Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores
Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm o...
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Veröffentlicht in: | Protection of metals and physical chemistry of surfaces 2021-11, Vol.57 (6), p.1105-1114 |
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container_title | Protection of metals and physical chemistry of surfaces |
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creator | Yakovlev, V. Yu Shkolin, A. V. Fomkin, A. A. Gorelikov, V. N. Men’shchikov, I. E. |
description | Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm obtained by successively eliminating one, two, etc., up to seven layers of hexagonal carbon in the crystal lattice of graphite were used in calculations. The integral energy of adsorption was calculated for the model structures and commercial carbon adsorbents. The dependence of the gravimetric density of carbon dioxide on temperature and pressure was found. |
doi_str_mv | 10.1134/S2070205121060204 |
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Yu ; Shkolin, A. V. ; Fomkin, A. A. ; Gorelikov, V. N. ; Men’shchikov, I. E.</creator><creatorcontrib>Yakovlev, V. Yu ; Shkolin, A. V. ; Fomkin, A. A. ; Gorelikov, V. N. ; Men’shchikov, I. E.</creatorcontrib><description>Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm obtained by successively eliminating one, two, etc., up to seven layers of hexagonal carbon in the crystal lattice of graphite were used in calculations. The integral energy of adsorption was calculated for the model structures and commercial carbon adsorbents. The dependence of the gravimetric density of carbon dioxide on temperature and pressure was found.</description><identifier>ISSN: 2070-2051</identifier><identifier>EISSN: 2070-206X</identifier><identifier>DOI: 10.1134/S2070205121060204</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorbents ; Adsorption ; Carbon dioxide ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Corrosion and Coatings ; Crystal lattices ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science ; Metallic Materials ; Physicochemical Processes at the Interfaces ; Tribology</subject><ispartof>Protection of metals and physical chemistry of surfaces, 2021-11, Vol.57 (6), p.1105-1114</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 2070-2051, Protection of Metals and Physical Chemistry of Surfaces, 2021, Vol. 57, No. 6, pp. 1105–1114. © Pleiades Publishing, Ltd., 2021. 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V.</creatorcontrib><creatorcontrib>Fomkin, A. A.</creatorcontrib><creatorcontrib>Gorelikov, V. N.</creatorcontrib><creatorcontrib>Men’shchikov, I. E.</creatorcontrib><title>Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores</title><title>Protection of metals and physical chemistry of surfaces</title><addtitle>Prot Met Phys Chem Surf</addtitle><description>Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm obtained by successively eliminating one, two, etc., up to seven layers of hexagonal carbon in the crystal lattice of graphite were used in calculations. The integral energy of adsorption was calculated for the model structures and commercial carbon adsorbents. The dependence of the gravimetric density of carbon dioxide on temperature and pressure was found.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Carbon dioxide</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion and Coatings</subject><subject>Crystal lattices</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Physicochemical Processes at the Interfaces</subject><subject>Tribology</subject><issn>2070-2051</issn><issn>2070-206X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKAzEUDaJgrX6Au4Dr0XuTTNIuS31CRbAK7oZ5JJo6TsYkg_r3ptTHQlzdwz3n3Mch5BDhGJGLkyUDBQxyZAgyAbFFRutWxkA-bP_gHHfJXggrACnVRI3I7awJzvfRuo46Q-elrxI6te7dNpq6Ljp67RrdfjPL6Ic6Dl4H-mbjE122Nrb2WdNrW3vXu0Tskx1TtkEffNUxuT8_u5tfZoubi6v5bJHVHGXMEBqmYVLlqlJKg2lQsdpMc84Vr3guxLRKv0BdgRE4UQYQyoZJaWrFplooPiZHm7m9d6-DDrFYucF3aWXBJCY5CoSkwo0qnReC16bovX0p_UeBUKyjK_5Elzxs4wlJ2z1q_zv5f9MnClJutA</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Yakovlev, V. 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E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores</atitle><jtitle>Protection of metals and physical chemistry of surfaces</jtitle><stitle>Prot Met Phys Chem Surf</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>57</volume><issue>6</issue><spage>1105</spage><epage>1114</epage><pages>1105-1114</pages><issn>2070-2051</issn><eissn>2070-206X</eissn><abstract>Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm obtained by successively eliminating one, two, etc., up to seven layers of hexagonal carbon in the crystal lattice of graphite were used in calculations. 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subjects | Adsorbents Adsorption Carbon dioxide Characterization and Evaluation of Materials Chemistry and Materials Science Corrosion and Coatings Crystal lattices Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Metallic Materials Physicochemical Processes at the Interfaces Tribology |
title | Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores |
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