Theoretical Study of the Rotational Structure of the c4′1Σu + (6)–X1Σg +(0–9) Absorption Bands of N2

We have theoretically determined the absorption oscillator strengths and wavenumbers for rotationally resolved transitions of the c4′1Σu + (6)-X1Σg +(0–9) bands of N2, which are relevant to analyze the spectra of planetary atmospheres. The Molecular Quantum Defect Orbital method has been used in our...

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Veröffentlicht in:The Astrophysical journal 2021-12, Vol.922 (2)
Hauptverfasser: Velasco, A. M., Alonso, J. L., Redondo, P., Lavín, C.
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container_title The Astrophysical journal
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creator Velasco, A. M.
Alonso, J. L.
Redondo, P.
Lavín, C.
description We have theoretically determined the absorption oscillator strengths and wavenumbers for rotationally resolved transitions of the c4′1Σu + (6)-X1Σg +(0–9) bands of N2, which are relevant to analyze the spectra of planetary atmospheres. The Molecular Quantum Defect Orbital method has been used in our calculations. The interaction between the c4′1Σu + (6) Rydberg state and the b′1Σu + valence states has been considered using an adequate rovibronic energy matrix. In addition, we have calculated the lifetimes of the rotational levels of the c4′1Σu + (6) state. We hope that the reported data, most of them for the first time, can be useful in the interpretation of planetary atmospheres where N2 is present.
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subjects Absorption
Absorption bands
Absorption spectra
Astrophysics
Band theory
Banded structure
Line intensities
Mathematical analysis
Molecular spectroscopy
Oscillator strengths
Planetary atmospheres
Radiative processes
Rydberg states
Valence
title Theoretical Study of the Rotational Structure of the c4′1Σu + (6)–X1Σg +(0–9) Absorption Bands of N2
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