Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation
Optimization and sensitivity analysis of the kinetic parameters of the catalytic ozonation process is crucial to improve water treatment, reactor design, and construction. This study evaluated the optimization of the kinetic constants for Diclofenac (DCF) degradation during catalytic ozonation with...
Gespeichert in:
| Veröffentlicht in: | Water (Basel) 2021-11, Vol.13 (21), p.3003 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 21 |
| container_start_page | 3003 |
| container_title | Water (Basel) |
| container_volume | 13 |
| creator | Lara-Ramos, José Antonio Figueroa Angulo, Miguel A. Machuca-Martínez, Fiderman Mueses, Miguel A. |
| description | Optimization and sensitivity analysis of the kinetic parameters of the catalytic ozonation process is crucial to improve water treatment, reactor design, and construction. This study evaluated the optimization of the kinetic constants for Diclofenac (DCF) degradation during catalytic ozonation with Goethite (FeOOH, as a catalyst) through different kinetic modeling approaches. A central composite design was used to evaluate the effect of ozone dose and catalyst loading. The results showed that FeOOH did not significantly influence the degradation of DCF, while the reactivity of DCF with ozone was high (with >90% degradations in 20 min). However, the variation in catalyst loading significantly affected TOC removal (>10%) and ozone use, with ozone efficiency in ozone transfer (RU) 5% higher than ozonation. After evaluating the different kinetic models of reaction speed by optimizing kinetic parameters and performing sensitivity analysis for the treatment of DCF by catalytic ozonation, it can be concluded that the addition of FeOOH improved the kinetics of the decomposition of ozone and the yield in the production of hydroxyl radicals. |
| doi_str_mv | 10.3390/w13213003 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2596058767</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2596058767</sourcerecordid><originalsourceid>FETCH-LOGICAL-c292t-b032b10a448ee873ebb497aa55e83a18a5dfe9ae72f8c9bf75a6d11d21939f1b3</originalsourceid><addsrcrecordid>eNpNkE1LAzEQhoMoWGoP_oOAJw_VfOx2k2Np_cJKD-p5md2dtClrUpNUWX-9WyviXGYYHh5mXkLOObuSUrPrTy4Fl4zJIzIQrJDjLMv48b_5lIxi3LC-Mq1Uzgake0YXbbIfNnV06qDtoo3UG5rWSGeQ-kWyNV1-eQfJekd3rsFA59YYDOgSfbQO98STb7C1bkWn223wUK8xUut-NHNbt96gg5rOcRWg-TGdkRMDbcTRbx-S19ubl9n9eLG8e5hNF-NaaJHGFZOi4gyyTCGqQmJVZboAyHNUEriCvDGoAQthVK0rU-QwaThvBNdSG17JIbk4ePuz3ncYU7nxu9B_GkuR6wnLVTEpeuryQNXBxxjQlNtg3yB0JWflPtzyL1z5DT4WbYE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2596058767</pqid></control><display><type>article</type><title>Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><creator>Lara-Ramos, José Antonio ; Figueroa Angulo, Miguel A. ; Machuca-Martínez, Fiderman ; Mueses, Miguel A.</creator><creatorcontrib>Lara-Ramos, José Antonio ; Figueroa Angulo, Miguel A. ; Machuca-Martínez, Fiderman ; Mueses, Miguel A.</creatorcontrib><description>Optimization and sensitivity analysis of the kinetic parameters of the catalytic ozonation process is crucial to improve water treatment, reactor design, and construction. This study evaluated the optimization of the kinetic constants for Diclofenac (DCF) degradation during catalytic ozonation with Goethite (FeOOH, as a catalyst) through different kinetic modeling approaches. A central composite design was used to evaluate the effect of ozone dose and catalyst loading. The results showed that FeOOH did not significantly influence the degradation of DCF, while the reactivity of DCF with ozone was high (with >90% degradations in 20 min). However, the variation in catalyst loading significantly affected TOC removal (>10%) and ozone use, with ozone efficiency in ozone transfer (RU) 5% higher than ozonation. After evaluating the different kinetic models of reaction speed by optimizing kinetic parameters and performing sensitivity analysis for the treatment of DCF by catalytic ozonation, it can be concluded that the addition of FeOOH improved the kinetics of the decomposition of ozone and the yield in the production of hydroxyl radicals.