Development of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water
Recycling mine tailings present a good alternative to manage the waste generated from mining and mineral processing industries. The geopolymer technology provides a green solution to the utilization of mining tailings, avoiding its negative environmental impacts. In this study, we used phosphate min...
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| Veröffentlicht in: | Water, air, and soil pollution air, and soil pollution, 2021-12, Vol.232 (12), Article 496 |
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| creator | de Sousa, Flávio Augusto Della-Rocca, Daniela de Amorim, Suélen Maria da Silveira Salla, Júlia Peralta, Rosely Aparecida Rodríguez-Castellón, Enrique Peralta Muniz Moreira, Regina de Fátima |
| description | Recycling mine tailings present a good alternative to manage the waste generated from mining and mineral processing industries. The geopolymer technology provides a green solution to the utilization of mining tailings, avoiding its negative environmental impacts. In this study, we used phosphate mine tailings to produce a novel geopolymeric membrane useful for removing copper ions and humic acid from an aqueous solution. Hydrogen peroxide was used in different concentrations as a porogenic agent, and the membranes exhibited good compressive strength (11.15–43.67 MPa) and high BET surface area (321–384 m
2
g
−1
), depending on the amount of hydrogen peroxide used in the synthesis. The hydraulic permeability of the membranes increased from 4.12 × 10
−5
to 11.84 × 10
−5
m s
−1
bar
−1
when H
2
O
2
was added, but the rejection of copper and humic acid remained nearly the same. Copper ions are adsorbed on the membrane surface, while negligible adsorption was measured for humic acid. The geopolymeric membranes efficiently removed Cu
2+
from water through the combined action of adsorption and rejection by the geopolymer inorganic membrane. The performance of the porous membrane in the removal of copper or humic acid from water increased by factors of 7–19 in comparison to the non-porous membrane. |
| doi_str_mv | 10.1007/s11270-021-05433-4 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2604982762</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A684555594</galeid><sourcerecordid>A684555594</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-e5642c3f1cd4a07eb078adb3fe6fd35fee996d8b3c2c0ee0b691d2df0f81034c3</originalsourceid><addsrcrecordid>eNp9kV1PHSEQhklTkx61f6BXJL1G-dgvLrdHW5toNI1NLwkLwxG7CyvsOcZ_X-w28a4zF5DJ-8wwvAh9YvSMUdqeZ8Z4SwnljNC6EoJU79CG1a0gXAr-Hm0orSRpZCs_oOOcH2kJ2bUb9HwBBxjjPEFYcHT4BqYh6QAZf9EZLI4B9-NvPXrSm8Uf9FJqdw8xzw_lim98AHyv_ejDLmMXE77aT97g3niLdbB4G-cZEv4BUzzoEbsUJ_yrkOkUHTk9Zvj47zxBP79e3m-vyPXtt-_b_poYUXcLgbqpuBGOGVtp2sJA207bQThonBW1A5Cysd0gDDcUgA6NZJZbR13HqKiMOEGf175zik97yIt6jPsUykjFm_InHW8bXlRnq2qnR1A-uLgkbUpaKOvEAM6Xet90VV1CVgXgK2BSzDmBU3Pyk04vilH16ohaHVHFEfXXEfUKiRXKRRx2kN7e8h_qD5e1jwc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2604982762</pqid></control><display><type>article</type><title>Development of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water</title><source>SpringerLink Journals - AutoHoldings</source><creator>de Sousa, Flávio Augusto ; Della-Rocca, Daniela ; de Amorim, Suélen Maria ; da Silveira Salla, Júlia ; Peralta, Rosely Aparecida ; Rodríguez-Castellón, Enrique ; Peralta Muniz Moreira, Regina de Fátima</creator><creatorcontrib>de Sousa, Flávio Augusto ; Della-Rocca, Daniela ; de Amorim, Suélen Maria ; da Silveira Salla, Júlia ; Peralta, Rosely Aparecida ; Rodríguez-Castellón, Enrique ; Peralta Muniz Moreira, Regina de Fátima</creatorcontrib><description>Recycling mine tailings present a good alternative to manage the waste generated from mining and mineral processing industries. The geopolymer technology provides a green solution to the utilization of mining tailings, avoiding its negative environmental impacts. In this study, we used phosphate mine tailings to produce a novel geopolymeric membrane useful for removing copper ions and humic acid from an aqueous solution. Hydrogen peroxide was used in different concentrations as a porogenic agent, and the membranes exhibited good compressive strength (11.15–43.67 MPa) and high BET surface area (321–384 m
2
g
−1
