Electroanalysis with a single microbead of phosphate binding resin (FerrIX™) mounted in epoxy film
Commercial resin microbeads are widely applied in ion exchange and extraction. Here, a single anion-selective and phosphate binding resin microbead (FerrIX™) is mounted into an epoxy membrane and investigated by 4-electrode membrane voltammetry and membrane impedance spectroscopy. Anion transport pr...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2021-12, Vol.25 (12), p.2881-2891 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Thompson, Abigail K. Mathwig, Klaus Fletcher, Philip J. Castaing, Rémi Marken, Frank |
| description | Commercial resin microbeads are widely applied in ion exchange and extraction. Here, a single anion-selective and phosphate binding resin microbead (FerrIX™) is mounted into an epoxy membrane and investigated by 4-electrode membrane voltammetry and membrane impedance spectroscopy. Anion transport properties are observed to dominate associated with three distinct potential domains: (I) a low bias ohmic potential domain (dominant at high electrolyte concentration), (II) a concentration polarisation potential domain, and (III) an over-limiting potential domain. Voltammetric responses show transient diffusion-migration features at higher scan rates and quasi-steady state features at lower scan rates. Inherent microbead conductivity is shown to be linked to two resistive elements, electrolyte concentration dependent and independent, in series. The effects of phosphate binding are revealed as transient pattern in impedance spectroscopy data. Preliminary data suggest phosphate concentration-dependent peak features in the imaginary impedance versus frequency plot due to phosphate binding into the microbead.
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| doi_str_mv | 10.1007/s10008-021-04982-2 |
| format | Article |
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Here, a single anion-selective and phosphate binding resin microbead (FerrIX™) is mounted into an epoxy membrane and investigated by 4-electrode membrane voltammetry and membrane impedance spectroscopy. Anion transport properties are observed to dominate associated with three distinct potential domains: (I) a low bias ohmic potential domain (dominant at high electrolyte concentration), (II) a concentration polarisation potential domain, and (III) an over-limiting potential domain. Voltammetric responses show transient diffusion-migration features at higher scan rates and quasi-steady state features at lower scan rates. Inherent microbead conductivity is shown to be linked to two resistive elements, electrolyte concentration dependent and independent, in series. The effects of phosphate binding are revealed as transient pattern in impedance spectroscopy data. Preliminary data suggest phosphate concentration-dependent peak features in the imaginary impedance versus frequency plot due to phosphate binding into the microbead.
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| subjects | Analytical Chemistry Anion exchanging Binding Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Diffusion rate Domains Electrochemistry Electrolytes Electrolytic analysis Energy Storage Impedance spectroscopy Ion exchange Membranes Nanoparticles Original Paper Physical Chemistry Quasi-steady states Resins Spectrum analysis Transport properties Voltammetry |
| title | Electroanalysis with a single microbead of phosphate binding resin (FerrIX™) mounted in epoxy film |
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