Structural-Morphological and Adhesive Properties of Calcium-Phosphate Coatings Formed on a Magnesium Alloy by Microarc Oxidation in an Electrolyte Containing Disperse Particles
Common patterns of calcium-phosphate coating formation by the method of micro-arc oxidation (MAO) in the anodic potentiostatic mode on the Mg0.8Ca alloy surface in an electrolyte containing disperse particles of beta tricalcium phosphate (β-TCP) are studied. As a result of plasma-chemical reactions...
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Veröffentlicht in: | Russian physics journal 2021-09, Vol.64 (5), p.830-837 |
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description | Common patterns of calcium-phosphate coating formation by the method of micro-arc oxidation (MAO) in the anodic potentiostatic mode on the Mg0.8Ca alloy surface in an electrolyte containing disperse particles of beta tricalcium phosphate (β-TCP) are studied. As a result of plasma-chemical reactions of interaction between the components of the electrolyte and the magnesium substrate, with the MAO voltage varied in the range of 350–500 V, a porous ceramic-like coating with β-TCP particles is formed on the surface. The influence of the structural-morphological properties of the coatings, formed under different voltages, on their adhesion properties is determined. The highest adhesive strength at a value of the ultimate load of 19 N is exhibited by the coatings with a thickness of 80 μm, a roughness of 8 μm, a surface porosity of 23%, and an average pore size of 5.9 μm, deposited at the MAO voltage of 500 V. The fracture of these coatings is completed at the interface between the coating and the intermediate oxide layer between the coating and the magnesium substrate. |
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The highest adhesive strength at a value of the ultimate load of 19 N is exhibited by the coatings with a thickness of 80 μm, a roughness of 8 μm, a surface porosity of 23%, and an average pore size of 5.9 μm, deposited at the MAO voltage of 500 V. The fracture of these coatings is completed at the interface between the coating and the intermediate oxide layer between the coating and the magnesium substrate.</description><identifier>ISSN: 1064-8887</identifier><identifier>EISSN: 1573-9228</identifier><identifier>DOI: 10.1007/s11182-021-02398-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adhesive strength ; Adhesives ; Analysis ; Anodizing ; Beta rays ; Calcium phosphate ; Calcium phosphates ; Ceramic coatings ; Chemical reactions ; Coatings ; Condensed Matter Physics ; Electric potential ; Electrolytes ; Hadrons ; Heavy Ions ; Lasers ; Magnesium alloys ; Magnesium base alloys ; Mathematical and Computational Physics ; Morphology ; Nuclear Physics ; Optical Devices ; Optics ; Oxidation ; Oxidation-reduction reaction ; Phosphate coatings ; Photonics ; Physics ; Physics and Astronomy ; Pore size ; Porosity ; Specialty metals industry ; Substrates ; Theoretical ; Transmission Control Protocol/Internet Protocol (Computer network protocol) ; Ultimate loads ; Voltage</subject><ispartof>Russian physics journal, 2021-09, Vol.64 (5), p.830-837</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>COPYRIGHT 2022 Springer</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c397t-3dc5680fecd18833ad2154063f01fc1c63e92d442fd4085bd954390aa0c4e0f53</citedby><cites>FETCH-LOGICAL-c397t-3dc5680fecd18833ad2154063f01fc1c63e92d442fd4085bd954390aa0c4e0f53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11182-021-02398-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11182-021-02398-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sedelnikova, M. B.</creatorcontrib><creatorcontrib>Ugodchikova, A. V.</creatorcontrib><creatorcontrib>Uvarkin, P. V.</creatorcontrib><creatorcontrib>Chebodaeva, V. V.</creatorcontrib><creatorcontrib>Tolkacheva, T. V.</creatorcontrib><creatorcontrib>Schmidt, J.</creatorcontrib><creatorcontrib>Sharkeev, Yu. P.