), depending on the amount of hydrogen peroxide used in the synthesis. The hydraulic permeability of the membranes increased from 4.12 × 10
−5
to 11.84 × 10
−5
m s
−1
bar
−1
when H
2
O
2
was added, but the rejection of copper and humic acid remained nearly the same. Copper ions are adsorbed on the membrane surface, while negligible adsorption was measured for humic acid. The geopolymeric membranes efficiently removed Cu
2+
from water through the combined action of adsorption and rejection by the geopolymer inorganic membrane. The performance of the porous membrane in the removal of copper or humic acid from water increased by factors of 7–19 in comparison to the non-porous membrane.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-021-05433-4</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Acids ; Adsorption ; Analysis ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Climate Change/Climate Change Impacts ; Compressive strength ; Copper ; Earth and Environmental Science ; Environment ; Environmental impact ; Environmental monitoring ; Geopolymers ; Humic acid ; Humic acids ; Hydraulic permeability ; Hydrogen peroxide ; Hydrogeology ; Industry ; Ions ; Membrane permeability ; Membranes ; Mine tailings ; Mine wastes ; Mineral industry ; Mineral processing ; Mining ; Mining industry ; Permeability ; Phosphate industry ; Phosphates ; Rejection ; Removal ; Soil Science & Conservation ; Surface chemistry ; Tailings ; Water Quality/Water Pollution ; Water reuse</subject><ispartof>Water, air, and soil pollution, 2021-12, Vol.232 (12), Article 496</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-e5642c3f1cd4a07eb078adb3fe6fd35fee996d8b3c2c0ee0b691d2df0f81034c3</citedby><cites>FETCH-LOGICAL-c358t-e5642c3f1cd4a07eb078adb3fe6fd35fee996d8b3c2c0ee0b691d2df0f81034c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-021-05433-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-021-05433-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>de Sousa, Flávio Augusto</creatorcontrib><creatorcontrib>Della-Rocca, Daniela</creatorcontrib><creatorcontrib>de Amorim, Suélen Maria</creatorcontrib><creatorcontrib>da Silveira Salla, Júlia</creatorcontrib><creatorcontrib>Peralta, Rosely Aparecida</creatorcontrib><creatorcontrib>Rodríguez-Castellón, Enrique</creatorcontrib><creatorcontrib>Peralta Muniz Moreira, Regina de Fátima</creatorcontrib><title>Development of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>Recycling mine tailings present a good alternative to manage the waste generated from mining and mineral processing industries. The geopolymer technology provides a green solution to the utilization of mining tailings, avoiding its negative environmental impacts. In this study, we used phosphate mine tailings to produce a novel geopolymeric membrane useful for removing copper ions and humic acid from an aqueous solution. Hydrogen peroxide was used in different concentrations as a porogenic agent, and the membranes exhibited good compressive strength (11.15–43.67 MPa) and high BET surface area (321–384 m
2
g
−1
), depending on the amount of hydrogen peroxide used in the synthesis. The hydraulic permeability of the membranes increased from 4.12 × 10
−5
to 11.84 × 10
−5
m s
−1
bar
−1
when H
2
O
2
was added, but the rejection of copper and humic acid remained nearly the same. Copper ions are adsorbed on the membrane surface, while negligible adsorption was measured for humic acid. The geopolymeric membranes efficiently removed Cu
2+
from water through the combined action of adsorption and rejection by the geopolymer inorganic membrane. The performance of the porous membrane in the removal of copper or humic acid from water increased by factors of 7–19 in comparison to the non-porous membrane.