Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure
CsPbBr 3–z I z /Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr 3–z I z composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO 2 :Al 3 O 2 ratio in the parent zeolite and the formation of composite nanorods rega...
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| Veröffentlicht in: | Theoretical and experimental chemistry 2021-09, Vol.57 (4), p.272-281 |
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| container_title | Theoretical and experimental chemistry |
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| creator | Posudievsky, O. Yu Konoshchuk, N. V. Rozovik, O. P. Boiko, O. P. Sorokin, V. M. Koshechko, V. G. Pokhodenko, V. D. |
| description | CsPbBr
3–z
I
z
/Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr
3–z
I
z
composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO
2
:Al
3
O
2
ratio in the parent zeolite and the formation of composite nanorods regardless of zeolite type in the case of iodine-containing HP due to the directional growth of CsPbBr
1.2
I
1.8
crystals towards the (110) plane are shown. It is found that CsPbBr
3–z
I
z
/Y(X) materials are characterized by a significantly greater lifetime and intensity of photoluminescence in comparison with individual HP due to confinement effect. Highly stable films of CsPbBr
3–z
I
z
/Y(X)@Sil (z = 0 or 1.8) nanocomposites in silicone, which are characterized by a significant reduction of the luminescence band width, which is associated with the effect of silicone polymer on halide-ion exchange in HP, are prepared. It is shown that the color rendering index could be increased up to 95, while the partial index R
9
could be increased up to 99 at correlated color temperature of ~4500 K when using CsPbBr
1.2
I
1.8
/X@Sil in white light emitting diodes. |
| doi_str_mv | 10.1007/s11237-021-09695-1 |
| format | Article |
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3–z
I
z
/Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr
3–z
I
z
composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO
2
:Al
3
O
2
ratio in the parent zeolite and the formation of composite nanorods regardless of zeolite type in the case of iodine-containing HP due to the directional growth of CsPbBr
1.2
I
1.8
crystals towards the (110) plane are shown. It is found that CsPbBr
3–z
I
z
/Y(X) materials are characterized by a significantly greater lifetime and intensity of photoluminescence in comparison with individual HP due to confinement effect. Highly stable films of CsPbBr
3–z
I
z
/Y(X)@Sil (z = 0 or 1.8) nanocomposites in silicone, which are characterized by a significant reduction of the luminescence band width, which is associated with the effect of silicone polymer on halide-ion exchange in HP, are prepared. It is shown that the color rendering index could be increased up to 95, while the partial index R
9
could be increased up to 99 at correlated color temperature of ~4500 K when using CsPbBr
1.2
I
1.8
/X@Sil in white light emitting diodes.</description><identifier>ISSN: 0040-5760</identifier><identifier>EISSN: 1573-935X</identifier><identifier>DOI: 10.1007/s11237-021-09695-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Color temperature ; Confinement ; Iodine ; Ion exchange ; Light emitting diodes ; Nanocomposites ; Nanoparticles ; Nanorods ; Perovskites ; Photoluminescence ; Silicon dioxide ; Silicone resins ; Silicones ; White light ; Zeolites</subject><ispartof>Theoretical and experimental chemistry, 2021-09, Vol.57 (4), p.272-281</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-ea5fd373c6325bbc2ad435e5ce42c4bc3f2a62c0f96e0e6cba38d08d44374723</citedby><cites>FETCH-LOGICAL-c319t-ea5fd373c6325bbc2ad435e5ce42c4bc3f2a62c0f96e0e6cba38d08d44374723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11237-021-09695-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11237-021-09695-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Posudievsky, O. Yu</creatorcontrib><creatorcontrib>Konoshchuk, N. V.</creatorcontrib><creatorcontrib>Rozovik, O. P.</creatorcontrib><creatorcontrib>Boiko, O. P.</creatorcontrib><creatorcontrib>Sorokin, V. M.</creatorcontrib><creatorcontrib>Koshechko, V. G.</creatorcontrib><creatorcontrib>Pokhodenko, V. D.</creatorcontrib><title>Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure</title><title>Theoretical and experimental chemistry</title><addtitle>Theor Exp Chem</addtitle><description>CsPbBr
3–z
I
z
/Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr
3–z
I
z
composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO
2
:Al
3
O
2
ratio in the parent zeolite and the formation of composite nanorods regardless of zeolite type in the case of iodine-containing HP due to the directional growth of CsPbBr
1.2
I
1.8
crystals towards the (110) plane are shown. It is found that CsPbBr
3–z
I
z
/Y(X) materials are characterized by a significantly greater lifetime and intensity of photoluminescence in comparison with individual HP due to confinement effect. Highly stable films of CsPbBr
3–z
I
z
