Highly dispersed Ni nanocatalysts supported by MOFs derived hierarchical N-doped porous carbon for hydrogenation of dicyclopentadiene
N-doped carbon possesses the advantages of electronic modification and immobilization of metal nanoparticles. Hence, N-doped carbon-based metal catalysts have received extensive attention. This study prepared uniformly dispersed Ni nanoparticles (24.0 wt%) on porous N-doped carbon, which was fabrica...
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| Veröffentlicht in: | Carbon (New York) 2021-10, Vol.184, p.855-863 |
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| creator | Jia, Dandan Zhao, Jie Tao, Zhiping Gao, Hongyi Fu, Zhaolin Yan, Rui Zhu, Zhongpeng Shu, Xingtian Wang, Ge |
| description | N-doped carbon possesses the advantages of electronic modification and immobilization of metal nanoparticles. Hence, N-doped carbon-based metal catalysts have received extensive attention. This study prepared uniformly dispersed Ni nanoparticles (24.0 wt%) on porous N-doped carbon, which was fabricated via the high temperature pyrolysis of nitrogen-rich ZnNi MOFs with 1H-1,2,3-triazole as the ligand. The 1H-1,2,3-triazole as a high energy ligand could volatilize violently to form a N-doped macroporous carbon-based structure. Zn acted as a fence and prevented the accumulation of Ni during the pyrolysis of ZnNi MOFs. The synergistic effect from the abundant porous structure together with uniformly dispersed Ni nanoparticles proves the excellent catalytic activity toward the hydrogenation of dicyclopentadiene, showing 100% DCPD conversion and >99% THDCPD selectivity.
Uniformly dispersed Ni nanocatalyst on porous N-doped carbon which was fabricated through increasing the pyrolysis temperature of ZnNi MOFs, shows enhanced catalytic activity toward the hydrogenation of DCPD. [Display omitted] |
| doi_str_mv | 10.1016/j.carbon.2021.09.002 |
| format | Article |
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Uniformly dispersed Ni nanocatalyst on porous N-doped carbon which was fabricated through increasing the pyrolysis temperature of ZnNi MOFs, shows enhanced catalytic activity toward the hydrogenation of DCPD. [Display omitted]</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2021.09.002</identifier><language>eng</language><publisher>New York: Elsevier Ltd</publisher><subject>Carbon ; Catalytic activity ; Catalytic converters ; Dispersion ; Electrocatalysis ; High temperature ; Hydrogenation ; Hydrogenation of dicyclopentadiene ; Ligands ; Metal-organic frameworks ; Nanoparticles ; Ni nanocatalysts ; Nickel ; Nitrogen ; Porous carbon ; Porous materials ; Pyrolysis ; Selectivity ; Studies ; Synergistic effect ; Triazoles ; ZnNi MOFs derivatives</subject><ispartof>Carbon (New York), 2021-10, Vol.184, p.855-863</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Oct 30, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c264t-d1ea4a4e7b6a263d0eb850d175a76c967cb1b1f136c7d0dcd4b04f8d54d470093</citedby><cites>FETCH-LOGICAL-c264t-d1ea4a4e7b6a263d0eb850d175a76c967cb1b1f136c7d0dcd4b04f8d54d470093</cites><orcidid>0000-0001-6709-5874</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbon.2021.09.002$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids></links><search><creatorcontrib>Jia, Dandan</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Tao, Zhiping</creatorcontrib><creatorcontrib>Gao, Hongyi</creatorcontrib><creatorcontrib>Fu, Zhaolin</creatorcontrib><creatorcontrib>Yan, Rui</creatorcontrib><creatorcontrib>Zhu, Zhongpeng</creatorcontrib><creatorcontrib>Shu, Xingtian</creatorcontrib><creatorcontrib>Wang, Ge</creatorcontrib><title>Highly dispersed Ni nanocatalysts supported by MOFs derived hierarchical N-doped porous carbon for hydrogenation of dicyclopentadiene</title><title>Carbon (New York)</title><description>N-doped carbon possesses the advantages of electronic modification and immobilization of metal nanoparticles. Hence, N-doped carbon-based metal catalysts have received extensive attention. This study prepared uniformly dispersed Ni nanoparticles (24.0 wt%) on porous N-doped carbon, which was fabricated via the high temperature pyrolysis of nitrogen-rich ZnNi MOFs with 1H-1,2,3-triazole as the ligand. The 1H-1,2,3-triazole as a high energy ligand could volatilize violently to form a N-doped macroporous carbon-based structure. Zn acted as a fence and prevented the accumulation of Ni during the pyrolysis of ZnNi MOFs. The synergistic effect from the abundant porous structure together with uniformly dispersed Ni nanoparticles proves the excellent catalytic activity toward the hydrogenation of dicyclopentadiene, showing 100% DCPD conversion and >99% THDCPD selectivity.
