The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries
•NVO material doped by niobium ion (Nb5+) was successfully prepared by the rheological phase method.•Nb-doping lead to an expansion of the lattice volume and increase the intrinsic conductivity.•NaNb0.018V2.982O8 demonstrates high-rate capability and long-term cyclability.•Pseudocapacitive behavior...
Gespeichert in:
| Veröffentlicht in: | Journal of alloys and compounds 2022-01, Vol.890, p.161885, Article 161885 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | 161885 |
| container_title | Journal of alloys and compounds |
| container_volume | 890 |
| creator | Zhu, Limin Pan, Chunliang Han, Qing Miao, Yongxia Yang, Xinli Xie, Lingling Cao, Xiaoyu |
| description | •NVO material doped by niobium ion (Nb5+) was successfully prepared by the rheological phase method.•Nb-doping lead to an expansion of the lattice volume and increase the intrinsic conductivity.•NaNb0.018V2.982O8 demonstrates high-rate capability and long-term cyclability.•Pseudocapacitive behavior of Nb-doped NVO is confirmed by kinetics analysis.
In this work, NaNb0.018V2.982O8 (NVO-0.018Nb) composite was served as the cathode of sodium-ion batteries (SIBs) to deliver a superior Na-storage capacity of 187 mA h g−1 at the current density of 1 C and voltage range of 1.5–4.0 V, and favorable energy density (419.3 Wh kg−1). Electrochemical impedance spectroscopy (EIS) measurements displayed decreased charge transfer resistance in the NVO-0.018Nb composite. The detailed kinetic analysis revealed enhanced surface-controlled behaviors, leading to improved sodium-storage capability. Scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) analyses demonstrated that NVO-0.018Nb composite exhibited unique structure with significantly enhanced structural stability during fast cycling. In sum, the proposed method looks promising for the design of future advanced electrode materials of SIBs. |
| doi_str_mv | 10.1016/j.jallcom.2021.161885 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2606201905</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0925838821032941</els_id><sourcerecordid>2606201905</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-217b39f4f3d92ea04966048de8bd9c92c8c644bbe0b10a36361ae18a82316bda3</originalsourceid><addsrcrecordid>eNqFkEtLAzEUhYMoWKs_QQi4njGPaZpZiRRfUNpNdRvyuGMzTCc1SQv9905pXbu6cO8553I-hO4pKSmh4rEtW911NmxKRhgtqaBSTi7QiMopLyoh6ks0IjWbFJJLeY1uUmoJIbTmdISa1Rqw32xj2IPD9mA733_jlLXxnc8HrHuHo86Ard7-7UKDF6ZwYTs4FvqLL-VwzevgADch4hSc320KH3psdM4QPaRbdNXoLsHdeY7R5-vLavZezJdvH7PneWE5n-aC0anhdVM13NUMNKlqIUglHUjjalszK62oKmOAGEo0F1xQDVRqyTgVxmk-Rg-n3KHQzw5SVm3YxX54qZgggg2tyWRQTU4qG0NKERq1jX6j40FRoo5IVavOSNURqTohHXxPJx8MFfYeokrWQ2_B-Qg2Kxf8Pwm_eXiCAQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2606201905</pqid></control><display><type>article</type><title>The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries</title><source>Access via ScienceDirect (Elsevier)</source><creator>Zhu, Limin ; Pan, Chunliang ; Han, Qing ; Miao, Yongxia ; Yang, Xinli ; Xie, Lingling ; Cao, Xiaoyu</creator><creatorcontrib>Zhu, Limin ; Pan, Chunliang ; Han, Qing ; Miao, Yongxia ; Yang, Xinli ; Xie, Lingling ; Cao, Xiaoyu</creatorcontrib><description>•NVO material doped by niobium ion (Nb5+) was successfully prepared by the rheological phase method.•Nb-doping lead to an expansion of the lattice volume and increase the intrinsic conductivity.•NaNb0.018V2.982O8 demonstrates high-rate capability and long-term cyclability.•Pseudocapacitive behavior of Nb-doped NVO is confirmed by kinetics analysis.
