Ferrocene metallopolymers of intrinsic microporosity (MPIMs)

We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 40...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-12, Vol.58 (2), p.238-241
Hauptverfasser:	Zhai, Tianran, Ambrose, Kenson, Nyayachavadi, Audithya, Walter, Kelly G, Rondeau-Gagné, Simon, Feldblyum, Jeremy I
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene - chemistry Copolymerization Ferrous Compounds - chemistry Metallocenes - chemistry Microporosity Molecular Structure Polymers - chemistry Solubility Spectrum Analysis, Raman Surface area Surface Properties
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