</description><identifier>ISSN: 2073-4441</identifier><identifier>EISSN: 2073-4441</identifier><identifier>DOI: 10.3390/w13213003</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Catalysts ; Degradation ; Design analysis ; Diclofenac ; Free radicals ; Goethite ; Hydroxyl radicals ; Mineralization ; Modelling ; Nonsteroidal anti-inflammatory drugs ; Optimization ; Oxidation ; Ozonation ; Ozone ; Parameter sensitivity ; Pharmaceuticals ; Reactor design ; Sensitivity analysis ; Water treatment</subject><ispartof>Water (Basel), 2021-11, Vol.13 (21), p.3003</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c292t-b032b10a448ee873ebb497aa55e83a18a5dfe9ae72f8c9bf75a6d11d21939f1b3</citedby><cites>FETCH-LOGICAL-c292t-b032b10a448ee873ebb497aa55e83a18a5dfe9ae72f8c9bf75a6d11d21939f1b3</cites><orcidid>0000-0002-4553-3957 ; 0000-0001-6324-5150 ; 0000-0003-1374-3877</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lara-Ramos, José Antonio</creatorcontrib><creatorcontrib>Figueroa Angulo, Miguel A.</creatorcontrib><creatorcontrib>Machuca-Martínez, Fiderman</creatorcontrib><creatorcontrib>Mueses, Miguel A.</creatorcontrib><title>Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation</title><title>Water (Basel)</title><description>Optimization and sensitivity analysis of the kinetic parameters of the catalytic ozonation process is crucial to improve water treatment, reactor design, and construction. This study evaluated the optimization of the kinetic constants for Diclofenac (DCF) degradation during catalytic ozonation with Goethite (FeOOH, as a catalyst) through different kinetic modeling approaches. A central composite design was used to evaluate the effect of ozone dose and catalyst loading. The results showed that FeOOH did not significantly influence the degradation of DCF, while the reactivity of DCF with ozone was high (with >90% degradations in 20 min). However, the variation in catalyst loading significantly affected TOC removal (>10%) and ozone use, with ozone efficiency in ozone transfer (RU) 5% higher than ozonation. After evaluating the different kinetic models of reaction speed by optimizing kinetic parameters and performing sensitivity analysis for the treatment of DCF by catalytic ozonation, it can be concluded that the addition of FeOOH improved the kinetics of the decomposition of ozone and the yield in the production of hydroxyl radicals.</description><subject>Catalysts</subject><subject>Degradation</subject><subject>Design analysis</subject><subject>Diclofenac</subject><subject>Free radicals</subject><subject>Goethite</subject><subject>Hydroxyl radicals</subject><subject>Mineralization</subject><subject>Modelling</subject><subject>Nonsteroidal anti-inflammatory drugs</subject><subject>Optimization</subject><subject>Oxidation</subject><subject>Ozonation</subject><subject>Ozone</subject><subject>Parameter sensitivity</subject><subject>Pharmaceuticals</subject><subject>Reactor design</subject><subject>Sensitivity analysis</subject><subject>Water treatment</subject><issn>2073-4441</issn><issn>2073-4441</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpNkE1LAzEQhoMoWGoP_oOAJw_VfOx2k2Np_cJKD-p5md2dtClrUpNUWX-9WyviXGYYHh5mXkLOObuSUrPrTy4Fl4zJIzIQrJDjLMv48b_5lIxi3LC-Mq1Uzgake0YXbbIfNnV06qDtoo3UG5rWSGeQ-kWyNV1-eQfJekd3rsFA59YYDOgSfbQO98STb7C1bkWn223wUK8xUut-NHNbt96gg5rOcRWg-TGdkRMDbcTRbx-S19ubl9n9eLG8e5hNF-NaaJHGFZOi4gyyTCGqQmJVZboAyHNUEriCvDGoAQthVK0rU-QwaThvBNdSG17JIbk4ePuz3ncYU7nxu9B_GkuR6wnLVTEpeuryQNXBxxjQlNtg3yB0JWflPtzyL1z5DT4WbYE</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Lara-Ramos, José Antonio</creator><creator>Figueroa Angulo, Miguel A.</creator><creator>Machuca-Martínez, Fiderman</creator><creator>Mueses, Miguel A.