Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A
The paper describes a comparative study on the effects of the composition of polymers of higher alkyl (meth)acrylates on their dispersion degree in petroleum oil I-20A. The dispersion degree parameter is evaluated in accordance with a modified spectrophotometric method proposed in the study. It was...
Gespeichert in:
| Veröffentlicht in: | Petroleum chemistry 2021-11, Vol.61 (11), p.1288-1295 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1295 |
|---|---|
| container_issue | 11 |
| container_start_page | 1288 |
| container_title | Petroleum chemistry |
| container_volume | 61 |
| creator | Bolshakova, E. A. Kazantsev, O. A. Arifullin, I. R. Kamorin, D. M. Moikin, A. A. Medzhibovskii, A. S. Simagin, A. S. |
| description | The paper describes a comparative study on the effects of the composition of polymers of higher alkyl (meth)acrylates on their dispersion degree in petroleum oil I-20A. The dispersion degree parameter is evaluated in accordance with a modified spectrophotometric method proposed in the study. It was found that increasing the polymer amphiphilicity by introducing nitrogen-based units in an amount of 5–15% dramatically enhances the dispersion properties, and that amide groups have a stronger effect than amine ones. Increasing the polyalkyl methacrylate amphiphilicity by introducing (in an amount of 5–40%) alkoxy oligo(ethylene glycol) methacrylate (AOEGM) units containing 3–7 ethoxy groups does not enhance the polymer’s dispersion ability. The only exception was a single case of a fairly high dispersion ability achieved for a copolymer containing 30% of AOEGM units with long hydrophilic chains consisting of ten ethoxy groups. |
| doi_str_mv | 10.1134/S0965544121110153 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2612414393</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A687644852</galeid><sourcerecordid>A687644852</sourcerecordid><originalsourceid>FETCH-LOGICAL-c335t-54bab525593ac1c2feeb8978568ce49817a90fb83221b365bc49bf0ad72d36843</originalsourceid><addsrcrecordid>eNp1kUtPGzEQgK0KpAboD-jNUi_lsODxYx-9RUABCQQS9LzyOuPEdHcdbO8h_74OQUKoIB889nzfeKwh5DuwEwAhTx9YUyolJXAAYKDEFzIDpVRRctHskdk2XWzzX8lBjE-MQQVSzEi49_1mwBCpt_TKLVcY6Lz_u-npz1tMq2NtwqbXCeMv-rhCemEtmvQCP6QwmTQFpH6k5y6ucxGXw_vgc5gcRuryCVPwPU4DvXM9vS44mx-Rfav7iN9e90Py5_fF49lVcXN3eX02vymMECrlZjvdKa5UI7QBwy1iVzdVrcraoGxqqHTDbFcLzqETpeqMbDrL9KLiC1HWUhySH7u66-CfJ4ypffJTGPOTLS-By_z_RrxRS91j60brU9BmcNG087KuSilrxTN18gGV1wIHZ_yI1uX7dwLsBBN8jAFtuw5u0GHTAmu3E2v_m1h2-M6JmR2XGN4a_lz6B2YklQg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2612414393</pqid></control><display><type>article</type><title>Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A</title><source>EBSCOhost Business Source Complete</source><source>SpringerLink Journals - AutoHoldings</source><creator>Bolshakova, E. A. ; Kazantsev, O. A. ; Arifullin, I. R. ; Kamorin, D. M. ; Moikin, A. A. ; Medzhibovskii, A. S. ; Simagin, A. S.</creator><creatorcontrib>Bolshakova, E. A. ; Kazantsev, O. A. ; Arifullin, I. R. ; Kamorin, D. M. ; Moikin, A. A. ; Medzhibovskii, A. S. ; Simagin, A. S.</creatorcontrib><description>The paper describes a comparative study on the effects of the composition of polymers of higher alkyl (meth)acrylates on their dispersion degree in petroleum oil I-20A. The dispersion degree parameter is evaluated in accordance with a modified spectrophotometric method proposed in the study. It was found that increasing the polymer amphiphilicity by introducing nitrogen-based units in an amount of 5–15% dramatically enhances the dispersion properties, and that amide groups have a stronger effect than amine ones. Increasing the polyalkyl methacrylate amphiphilicity by introducing (in an amount of 5–40%) alkoxy oligo(ethylene glycol) methacrylate (AOEGM) units containing 3–7 ethoxy groups does not enhance the polymer’s dispersion ability. The only exception was a single case of a fairly high dispersion ability achieved for a copolymer containing 30% of AOEGM units with long hydrophilic chains consisting of ten ethoxy groups.