/Y(X)@Sil (z = 0 or 1.8) nanocomposites in silicone, which are characterized by a significant reduction of the luminescence band width, which is associated with the effect of silicone polymer on halide-ion exchange in HP, are prepared. It is shown that the color rendering index could be increased up to 95, while the partial index R
9
could be increased up to 99 at correlated color temperature of ~4500 K when using CsPbBr
1.2
I
1.8
/X@Sil in white light emitting diodes.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Color temperature</subject><subject>Confinement</subject><subject>Iodine</subject><subject>Ion exchange</subject><subject>Light emitting diodes</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Nanorods</subject><subject>Perovskites</subject><subject>Photoluminescence</subject><subject>Silicon dioxide</subject><subject>Silicone resins</subject><subject>Silicones</subject><subject>White light</subject><subject>Zeolites</subject><issn>0040-5760</issn><issn>1573-935X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kc1O3DAUhS1UJKYDL8DKEuvQ658kk2U1mgEkREeCBWJjOc41k2kmDrYD6sP0XeshtN2xso78fecuDiHnDC4ZQPktMMZFmQFnGVRFlWfsiMxYXoqsEvnjFzIDkJDlZQEn5GsIO4CkLWBGfq-sRROps3Tpetv2uMc-xZ7eRz-aOHrdUd039H5I2CEst9prE9G3IbYmTOZ-cKGNOKWwqR8FvdZd2yDdoHev4Wf6pHe6d4P2yeoS-dbGLX1C1_311nrc6UPLv9N4So6t7gKefbxz8rBePSyvs9sfVzfL77eZEayKGercNqIUphA8r2vDdSNFjrlByY2sjbBcF9yArQoELEytxaKBRSOlKGXJxZxcTLWDdy8jhqh2bvR9uqh4AVIuBEvonPCJMt6F4NGqwbd77X8pBuqwgppWUGkF9b6CYkkSkxQS3D-j_1_9ifUHHnyODA</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Posudievsky, O. Yu</creator><creator>Konoshchuk, N. V.</creator><creator>Rozovik, O. P.</creator><creator>Boiko, O. P.</creator><creator>Sorokin, V. M.</creator><creator>Koshechko, V. G.</creator><creator>Pokhodenko, V. D.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210901</creationdate><title>Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure</title><author>Posudievsky, O. Yu ; Konoshchuk, N. V. ; Rozovik, O. P. ; Boiko, O. P. ; Sorokin, V. M. ; Koshechko, V. G. ; Pokhodenko, V. D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-ea5fd373c6325bbc2ad435e5ce42c4bc3f2a62c0f96e0e6cba38d08d44374723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Color temperature</topic><topic>Confinement</topic><topic>Iodine</topic><topic>Ion exchange</topic><topic>Light emitting diodes</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Nanorods</topic><topic>Perovskites</topic><topic>Photoluminescence</topic><topic>Silicon dioxide</topic><topic>Silicone resins</topic><topic>Silicones</topic><topic>White light</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Posudievsky, O. Yu</creatorcontrib><creatorcontrib>Konoshchuk, N. V.</creatorcontrib><creatorcontrib>Rozovik, O. P.</creatorcontrib><creatorcontrib>Boiko, O. P.</creatorcontrib><creatorcontrib>Sorokin, V. M.</creatorcontrib><creatorcontrib>Koshechko, V. G.</creatorcontrib><creatorcontrib>Pokhodenko, V. D.</creatorcontrib><collection>CrossRef</collection><jtitle>Theoretical and experimental chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Posudievsky, O. Yu</au><au>Konoshchuk, N. V.</au><au>Rozovik, O. P.</au><au>Boiko, O. P.</au><au>Sorokin, V. M.</au><au>Koshechko, V. G.</au><au>Pokhodenko, V. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure</atitle><jtitle>Theoretical and experimental chemistry</jtitle><stitle>Theor Exp Chem</stitle><date>2021-09-01</date><risdate>2021</risdate><volume>57</volume><issue>4</issue><spage>272</spage><epage>281</epage><pages>272-281</pages><issn>0040-5760</issn><eissn>1573-935X</eissn><abstract>CsPbBr
3–z
I
z
/Y(X) nanocomposites based on FAU (Y and X) zeolites and halide perovskite nanoparticles (HP NP) with CsPbBr
3–z
I
z
composition (z = 0 or 1.8) are prepared. The dependence of HP NP content on the SiO
2
:Al
3
O
2
ratio in the parent zeolite and the formation of composite nanorods regardless of zeolite type in the case of iodine-containing HP due to the directional growth of CsPbBr
1.2
I
1.8
crystals towards the (110) plane are shown. It is found that CsPbBr
3–z
I
z
/Y(X) materials are characterized by a significantly greater lifetime and intensity of photoluminescence in comparison with individual HP due to confinement effect. Highly stable films of CsPbBr
3–z
I
z
/Y(X)@Sil (z = 0 or 1.8) nanocomposites in silicone, which are characterized by a significant reduction of the luminescence band width, which is associated with the effect of silicone polymer on halide-ion exchange in HP, are prepared. It is shown that the color rendering index could be increased up to 95, while the partial index R
9
could be increased up to 99 at correlated color temperature of ~4500 K when using CsPbBr
1.2
I
1.8
/X@Sil in white light emitting diodes.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11237-021-09695-1</doi><tpages>10</tpages></addata></record> |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Color temperature Confinement Iodine Ion exchange Light emitting diodes Nanocomposites Nanoparticles Nanorods Perovskites Photoluminescence Silicon dioxide Silicone resins Silicones White light Zeolites |
| title | Effect of Confinement on Structural and Spectral Characteristics of Composites of CsPbX3 Halide Perovskite Nanoparticles with Zeolites of Faujasite Structure |
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