(II) adsorption increased for bulk soil and clay fractions. The adsorption capacity of the clay fraction for Cu(II) was higher than that of the bulk soil irrespective of the selective chemical extraction treatment. When the initial pH increased from 2 to 3.5, the adsorption capacity increased rapidly; when the pH &gt; 6, the adsorption capacity did not change significantly. When the pH was greater than 6, increased Cu(II) adsorption may occur due to the precipitation of Cu(II). Increased ionic strength can inhibit Cu(II) adsorption. The effects of foreign ions on Cu(II) adsorption were in the order Na +  &lt; K +  &lt; Mg 2+  &lt; Ca 2+ for cations and NO 3 −  &lt; SO 4 2− ≈ Cl − for anions. 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However, the research in this area is currently lacking. In this study, the clay fraction was separated from alluvial acid soil. In addition, organic matter, free Fe oxides, and Mn oxides were selectively removed by washing the bulk soil and the clay fraction with H 2 O 2 , Na 3 C 6 H 5 O 7 ·2H 2 O + NaHCO 3  + Na 2 S 2 O 4 , and HONH 3 Cl. Adsorption experiment results indicate that Cu(II) adsorption decreased for bulk soil and clay fractions after removing organic matter and Mn oxides. However, after free Fe oxides were removed, the Cu(II) adsorption increased for bulk soil and clay fractions. The adsorption capacity of the clay fraction for Cu(II) was higher than that of the bulk soil irrespective of the selective chemical extraction treatment. When the initial pH increased from 2 to 3.5, the adsorption capacity increased rapidly; when the pH &gt; 6, the adsorption capacity did not change significantly. When the pH was greater than 6, increased Cu(II) adsorption may occur due to the precipitation of Cu(II). Increased ionic strength can inhibit Cu(II) adsorption. The effects of foreign ions on Cu(II) adsorption were in the order Na +  &lt; K +  &lt; Mg 2+  &lt; Ca 2+ for cations and NO 3 −  &lt; SO 4 2− ≈ Cl − for anions. The Cu(II) adsorption was an endothermic and spontaneous process under the investigated experimental conditions.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s12517-021-09099-4</doi><oa>free_for_read</oa></addata></record>
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subjects Acidic soils
Adsorption
Alluvial clays
Alluvial soils
Anions
Calcium ions
Capacity
Cations
Chemical extraction
Chemical properties
Chemical treatment
Chemicophysical properties
Clay
Clay soils
Components
Copper
Earth and Environmental Science
Earth science
Earth Sciences
Endothermic reactions
Fractions
Hydrogen peroxide
Ionic strength
Iron
Magnesium
Manganese
Organic matter
Organic soils
Original Paper
Oxides
pH effects
Sodium bicarbonate
Sodium dithionite
Soil
Soil adsorption
Soil chemistry
Soil properties
Soil temperature
Temperature
title Effects of soil components, solution chemical properties, and temperature on Cu(II) adsorption by alluvial acid soil: a case study in Southwest China
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