Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N‐methylation
Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines an...
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| creator | Zhou, Chao‐Zheng Zhao, Yu‐Rou Tan, Fang‐Fang Guo, Yan‐Jun Li, Yang |
| description | Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.
Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway. |
| doi_str_mv | 10.1002/cctc.202101099 |
| format | Article |
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Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.</description><identifier>ISSN: 1867-3880</identifier><identifier>EISSN: 1867-3899</identifier><identifier>DOI: 10.1002/cctc.202101099</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Aniline ; Biomass ; Formic acid ; hydrogen source ; Hydrogenation ; Indoles ; Lignocellulose ; lignocellulosic biomass ; Methylation ; N-methylation ; Organic compounds ; renewable formic acid</subject><ispartof>ChemCatChem, 2021-11, Vol.13 (22), p.4724-4728</ispartof><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3179-ce89b62902d38d7901c516709887246aaeb40ab83d68008f81ac6af83c5157f83</citedby><cites>FETCH-LOGICAL-c3179-ce89b62902d38d7901c516709887246aaeb40ab83d68008f81ac6af83c5157f83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcctc.202101099$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcctc.202101099$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Zhou, Chao‐Zheng</creatorcontrib><creatorcontrib>Zhao, Yu‐Rou</creatorcontrib><creatorcontrib>Tan, Fang‐Fang</creatorcontrib><creatorcontrib>Guo, Yan‐Jun</creatorcontrib><creatorcontrib>Li, Yang</creatorcontrib><title>Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N‐methylation</title><title>ChemCatChem</title><description>Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.
Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.</description><subject>Aniline</subject><subject>Biomass</subject><subject>Formic acid</subject><subject>hydrogen source</subject><subject>Hydrogenation</subject><subject>Indoles</subject><subject>Lignocellulose</subject><subject>lignocellulosic biomass</subject><subject>Methylation</subject><subject>N-methylation</subject><subject>Organic compounds</subject><subject>renewable formic acid</subject><issn>1867-3880</issn><issn>1867-3899</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkM1OwzAQhC0EEqVw5WyJc9p10jj2EUX8SRVc2rPlOE7ryomLnVLCiUfgGXkSUoLgyGlWu9_MSoPQJYEJAYinSrVqEkNMgADnR2hEGM2ihHF-_DszOEVnIWwAKE-ydIRel62x5k22xjXYVdjrRu9lYTWunK-NwlKZElfe1diaVeOUtnZnXegvhXG1DOEA4natcdBWq9a8aLzuSu9WuhlSZVNOe-Tx8_2j1u26s9_rc3RSSRv0xY-O0fL2ZpHfR_Onu4f8eh6phGQ8UprxgsYc4jJhZcaBqJTQDDhjWTyjUupiBrJgSUkZAKsYkYrKiiU9lma9jtHVkLv17nmnQys2bueb_qWIKQBhPKVJT00GSnkXgteV2HpTS98JAuLQrji0K37b7Q18MOyN1d0_tMjzRf7n_QLOroEu</recordid><startdate>20211122</startdate><enddate>20211122</enddate><creator>Zhou, Chao‐Zheng</creator><creator>Zhao, Yu‐Rou</creator><creator>Tan, Fang‐Fang</creator><creator>Guo, Yan‐Jun</creator><creator>Li, Yang</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211122</creationdate><title>Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N‐methylation</title><author>Zhou, Chao‐Zheng ; Zhao, Yu‐Rou ; Tan, Fang‐Fang ; Guo, Yan‐Jun ; Li, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3179-ce89b62902d38d7901c516709887246aaeb40ab83d68008f81ac6af83c5157f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aniline</topic><topic>Biomass</topic><topic>Formic acid</topic><topic>hydrogen source</topic><topic>Hydrogenation</topic><topic>Indoles</topic><topic>Lignocellulose</topic><topic>lignocellulosic biomass</topic><topic>Methylation</topic><topic>N-methylation</topic><topic>Organic compounds</topic><topic>renewable formic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Chao‐Zheng</creatorcontrib><creatorcontrib>Zhao, Yu‐Rou</creatorcontrib><creatorcontrib>Tan, Fang‐Fang</creatorcontrib><creatorcontrib>Guo, Yan‐Jun</creatorcontrib><creatorcontrib>Li, Yang</creatorcontrib><collection>CrossRef</collection><jtitle>ChemCatChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Chao‐Zheng</au><au>Zhao, Yu‐Rou</au><au>Tan, Fang‐Fang</au><au>Guo, Yan‐Jun</au><au>Li, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N‐methylation</atitle><jtitle>ChemCatChem</jtitle><date>2021-11-22</date><risdate>2021</risdate><volume>13</volume><issue>22</issue><spage>4724</spage><epage>4728</epage><pages>4724-4728</pages><issn>1867-3880</issn><eissn>1867-3899</eissn><abstract>Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.
Lignocellulosic biomass is one of the most abundant renewable sources in nature. Herein, we have developed the utilization of renewable formic acid from lignocellulosic biomass as a hydrogen source and a carbon source for the selective hydrogenation and further N‐methylation of various quinolines and the derivatives, various indoles under mild conditions in high efficiencies. N‐methylation of various anilines is also developed. Mechanistic studies indicate that the hydrogenation occurs via a transfer hydrogenation pathway.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cctc.202101099</doi><tpages>5</tpages></addata></record> |
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| subjects | Aniline Biomass Formic acid hydrogen source Hydrogenation Indoles Lignocellulose lignocellulosic biomass Methylation N-methylation Organic compounds renewable formic acid |
| title | Utilization of renewable formic acid from lignocellulosic biomass for the selective hydrogenation and/or N‐methylation |
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