Structural-Morphological and Adhesive Properties of Calcium-Phosphate Coatings Formed on a Magnesium Alloy by Microarc Oxidation in an Electrolyte Containing Disperse Particles

Common patterns of calcium-phosphate coating formation by the method of micro-arc oxidation (MAO) in the anodic potentiostatic mode on the Mg0.8Ca alloy surface in an electrolyte containing disperse particles of beta tricalcium phosphate (β-TCP) are studied. As a result of plasma-chemical reactions...

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Veröffentlicht in:Russian physics journal 2021-09, Vol.64 (5), p.830-837
Hauptverfasser: Sedelnikova, M. B., Ugodchikova, A. V., Uvarkin, P. V., Chebodaeva, V. V., Tolkacheva, T. V., Schmidt, J., Sharkeev, Yu. P.
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container_issue 5
container_start_page 830
container_title Russian physics journal
container_volume 64
creator Sedelnikova, M. B.
Ugodchikova, A. V.
Uvarkin, P. V.
Chebodaeva, V. V.
Tolkacheva, T. V.
Schmidt, J.
Sharkeev, Yu. P.
description Common patterns of calcium-phosphate coating formation by the method of micro-arc oxidation (MAO) in the anodic potentiostatic mode on the Mg0.8Ca alloy surface in an electrolyte containing disperse particles of beta tricalcium phosphate (β-TCP) are studied. As a result of plasma-chemical reactions of interaction between the components of the electrolyte and the magnesium substrate, with the MAO voltage varied in the range of 350–500 V, a porous ceramic-like coating with β-TCP particles is formed on the surface. The influence of the structural-morphological properties of the coatings, formed under different voltages, on their adhesion properties is determined. The highest adhesive strength at a value of the ultimate load of 19 N is exhibited by the coatings with a thickness of 80 μm, a roughness of 8 μm, a surface porosity of 23%, and an average pore size of 5.9 μm, deposited at the MAO voltage of 500 V. The fracture of these coatings is completed at the interface between the coating and the intermediate oxide layer between the coating and the magnesium substrate.
doi_str_mv 10.1007/s11182-021-02398-z
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subjects Adhesive strength
Adhesives
Analysis
Anodizing
Beta rays
Calcium phosphate
Calcium phosphates
Ceramic coatings
Chemical reactions
Coatings
Condensed Matter Physics
Electric potential
Electrolytes
Hadrons
Heavy Ions
Lasers
Magnesium alloys
Magnesium base alloys
Mathematical and Computational Physics
Morphology
Nuclear Physics
Optical Devices
Optics
Oxidation
Oxidation-reduction reaction
Phosphate coatings
Photonics
Physics
Physics and Astronomy
Pore size
Porosity
Specialty metals industry
Substrates
Theoretical
Transmission Control Protocol/Internet Protocol (Computer network protocol)
Ultimate loads
Voltage
title Structural-Morphological and Adhesive Properties of Calcium-Phosphate Coatings Formed on a Magnesium Alloy by Microarc Oxidation in an Electrolyte Containing Disperse Particles
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