In this work, NaNb0.018V2.982O8 (NVO-0.018Nb) composite was served as the cathode of sodium-ion batteries (SIBs) to deliver a superior Na-storage capacity of 187 mA h g−1 at the current density of 1 C and voltage range of 1.5–4.0 V, and favorable energy density (419.3 Wh kg−1). Electrochemical impedance spectroscopy (EIS) measurements displayed decreased charge transfer resistance in the NVO-0.018Nb composite. The detailed kinetic analysis revealed enhanced surface-controlled behaviors, leading to improved sodium-storage capability. Scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) analyses demonstrated that NVO-0.018Nb composite exhibited unique structure with significantly enhanced structural stability during fast cycling. In sum, the proposed method looks promising for the design of future advanced electrode materials of SIBs.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2021.161885</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Cathodes ; Charge transfer ; Cycles ; Electrochemical impedance spectroscopy ; Electrode materials ; Enhanced electrochemical performances ; Flux density ; NaV3O8 cathode materials ; Nb5+ ions doping ; Niobium ; Rechargeable batteries ; Sodium-ion batteries ; Storage batteries ; Storage capacity ; Structural stability ; X ray powder diffraction</subject><ispartof>Journal of alloys and compounds, 2022-01, Vol.890, p.161885, Article 161885</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jan 22, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-217b39f4f3d92ea04966048de8bd9c92c8c644bbe0b10a36361ae18a82316bda3</citedby><cites>FETCH-LOGICAL-c337t-217b39f4f3d92ea04966048de8bd9c92c8c644bbe0b10a36361ae18a82316bda3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2021.161885$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3552,27931,27932,46002</link.rule.ids></links><search><creatorcontrib>Zhu, Limin</creatorcontrib><creatorcontrib>Pan, Chunliang</creatorcontrib><creatorcontrib>Han, Qing</creatorcontrib><creatorcontrib>Miao, Yongxia</creatorcontrib><creatorcontrib>Yang, Xinli</creatorcontrib><creatorcontrib>Xie, Lingling</creatorcontrib><creatorcontrib>Cao, Xiaoyu</creatorcontrib><title>The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries</title><title>Journal of alloys and compounds</title><description>•NVO material doped by niobium ion (Nb5+) was successfully prepared by the rheological phase method.•Nb-doping lead to an expansion of the lattice volume and increase the intrinsic conductivity.•NaNb0.018V2.982O8 demonstrates high-rate capability and long-term cyclability.•Pseudocapacitive behavior of Nb-doped NVO is confirmed by kinetics analysis.
In this work, NaNb0.018V2.982O8 (NVO-0.018Nb) composite was served as the cathode of sodium-ion batteries (SIBs) to deliver a superior Na-storage capacity of 187 mA h g−1 at the current density of 1 C and voltage range of 1.5–4.0 V, and favorable energy density (419.3 Wh kg−1). Electrochemical impedance spectroscopy (EIS) measurements displayed decreased charge transfer resistance in the NVO-0.018Nb composite. The detailed kinetic analysis revealed enhanced surface-controlled behaviors, leading to improved sodium-storage capability. Scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) analyses demonstrated that NVO-0.018Nb composite exhibited unique structure with significantly enhanced structural stability during fast cycling. In sum, the proposed method looks promising for the design of future advanced electrode materials of SIBs.</description><subject>Cathodes</subject><subject>Charge transfer</subject><subject>Cycles</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrode materials</subject><subject>Enhanced electrochemical performances</subject><subject>Flux density</subject><subject>NaV3O8 cathode materials</subject><subject>Nb5+ ions doping</subject><subject>Niobium</subject><subject>Rechargeable batteries</subject><subject>Sodium-ion batteries</subject><subject>Storage batteries</subject><subject>Storage capacity</subject><subject>Structural stability</subject><subject>X ray powder diffraction</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_QQi4njGPaZpZiRRfUNpNdRvyuGMzTCc1SQv9905pXbu6cO8553I-hO4pKSmh4rEtW911NmxKRhgtqaBSTi7QiMopLyoh6ks0IjWbFJJLeY1uUmoJIbTmdISa1Rqw32xj2IPD9mA733_jlLXxnc8HrHuHo86Ard7-7UKDF6ZwYTs4FvqLL-VwzevgADch4hSc320KH3psdM4QPaRbdNXoLsHdeY7R5-vLavZezJdvH7PneWE5n-aC0anhdVM13NUMNKlqIUglHUjjalszK62oKmOAGEo0F1xQDVRqyTgVxmk-Rg-n3KHQzw5SVm3YxX54qZgggg2tyWRQTU4qG0NKERq1jX6j40FRoo5IVavOSNURqTohHXxPJx8MFfYeokrWQ2_B-Qg2Kxf8Pwm_eXiCAQ</recordid><startdate>20220115</startdate><enddate>20220115</enddate><creator>Zhu, Limin</creator><creator>Pan, Chunliang</creator><creator>Han, Qing</creator><creator>Miao, Yongxia</creator><creator>Yang, Xinli</creator><creator>Xie, Lingling</creator><creator>Cao, Xiaoyu</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220115</creationdate><title>The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries</title><author>Zhu, Limin ; Pan, Chunliang ; Han, Qing ; Miao, Yongxia ; Yang, Xinli ; Xie, Lingling ; Cao, Xiaoyu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-217b39f4f3d92ea04966048de8bd9c92c8c644bbe0b10a36361ae18a82316bda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cathodes</topic><topic>Charge transfer</topic><topic>Cycles</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrode materials</topic><topic>Enhanced electrochemical performances</topic><topic>Flux density</topic><topic>NaV3O8 cathode materials</topic><topic>Nb5+ ions doping</topic><topic>Niobium</topic><topic>Rechargeable batteries</topic><topic>Sodium-ion batteries</topic><topic>Storage batteries</topic><topic>Storage capacity</topic><topic>Structural stability</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Limin</creatorcontrib><creatorcontrib>Pan, Chunliang</creatorcontrib><creatorcontrib>Han, Qing</creatorcontrib><creatorcontrib>Miao, Yongxia</creatorcontrib><creatorcontrib>Yang, Xinli</creatorcontrib><creatorcontrib>Xie, Lingling</creatorcontrib><creatorcontrib>Cao, Xiaoyu</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Limin</au><au>Pan, Chunliang</au><au>Han, Qing</au><au>Miao, Yongxia</au><au>Yang, Xinli</au><au>Xie, Lingling</au><au>Cao, Xiaoyu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-01-15</date><risdate>2022</risdate><volume>890</volume><spage>161885</spage><pages>161885-</pages><artnum>161885</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>•NVO material doped by niobium ion (Nb5+) was successfully prepared by the rheological phase method.•Nb-doping lead to an expansion of the lattice volume and increase the intrinsic conductivity.•NaNb0.018V2.982O8 demonstrates high-rate capability and long-term cyclability.•Pseudocapacitive behavior of Nb-doped NVO is confirmed by kinetics analysis.
In this work, NaNb0.018V2.982O8 (NVO-0.018Nb) composite was served as the cathode of sodium-ion batteries (SIBs) to deliver a superior Na-storage capacity of 187 mA h g−1 at the current density of 1 C and voltage range of 1.5–4.0 V, and favorable energy density (419.3 Wh kg−1). Electrochemical impedance spectroscopy (EIS) measurements displayed decreased charge transfer resistance in the NVO-0.018Nb composite. The detailed kinetic analysis revealed enhanced surface-controlled behaviors, leading to improved sodium-storage capability. Scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) analyses demonstrated that NVO-0.018Nb composite exhibited unique structure with significantly enhanced structural stability during fast cycling. In sum, the proposed method looks promising for the design of future advanced electrode materials of SIBs.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2021.161885</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0925-8388 |
| ispartof | Journal of alloys and compounds, 2022-01, Vol.890, p.161885, Article 161885 |
| issn | 0925-8388 1873-4669 |
| language | eng |
| recordid | cdi_proquest_journals_2606201905 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Cathodes Charge transfer Cycles Electrochemical impedance spectroscopy Electrode materials Enhanced electrochemical performances Flux density NaV3O8 cathode materials Nb5+ ions doping Niobium Rechargeable batteries Sodium-ion batteries Storage batteries Storage capacity Structural stability X ray powder diffraction |
| title | The improved cycling stability and rate capability of Nb-doped NaV3O8 cathode for sodium-ion batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-03T20%3A59%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20improved%20cycling%20stability%20and%20rate%20capability%20of%20Nb-doped%20NaV3O8%20cathode%20for%20sodium-ion%20batteries&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=Zhu,%20Limin&rft.date=2022-01-15&rft.volume=890&rft.spage=161885&rft.pages=161885-&rft.artnum=161885&rft.issn=0925-8388&rft.eissn=1873-4669&rft_id=info:doi/10.1016/j.jallcom.2021.161885&rft_dat=%3Cproquest_cross%3E2606201905%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2606201905&rft_id=info:pmid/&rft_els_id=S0925838821032941&rfr_iscdi=true |