Microstructure and mechanical properties of Ag nanoparticles-modified Sn–58Bi/Cu solder joints during liquid-state reaction

Alloying various elements into the solders or the Cu substrate has been conducted to prevent embrittlement of Sn–Bi/Cu solder joints, caused by Bi segregation and growth of Kirkendall voids, via changes in the intermetallic compounds (IMCs) and interfacial microstructure of the solder joints. In thi...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2021-12, Vol.32 (24), p.28346-28357
Hauptverfasser: Park, Dae-Young, Kim, Jungsoo, Yu, Dong-Yurl, Yoo, Sehoon, Park, Hyun-Soon, Sohn, Yoonchul, Ko, Yong-Ho
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container_end_page 28357
container_issue 24
container_start_page 28346
container_title Journal of materials science. Materials in electronics
container_volume 32
creator Park, Dae-Young
Kim, Jungsoo
Yu, Dong-Yurl
Yoo, Sehoon
Park, Hyun-Soon
Sohn, Yoonchul
Ko, Yong-Ho
description Alloying various elements into the solders or the Cu substrate has been conducted to prevent embrittlement of Sn–Bi/Cu solder joints, caused by Bi segregation and growth of Kirkendall voids, via changes in the intermetallic compounds (IMCs) and interfacial microstructure of the solder joints. In this study, reactions between Cu and Sn–58Bi alloyed with Ag nanoparticles (NPs) were investigated by varying number of reflow. Even after 9 times of reflow, formation of Cu 3 Sn and Kirkendall void was not much observed at the interface, contrary to what is expected in Sn–58Bi/Cu solder joints after solid-state aging. The experimental results revealed that alloying a large amount of Ag was not helpful to strengthening the solder joint, whereas small addition of Ag NPs (0.5 wt.%) effectively improved the mechanical reliability via refinement of the eutectic microstructure of Sn–58Bi solder and suppression of growth of the Cu 6 Sn 5 grains at the interface. With increasing amount of Ag NPs, shear strength decreased because of increase and coarsening of Ag 3 Sn particles and formation of weak interfaces of solder/Ag 3 Sn and Ag 3 Sn/Cu 6 Sn 5 , where brittle fracture was observed. For liquid-state reaction, addition of a small amount of Ag into Sn–58Bi solder was successful to enhance mechanical reliability without formation of Kirkendall voids at the reaction interface.
doi_str_mv 10.1007/s10854-021-07210-9
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In this study, reactions between Cu and Sn–58Bi alloyed with Ag nanoparticles (NPs) were investigated by varying number of reflow. Even after 9 times of reflow, formation of Cu 3 Sn and Kirkendall void was not much observed at the interface, contrary to what is expected in Sn–58Bi/Cu solder joints after solid-state aging. The experimental results revealed that alloying a large amount of Ag was not helpful to strengthening the solder joint, whereas small addition of Ag NPs (0.5 wt.%) effectively improved the mechanical reliability via refinement of the eutectic microstructure of Sn–58Bi solder and suppression of growth of the Cu 6 Sn 5 grains at the interface. With increasing amount of Ag NPs, shear strength decreased because of increase and coarsening of Ag 3 Sn particles and formation of weak interfaces of solder/Ag 3 Sn and Ag 3 Sn/Cu 6 Sn 5 , where brittle fracture was observed. 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Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><addtitle>J MATER SCI-MATER EL</addtitle><description>Alloying various elements into the solders or the Cu substrate has been conducted to prevent embrittlement of Sn–Bi/Cu solder joints, caused by Bi segregation and growth of Kirkendall voids, via changes in the intermetallic compounds (IMCs) and interfacial microstructure of the solder joints. In this study, reactions between Cu and Sn–58Bi alloyed with Ag nanoparticles (NPs) were investigated by varying number of reflow. Even after 9 times of reflow, formation of Cu 3 Sn and Kirkendall void was not much observed at the interface, contrary to what is expected in Sn–58Bi/Cu solder joints after solid-state aging. The experimental results revealed that alloying a large amount of Ag was not helpful to strengthening the solder joint, whereas small addition of Ag NPs (0.5 wt.%) effectively improved the mechanical reliability via refinement of the eutectic microstructure of Sn–58Bi solder and suppression of growth of the Cu 6 Sn 5 grains at the interface. With increasing amount of Ag NPs, shear strength decreased because of increase and coarsening of Ag 3 Sn particles and formation of weak interfaces of solder/Ag 3 Sn and Ag 3 Sn/Cu 6 Sn 5 , where brittle fracture was observed. 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Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><stitle>J MATER SCI-MATER EL</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>32</volume><issue>24</issue><spage>28346</spage><epage>28357</epage><pages>28346-28357</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Alloying various elements into the solders or the Cu substrate has been conducted to prevent embrittlement of Sn–Bi/Cu solder joints, caused by Bi segregation and growth of Kirkendall voids, via changes in the intermetallic compounds (IMCs) and interfacial microstructure of the solder joints. In this study, reactions between Cu and Sn–58Bi alloyed with Ag nanoparticles (NPs) were investigated by varying number of reflow. Even after 9 times of reflow, formation of Cu 3 Sn and Kirkendall void was not much observed at the interface, contrary to what is expected in Sn–58Bi/Cu solder joints after solid-state aging. The experimental results revealed that alloying a large amount of Ag was not helpful to strengthening the solder joint, whereas small addition of Ag NPs (0.5 wt.%) effectively improved the mechanical reliability via refinement of the eutectic microstructure of Sn–58Bi solder and suppression of growth of the Cu 6 Sn 5 grains at the interface. With increasing amount of Ag NPs, shear strength decreased because of increase and coarsening of Ag 3 Sn particles and formation of weak interfaces of solder/Ag 3 Sn and Ag 3 Sn/Cu 6 Sn 5 , where brittle fracture was observed. For liquid-state reaction, addition of a small amount of Ag into Sn–58Bi solder was successful to enhance mechanical reliability without formation of Kirkendall voids at the reaction interface.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-021-07210-9</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-1619-8467</orcidid></addata></record>
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subjects Aging (metallurgy)
Alloying elements
Characterization and Evaluation of Materials
Chemistry and Materials Science
Copper
Engineering
Engineering, Electrical & Electronic
Interfaces
Intermetallic compounds
Materials Science
Materials Science, Multidisciplinary
Mechanical properties
Microstructure
Nanoparticles
Optical and Electronic Materials
Physical Sciences
Physics
Physics, Applied
Physics, Condensed Matter
Reliability
Science & Technology
Shear strength
Silver
Soldered joints
Solders
Substrates
Technology
Tin
title Microstructure and mechanical properties of Ag nanoparticles-modified Sn–58Bi/Cu solder joints during liquid-state reaction
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