Regio- and stereoselective (3 + 2)-cycloaddition reactions of nitrones with cyclic allenes

An effective approach to access functionalized 2 H -cyclonona(deca)[ d ]isoxazoles and 15-oxo-3,10-methanobenzo[ b ][1]azacyclododecines has been developed by the reaction of N -aryl- C , C -bis(methoxycarbonyl)nitrones with cyclonona(deca)-1,2-dienes in a one-pot fashion. The reaction of N -aryl- C...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-11, Vol.19 (44), p.9773-9784
Hauptverfasser:	Efremova, Mariia M, Makarova, Anastasia A, Novikov, Alexander S, Kryukova, Mariya A, Kuznetsov, Mikhail A, Molchanov, Alexander P
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Chemical reactions Cycloaddition Dienes Isoxazolidines Quantum chemistry Regioselectivity Stereoselectivity
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