Ferrocene metallopolymers of intrinsic microporosity (MPIMs)
We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 40...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-12, Vol.58 (2), p.238-241 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Zhai, Tianran Ambrose, Kenson Nyayachavadi, Audithya Walter, Kelly G Rondeau-Gagné, Simon Feldblyum, Jeremy I |
| description | We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 400 m
2
g
−1
. As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers.
Ferrocene-containing polymers can simultaneously possess porosity, solubility, and intrachain electronic communication. |
| doi_str_mv | 10.1039/d1cc05022b |
| format | Article |
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2
g
−1
. As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers.
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2
g
−1
. As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers.
Ferrocene-containing polymers can simultaneously possess porosity, solubility, and intrachain electronic communication.</description><subject>Acetylene - chemistry</subject><subject>Copolymerization</subject><subject>Ferrous Compounds - chemistry</subject><subject>Metallocenes - chemistry</subject><subject>Microporosity</subject><subject>Molecular Structure</subject><subject>Polymers - chemistry</subject><subject>Solubility</subject><subject>Spectrum Analysis, Raman</subject><subject>Surface area</subject><subject>Surface Properties</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpd0c9LwzAUB_AgipvTi3el4GUK1fxsGvCi1elgQw8K3kKaJdDRNjNpD_vvzdxUMJcE3oeXl28AOEXwGkEibhZIa8ggxuUeGCKS0ZTR_GN_c2Yi5YSyATgKYQnjQiw_BANCucAMoyG4nRjvnTatSRrTqbp2K1evG-ND4mxStZ2v2lDppKm0jyXvQtWtk_H8dToPl8fgwKo6mJPdPgLvk8e34jmdvTxNi7tZqgknXaqhiDfnXGdWcytywjnSpbGkFFDRUmclM5hYqiAyDJFFiSy0uVCICEUVRWQExtu-K-8-exM62VRBm7pWrXF9kJgJAXlGuIj04h9dut63cTqJM4Q5w9FFdbVV8VEheGPlyleN8muJoNxkKh9QUXxneh_x-a5lXzZm8Ut_QozgbAt80L_Vv08hX3jCeeQ</recordid><startdate>20211223</startdate><enddate>20211223</enddate><creator>Zhai, Tianran</creator><creator>Ambrose, Kenson</creator><creator>Nyayachavadi, Audithya</creator><creator>Walter, Kelly G</creator><creator>Rondeau-Gagné, Simon</creator><creator>Feldblyum, Jeremy I</creator><general>Royal Society of Chemistry</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6667-9587</orcidid><orcidid>https://orcid.org/0000-0003-1079-2198</orcidid></search><sort><creationdate>20211223</creationdate><title>Ferrocene metallopolymers of intrinsic microporosity (MPIMs)</title><author>Zhai, Tianran ; Ambrose, Kenson ; Nyayachavadi, Audithya ; Walter, Kelly G ; Rondeau-Gagné, Simon ; Feldblyum, Jeremy I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-c0900087c6fc7f983771cbef3b90a4bc6b5e23f4a01e513db1f0f89a139a4a413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetylene - chemistry</topic><topic>Copolymerization</topic><topic>Ferrous Compounds - chemistry</topic><topic>Metallocenes - chemistry</topic><topic>Microporosity</topic><topic>Molecular Structure</topic><topic>Polymers - chemistry</topic><topic>Solubility</topic><topic>Spectrum Analysis, Raman</topic><topic>Surface area</topic><topic>Surface Properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhai, Tianran</creatorcontrib><creatorcontrib>Ambrose, Kenson</creatorcontrib><creatorcontrib>Nyayachavadi, Audithya</creatorcontrib><creatorcontrib>Walter, Kelly G</creatorcontrib><creatorcontrib>Rondeau-Gagné, Simon</creatorcontrib><creatorcontrib>Feldblyum, Jeremy I</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhai, Tianran</au><au>Ambrose, Kenson</au><au>Nyayachavadi, Audithya</au><au>Walter, Kelly G</au><au>Rondeau-Gagné, Simon</au><au>Feldblyum, Jeremy I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ferrocene metallopolymers of intrinsic microporosity (MPIMs)</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2021-12-23</date><risdate>2021</risdate><volume>58</volume><issue>2</issue><spage>238</spage><epage>241</epage><pages>238-241</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 400 m
2
g
−1
. As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers.
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| ispartof | Chemical communications (Cambridge, England), 2021-12, Vol.58 (2), p.238-241 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acetylene - chemistry Copolymerization Ferrous Compounds - chemistry Metallocenes - chemistry Microporosity Molecular Structure Polymers - chemistry Solubility Spectrum Analysis, Raman Surface area Surface Properties |
| title | Ferrocene metallopolymers of intrinsic microporosity (MPIMs) |
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