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544121110153</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acrylates ; Chemistry ; Chemistry and Materials Science ; Comparative studies ; Composition effects ; Copolymers ; Crude oil ; Dispersion ; Ethylene glycol ; Industrial Chemistry/Chemical Engineering ; Methamphetamine ; Parameter modification ; Polymers ; Spectrophotometry</subject><ispartof>Petroleum chemistry, 2021-11, Vol.61 (11), p.1288-1295</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c335t-54bab525593ac1c2feeb8978568ce49817a90fb83221b365bc49bf0ad72d36843</cites><orcidid>0000-0002-0154-2552 ; 0000-0003-1536-3966 ; 0000-0002-5939-2913 ; 0000-0002-8339-0088 ; 0000-0002-6985-2098 ; 0000-0002-8712-5062</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965544121110153$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965544121110153$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Bolshakova, E. A.</creatorcontrib><creatorcontrib>Kazantsev, O. A.</creatorcontrib><creatorcontrib>Arifullin, I. R.</creatorcontrib><creatorcontrib>Kamorin, D. M.</creatorcontrib><creatorcontrib>Moikin, A. A.</creatorcontrib><creatorcontrib>Medzhibovskii, A. S.</creatorcontrib><creatorcontrib>Simagin, A. S.</creatorcontrib><title>Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>The paper describes a comparative study on the effects of the composition of polymers of higher alkyl (meth)acrylates on their dispersion degree in petroleum oil I-20A. The dispersion degree parameter is evaluated in accordance with a modified spectrophotometric method proposed in the study. It was found that increasing the polymer amphiphilicity by introducing nitrogen-based units in an amount of 5–15% dramatically enhances the dispersion properties, and that amide groups have a stronger effect than amine ones. Increasing the polyalkyl methacrylate amphiphilicity by introducing (in an amount of 5–40%) alkoxy oligo(ethylene glycol) methacrylate (AOEGM) units containing 3–7 ethoxy groups does not enhance the polymer’s dispersion ability. The only exception was a single case of a fairly high dispersion ability achieved for a copolymer containing 30% of AOEGM units with long hydrophilic chains consisting of ten ethoxy groups.</description><subject>Acrylates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Comparative studies</subject><subject>Composition effects</subject><subject>Copolymers</subject><subject>Crude oil</subject><subject>Dispersion</subject><subject>Ethylene glycol</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Methamphetamine</subject><subject>Parameter modification</subject><subject>Polymers</subject><subject>Spectrophotometry</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kUtPGzEQgK0KpAboD-jNUi_lsODxYx-9RUABCQQS9LzyOuPEdHcdbO8h_74OQUKoIB889nzfeKwh5DuwEwAhTx9YUyolJXAAYKDEFzIDpVRRctHskdk2XWzzX8lBjE-MQQVSzEi49_1mwBCpt_TKLVcY6Lz_u-npz1tMq2NtwqbXCeMv-rhCemEtmvQCP6QwmTQFpH6k5y6ucxGXw_vgc5gcRuryCVPwPU4DvXM9vS44mx-Rfav7iN9e90Py5_fF49lVcXN3eX02vymMECrlZjvdKa5UI7QBwy1iVzdVrcraoGxqqHTDbFcLzqETpeqMbDrL9KLiC1HWUhySH7u66-CfJ4ypffJTGPOTLS-By_z_RrxRS91j60brU9BmcNG087KuSilrxTN18gGV1wIHZ_yI1uX7dwLsBBN8jAFtuw5u0GHTAmu3E2v_m1h2-M6JmR2XGN4a_lz6B2YklQg</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Bolshakova, E. A.</creator><creator>Kazantsev, O. A.</creator><creator>Arifullin, I. R.</creator><creator>Kamorin, D. M.</creator><creator>Moikin, A. A.</creator><creator>Medzhibovskii, A. S.</creator><creator>Simagin, A. S.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0154-2552</orcidid><orcidid>https://orcid.org/0000-0003-1536-3966</orcidid><orcidid>https://orcid.org/0000-0002-5939-2913</orcidid><orcidid>https://orcid.org/0000-0002-8339-0088</orcidid><orcidid>https://orcid.org/0000-0002-6985-2098</orcidid><orcidid>https://orcid.org/0000-0002-8712-5062</orcidid></search><sort><creationdate>20211101</creationdate><title>Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A</title><author>Bolshakova, E. A. ; Kazantsev, O. A. ; Arifullin, I. R. ; Kamorin, D. M. ; Moikin, A. A. ; Medzhibovskii, A. S. ; Simagin, A. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-54bab525593ac1c2feeb8978568ce49817a90fb83221b365bc49bf0ad72d36843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acrylates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Comparative studies</topic><topic>Composition effects</topic><topic>Copolymers</topic><topic>Crude oil</topic><topic>Dispersion</topic><topic>Ethylene glycol</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Methamphetamine</topic><topic>Parameter modification</topic><topic>Polymers</topic><topic>Spectrophotometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bolshakova, E. A.</creatorcontrib><creatorcontrib>Kazantsev, O. A.</creatorcontrib><creatorcontrib>Arifullin, I. R.</creatorcontrib><creatorcontrib>Kamorin, D. M.</creatorcontrib><creatorcontrib>Moikin, A. A.</creatorcontrib><creatorcontrib>Medzhibovskii, A. S.</creatorcontrib><creatorcontrib>Simagin, A. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bolshakova, E. A.</au><au>Kazantsev, O. A.</au><au>Arifullin, I. R.</au><au>Kamorin, D. M.</au><au>Moikin, A. A.</au><au>Medzhibovskii, A. S.</au><au>Simagin, A. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>61</volume><issue>11</issue><spage>1288</spage><epage>1295</epage><pages>1288-1295</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>The paper describes a comparative study on the effects of the composition of polymers of higher alkyl (meth)acrylates on their dispersion degree in petroleum oil I-20A. The dispersion degree parameter is evaluated in accordance with a modified spectrophotometric method proposed in the study. It was found that increasing the polymer amphiphilicity by introducing nitrogen-based units in an amount of 5–15% dramatically enhances the dispersion properties, and that amide groups have a stronger effect than amine ones. Increasing the polyalkyl methacrylate amphiphilicity by introducing (in an amount of 5–40%) alkoxy oligo(ethylene glycol) methacrylate (AOEGM) units containing 3–7 ethoxy groups does not enhance the polymer’s dispersion ability. The only exception was a single case of a fairly high dispersion ability achieved for a copolymer containing 30% of AOEGM units with long hydrophilic chains consisting of ten ethoxy groups.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0965544121110153</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-0154-2552</orcidid><orcidid>https://orcid.org/0000-0003-1536-3966</orcidid><orcidid>https://orcid.org/0000-0002-5939-2913</orcidid><orcidid>https://orcid.org/0000-0002-8339-0088</orcidid><orcidid>https://orcid.org/0000-0002-6985-2098</orcidid><orcidid>https://orcid.org/0000-0002-8712-5062</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0965-5441 |
| ispartof | Petroleum chemistry, 2021-11, Vol.61 (11), p.1288-1295 |
| issn | 0965-5441 1555-6239 |
| language | eng |
| recordid | cdi_proquest_journals_2612414393 |
| source | EBSCOhost Business Source Complete; SpringerLink Journals - AutoHoldings |
| subjects | Acrylates Chemistry Chemistry and Materials Science Comparative studies Composition effects Copolymers Crude oil Dispersion Ethylene glycol Industrial Chemistry/Chemical Engineering Methamphetamine Parameter modification Polymers Spectrophotometry |
| title | Polymers of Higher Alkyl (Meth)acrylates: The Effects of Structure on Dispersion Properties in Petroleum Oil I-20A |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T09%3A35%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polymers%20of%20Higher%20Alkyl%20(Meth)acrylates:%20The%20Effects%20of%20Structure%20on%20Dispersion%20Properties%20in%20Petroleum%20Oil%20I-20A&rft.jtitle=Petroleum%20chemistry&rft.au=Bolshakova,%20E.%20A.&rft.date=2021-11-01&rft.volume=61&rft.issue=11&rft.spage=1288&rft.epage=1295&rft.pages=1288-1295&rft.issn=0965-5441&rft.eissn=1555-6239&rft_id=info:doi/10.1134/S0965544121110153&rft_dat=%3Cgale_proqu%3EA687644852%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2612414393&rft_id=info:pmid/&rft_galeid=A687644852&rfr_iscdi=true |