</description><subject>Acids</subject><subject>Adsorption</subject><subject>Analysis</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Compressive strength</subject><subject>Copper</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental impact</subject><subject>Environmental monitoring</subject><subject>Geopolymers</subject><subject>Humic acid</subject><subject>Humic acids</subject><subject>Hydraulic permeability</subject><subject>Hydrogen peroxide</subject><subject>Hydrogeology</subject><subject>Industry</subject><subject>Ions</subject><subject>Membrane permeability</subject><subject>Membranes</subject><subject>Mine tailings</subject><subject>Mine wastes</subject><subject>Mineral industry</subject><subject>Mineral processing</subject><subject>Mining</subject><subject>Mining industry</subject><subject>Permeability</subject><subject>Phosphate industry</subject><subject>Phosphates</subject><subject>Rejection</subject><subject>Removal</subject><subject>Soil Science & Conservation</subject><subject>Surface chemistry</subject><subject>Tailings</subject><subject>Water Quality/Water Pollution</subject><subject>Water 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of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water</title><author>de Sousa, Flávio Augusto ; Della-Rocca, Daniela ; de Amorim, Suélen Maria ; da Silveira Salla, Júlia ; Peralta, Rosely Aparecida ; Rodríguez-Castellón, Enrique ; Peralta Muniz Moreira, Regina de Fátima</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-e5642c3f1cd4a07eb078adb3fe6fd35fee996d8b3c2c0ee0b691d2df0f81034c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acids</topic><topic>Adsorption</topic><topic>Analysis</topic><topic>Aqueous solutions</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Compressive strength</topic><topic>Copper</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental 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Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Water, air, and soil pollution</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Sousa, Flávio Augusto</au><au>Della-Rocca, Daniela</au><au>de Amorim, Suélen Maria</au><au>da Silveira Salla, Júlia</au><au>Peralta, Rosely Aparecida</au><au>Rodríguez-Castellón, Enrique</au><au>Peralta Muniz Moreira, Regina de Fátima</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>232</volume><issue>12</issue><artnum>496</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>Recycling mine tailings present a good alternative to manage the waste generated from mining and mineral processing industries. The geopolymer technology provides a green solution to the utilization of mining tailings, avoiding its negative environmental impacts. In this study, we used phosphate mine tailings to produce a novel geopolymeric membrane useful for removing copper ions and humic acid from an aqueous solution. Hydrogen peroxide was used in different concentrations as a porogenic agent, and the membranes exhibited good compressive strength (11.15–43.67 MPa) and high BET surface area (321–384 m
2
g
−1
), depending on the amount of hydrogen peroxide used in the synthesis. The hydraulic permeability of the membranes increased from 4.12 × 10
−5
to 11.84 × 10
−5
m s
−1
bar
−1
when H
2
O
2
was added, but the rejection of copper and humic acid remained nearly the same. Copper ions are adsorbed on the membrane surface, while negligible adsorption was measured for humic acid. The geopolymeric membranes efficiently removed Cu
2+
from water through the combined action of adsorption and rejection by the geopolymer inorganic membrane. The performance of the porous membrane in the removal of copper or humic acid from water increased by factors of 7–19 in comparison to the non-porous membrane.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-021-05433-4</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0049-6979 |
| ispartof | Water, air, and soil pollution, 2021-12, Vol.232 (12), Article 496 |
| issn | 0049-6979 1573-2932 |
| language | eng |
| recordid | cdi_proquest_journals_2604982762 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acids Adsorption Analysis Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Climate Change/Climate Change Impacts Compressive strength Copper Earth and Environmental Science Environment Environmental impact Environmental monitoring Geopolymers Humic acid Humic acids Hydraulic permeability Hydrogen peroxide Hydrogeology Industry Ions Membrane permeability Membranes Mine tailings Mine wastes Mineral industry Mineral processing Mining Mining industry Permeability Phosphate industry Phosphates Rejection Removal Soil Science & Conservation Surface chemistry Tailings Water Quality/Water Pollution Water reuse |
| title | Development of Membranes Based on Alkali-Activated Phosphate Mine Tailings for Humic Acid and Copper Removal from Water |
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