Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores

Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm o...

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Veröffentlicht in:Protection of metals and physical chemistry of surfaces 2021-11, Vol.57 (6), p.1105-1114
Hauptverfasser: Yakovlev, V. Yu, Shkolin, A. V., Fomkin, A. A., Gorelikov, V. N., Men’shchikov, I. E.
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container_issue 6
container_start_page 1105
container_title Protection of metals and physical chemistry of surfaces
container_volume 57
creator Yakovlev, V. Yu
Shkolin, A. V.
Fomkin, A. A.
Gorelikov, V. N.
Men’shchikov, I. E.
description Carbon dioxide adsorption onto model supramolecular structures with slitlike micropores was calculated based on the Dubinin theory of volume filling of micropores using the linearity property of isosteres. Models of carbon adsorbents with slitlike micropores with a width ranging from 0.5 to 2.5 nm obtained by successively eliminating one, two, etc., up to seven layers of hexagonal carbon in the crystal lattice of graphite were used in calculations. The integral energy of adsorption was calculated for the model structures and commercial carbon adsorbents. The dependence of the gravimetric density of carbon dioxide on temperature and pressure was found.
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subjects Adsorbents
Adsorption
Carbon dioxide
Characterization and Evaluation of Materials
Chemistry and Materials Science
Corrosion and Coatings
Crystal lattices
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Materials Science
Metallic Materials
Physicochemical Processes at the Interfaces
Tribology
title Adsorption of Carbon Dioxide onto Model Carbon Structures with Slitlike Micropores
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