Increasing Olefin Metathesis Activity of Silica‐Supported Molybdenum Imido Adamantylidene Complexes through E Ligand σ‐Donation

Molybdenum imido adamantylidene complexes with different substituents on the imido ligand (dipp=2,6‐diisopropylphenyl, ArF5=C6F5, and tBu) having distinct electron donating abilities were investigated for the metathesis of internal and terminal olefins, for both molecular and silica‐supported specie...

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Veröffentlicht in:	Helvetica chimica acta 2021-11, Vol.104 (11), p.n/a
Hauptverfasser:	Nater, Darryl F., Paul, Bhaskar, Lätsch, Lukas, Schrock, Richard R., Copéret, Christophe
Format:	Artikel
Sprache:	eng
Schlagworte:	adamantylidenes Alkenes Coordination compounds electron donation Immobilization Intermediates Ligands Metathesis Molybdenum olefin metathesis Silica Silicon dioxide surface chemistry surface organometallic chemistry
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