</creatorcontrib><title>Structural-Morphological and Adhesive Properties of Calcium-Phosphate Coatings Formed on a Magnesium Alloy by Microarc Oxidation in an Electrolyte Containing Disperse Particles</title><title>Russian physics journal</title><addtitle>Russ Phys J</addtitle><description>Common patterns of calcium-phosphate coating formation by the method of micro-arc oxidation (MAO) in the anodic potentiostatic mode on the Mg0.8Ca alloy surface in an electrolyte containing disperse particles of beta tricalcium phosphate (β-TCP) are studied. As a result of plasma-chemical reactions of interaction between the components of the electrolyte and the magnesium substrate, with the MAO voltage varied in the range of 350–500 V, a porous ceramic-like coating with β-TCP particles is formed on the surface. The influence of the structural-morphological properties of the coatings, formed under different voltages, on their adhesion properties is determined. The highest adhesive strength at a value of the ultimate load of 19 N is exhibited by the coatings with a thickness of 80 μm, a roughness of 8 μm, a surface porosity of 23%, and an average pore size of 5.9 μm, deposited at the MAO voltage of 500 V. The fracture of these coatings is completed at the interface between the coating and the intermediate oxide layer between the coating and the magnesium substrate.</description><subject>Adhesive strength</subject><subject>Adhesives</subject><subject>Analysis</subject><subject>Anodizing</subject><subject>Beta rays</subject><subject>Calcium phosphate</subject><subject>Calcium phosphates</subject><subject>Ceramic coatings</subject><subject>Chemical reactions</subject><subject>Coatings</subject><subject>Condensed Matter Physics</subject><subject>Electric potential</subject><subject>Electrolytes</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Lasers</subject><subject>Magnesium alloys</subject><subject>Magnesium base alloys</subject><subject>Mathematical and Computational Physics</subject><subject>Morphology</subject><subject>Nuclear Physics</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Oxidation</subject><subject>Oxidation-reduction reaction</subject><subject>Phosphate coatings</subject><subject>Photonics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Pore size</subject><subject>Porosity</subject><subject>Specialty metals industry</subject><subject>Substrates</subject><subject>Theoretical</subject><subject>Transmission Control Protocol/Internet Protocol (Computer network protocol)</subject><subject>Ultimate loads</subject><subject>Voltage</subject><issn>1064-8887</issn><issn>1573-9228</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqNkdtqFTEYhQdRsFZfwKuA16k5zCFzudm2KnTTgnod0hxmp2SSMclId5_KR_S3I3gnEkJCWN9aP1lN85aSC0rI8L5QSgXDhFHYfBT48VlzRruB45Ex8RzupG-xEGJ42bwq5Z4QwPrhrPn5peZV1zWrgA8pL8cU0uS1CkhFg3bmaIv_YdFtTovN1duCkkN7FbRfZ3x7TGU5qmrRPqnq41TQVcqzNShFpNBBTRHwdUa7ENIJ3Z3QweucVNbo5sEbQEDnQRrRZbC65hROT2axKh_BD33wBXILDKAgXQdbXjcvnArFvvlznjffri6_7j_h65uPn_e7a6z5OFTMje56QZzVhgrBuTKMdi3puSPUaap7bkdm2pY50xLR3Zmxa_lIlCK6tcR1_Lx5t_kuOX1fbanyPq05QqRk3dgTMOMUVBebalLBSh9dqllpWMbOXqdonYf33QDWnNOh_V-gHwfOgeoBYBsAH1dKtk4u2c8qnyQl8nf3cuteQvfyqXv5CBDfoALiONn8d_h_UL8An6q1Dw</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Sedelnikova, M. 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As a result of plasma-chemical reactions of interaction between the components of the electrolyte and the magnesium substrate, with the MAO voltage varied in the range of 350–500 V, a porous ceramic-like coating with β-TCP particles is formed on the surface. The influence of the structural-morphological properties of the coatings, formed under different voltages, on their adhesion properties is determined. The highest adhesive strength at a value of the ultimate load of 19 N is exhibited by the coatings with a thickness of 80 μm, a roughness of 8 μm, a surface porosity of 23%, and an average pore size of 5.9 μm, deposited at the MAO voltage of 500 V. The fracture of these coatings is completed at the interface between the coating and the intermediate oxide layer between the coating and the magnesium substrate.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11182-021-02398-z</doi><tpages>8</tpages></addata></record> |
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subjects | Adhesive strength Adhesives Analysis Anodizing Beta rays Calcium phosphate Calcium phosphates Ceramic coatings Chemical reactions Coatings Condensed Matter Physics Electric potential Electrolytes Hadrons Heavy Ions Lasers Magnesium alloys Magnesium base alloys Mathematical and Computational Physics Morphology Nuclear Physics Optical Devices Optics Oxidation Oxidation-reduction reaction Phosphate coatings Photonics Physics Physics and Astronomy Pore size Porosity Specialty metals industry Substrates Theoretical Transmission Control Protocol/Internet Protocol (Computer network protocol) Ultimate loads Voltage |
title | Structural-Morphological and Adhesive Properties of Calcium-Phosphate Coatings Formed on a Magnesium Alloy by Microarc Oxidation in an Electrolyte Containing Disperse Particles |
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