</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-4553-3957</orcidid><orcidid>https://orcid.org/0000-0001-6324-5150</orcidid><orcidid>https://orcid.org/0000-0003-1374-3877</orcidid></search><sort><creationdate>20211101</creationdate><title>Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation</title><author>Lara-Ramos, José Antonio ; Figueroa Angulo, Miguel A. ; Machuca-Martínez, Fiderman ; Mueses, Miguel A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c292t-b032b10a448ee873ebb497aa55e83a18a5dfe9ae72f8c9bf75a6d11d21939f1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Catalysts</topic><topic>Degradation</topic><topic>Design analysis</topic><topic>Diclofenac</topic><topic>Free radicals</topic><topic>Goethite</topic><topic>Hydroxyl radicals</topic><topic>Mineralization</topic><topic>Modelling</topic><topic>Nonsteroidal anti-inflammatory drugs</topic><topic>Optimization</topic><topic>Oxidation</topic><topic>Ozonation</topic><topic>Ozone</topic><topic>Parameter sensitivity</topic><topic>Pharmaceuticals</topic><topic>Reactor design</topic><topic>Sensitivity analysis</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lara-Ramos, José Antonio</creatorcontrib><creatorcontrib>Figueroa Angulo, Miguel A.</creatorcontrib><creatorcontrib>Machuca-Martínez, Fiderman</creatorcontrib><creatorcontrib>Mueses, Miguel A.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Water (Basel)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lara-Ramos, José Antonio</au><au>Figueroa Angulo, Miguel A.</au><au>Machuca-Martínez, Fiderman</au><au>Mueses, Miguel A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation</atitle><jtitle>Water (Basel)</jtitle><date>2021-11-01</date><risdate>2021</risdate><volume>13</volume><issue>21</issue><spage>3003</spage><pages>3003-</pages><issn>2073-4441</issn><eissn>2073-4441</eissn><abstract>Optimization and sensitivity analysis of the kinetic parameters of the catalytic ozonation process is crucial to improve water treatment, reactor design, and construction. This study evaluated the optimization of the kinetic constants for Diclofenac (DCF) degradation during catalytic ozonation with Goethite (FeOOH, as a catalyst) through different kinetic modeling approaches. A central composite design was used to evaluate the effect of ozone dose and catalyst loading. The results showed that FeOOH did not significantly influence the degradation of DCF, while the reactivity of DCF with ozone was high (with >90% degradations in 20 min). However, the variation in catalyst loading significantly affected TOC removal (>10%) and ozone use, with ozone efficiency in ozone transfer (RU) 5% higher than ozonation. After evaluating the different kinetic models of reaction speed by optimizing kinetic parameters and performing sensitivity analysis for the treatment of DCF by catalytic ozonation, it can be concluded that the addition of FeOOH improved the kinetics of the decomposition of ozone and the yield in the production of hydroxyl radicals.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/w13213003</doi><orcidid>https://orcid.org/0000-0002-4553-3957</orcidid><orcidid>https://orcid.org/0000-0001-6324-5150</orcidid><orcidid>https://orcid.org/0000-0003-1374-3877</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2073-4441 |
| ispartof | Water (Basel), 2021-11, Vol.13 (21), p.3003 |
| issn | 2073-4441 2073-4441 |
| language | eng |
| recordid | cdi_proquest_journals_2596058767 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals |
| subjects | Catalysts Degradation Design analysis Diclofenac Free radicals Goethite Hydroxyl radicals Mineralization Modelling Nonsteroidal anti-inflammatory drugs Optimization Oxidation Ozonation Ozone Parameter sensitivity Pharmaceuticals Reactor design Sensitivity analysis Water treatment |
| title | Sensitivity Analysis of the Catalytic Ozonation under Different Kinetic Modeling Approaches in the Diclofenac Degradation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T22%3A23%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sensitivity%20Analysis%20of%20the%20Catalytic%20Ozonation%20under%20Different%20Kinetic%20Modeling%20Approaches%20in%20the%20Diclofenac%20Degradation&rft.jtitle=Water%20(Basel)&rft.au=Lara-Ramos,%20Jos%C3%A9%20Antonio&rft.date=2021-11-01&rft.volume=13&rft.issue=21&rft.spage=3003&rft.pages=3003-&rft.issn=2073-4441&rft.eissn=2073-4441&rft_id=info:doi/10.3390/w13213003&rft_dat=%3Cproquest_cross%3E2596058767%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2596058767&rft_id=info:pmid/&rfr_iscdi=true |