Uniformly dispersed Ni nanocatalyst on porous N-doped carbon which was fabricated through increasing the pyrolysis temperature of ZnNi MOFs, shows enhanced catalytic activity toward the hydrogenation of DCPD. [Display omitted]</description><subject>Carbon</subject><subject>Catalytic activity</subject><subject>Catalytic converters</subject><subject>Dispersion</subject><subject>Electrocatalysis</subject><subject>High temperature</subject><subject>Hydrogenation</subject><subject>Hydrogenation of dicyclopentadiene</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>Nanoparticles</subject><subject>Ni nanocatalysts</subject><subject>Nickel</subject><subject>Nitrogen</subject><subject>Porous carbon</subject><subject>Porous materials</subject><subject>Pyrolysis</subject><subject>Selectivity</subject><subject>Studies</subject><subject>Synergistic effect</subject><subject>Triazoles</subject><subject>ZnNi MOFs derivatives</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UEFOwzAQtBBIlMIPOFjinLB2HCe5IKGKUqTSXuBsObbTugpxsNNKeQD_xlU4c1rt7szsziB0TyAlQPjjIVXS165LKVCSQpUC0As0I2WRJVlZkUs0A4Ay4ZRm1-gmhENsWUnYDP2s7G7fjljb0BsfjMYbizvZOSUH2Y5hCDgc-975Ia7qEb9vlwFr4-0p9ntrvPRqb5Vs8SbRro_DiHXHgKePcOM83o_au53p5GDjxDXxmBpVG9HdILU1nblFV41sg7n7q3P0uXz5WKyS9fb1bfG8ThTlbEg0MZJJZoqaS8ozDaYuc9CkyGXBVcULVZOaNCTjqtCglWY1sKbUOdOsAKiyOXqYdHvvvo8mDOLgjr6LJwXNq5wwyksSUWxCKe9C8KYRvbdf0o-CgDgHLg5isifOgQuoRAw80p4mmokOTjEaEVQ0p4y23qhBaGf_F_gFm-SOWg</recordid><startdate>20211030</startdate><enddate>20211030</enddate><creator>Jia, Dandan</creator><creator>Zhao, Jie</creator><creator>Tao, Zhiping</creator><creator>Gao, Hongyi</creator><creator>Fu, Zhaolin</creator><creator>Yan, Rui</creator><creator>Zhu, Zhongpeng</creator><creator>Shu, Xingtian</creator><creator>Wang, Ge</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-6709-5874</orcidid></search><sort><creationdate>20211030</creationdate><title>Highly dispersed Ni nanocatalysts supported by MOFs derived hierarchical N-doped porous carbon for hydrogenation of dicyclopentadiene</title><author>Jia, Dandan ; Zhao, Jie ; Tao, Zhiping ; Gao, Hongyi ; Fu, Zhaolin ; Yan, Rui ; Zhu, Zhongpeng ; Shu, Xingtian ; Wang, Ge</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-d1ea4a4e7b6a263d0eb850d175a76c967cb1b1f136c7d0dcd4b04f8d54d470093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Carbon</topic><topic>Catalytic activity</topic><topic>Catalytic converters</topic><topic>Dispersion</topic><topic>Electrocatalysis</topic><topic>High temperature</topic><topic>Hydrogenation</topic><topic>Hydrogenation of dicyclopentadiene</topic><topic>Ligands</topic><topic>Metal-organic frameworks</topic><topic>Nanoparticles</topic><topic>Ni nanocatalysts</topic><topic>Nickel</topic><topic>Nitrogen</topic><topic>Porous carbon</topic><topic>Porous materials</topic><topic>Pyrolysis</topic><topic>Selectivity</topic><topic>Studies</topic><topic>Synergistic effect</topic><topic>Triazoles</topic><topic>ZnNi MOFs derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jia, Dandan</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Tao, Zhiping</creatorcontrib><creatorcontrib>Gao, Hongyi</creatorcontrib><creatorcontrib>Fu, Zhaolin</creatorcontrib><creatorcontrib>Yan, Rui</creatorcontrib><creatorcontrib>Zhu, Zhongpeng</creatorcontrib><creatorcontrib>Shu, Xingtian</creatorcontrib><creatorcontrib>Wang, Ge</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Dandan</au><au>Zhao, Jie</au><au>Tao, Zhiping</au><au>Gao, Hongyi</au><au>Fu, Zhaolin</au><au>Yan, Rui</au><au>Zhu, Zhongpeng</au><au>Shu, Xingtian</au><au>Wang, Ge</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly dispersed Ni nanocatalysts supported by MOFs derived hierarchical N-doped porous carbon for hydrogenation of dicyclopentadiene</atitle><jtitle>Carbon (New York)</jtitle><date>2021-10-30</date><risdate>2021</risdate><volume>184</volume><spage>855</spage><epage>863</epage><pages>855-863</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><abstract>N-doped carbon possesses the advantages of electronic modification and immobilization of metal nanoparticles. Hence, N-doped carbon-based metal catalysts have received extensive attention. This study prepared uniformly dispersed Ni nanoparticles (24.0 wt%) on porous N-doped carbon, which was fabricated via the high temperature pyrolysis of nitrogen-rich ZnNi MOFs with 1H-1,2,3-triazole as the ligand. The 1H-1,2,3-triazole as a high energy ligand could volatilize violently to form a N-doped macroporous carbon-based structure. Zn acted as a fence and prevented the accumulation of Ni during the pyrolysis of ZnNi MOFs. The synergistic effect from the abundant porous structure together with uniformly dispersed Ni nanoparticles proves the excellent catalytic activity toward the hydrogenation of dicyclopentadiene, showing 100% DCPD conversion and >99% THDCPD selectivity.
Uniformly dispersed Ni nanocatalyst on porous N-doped carbon which was fabricated through increasing the pyrolysis temperature of ZnNi MOFs, shows enhanced catalytic activity toward the hydrogenation of DCPD. [Display omitted]</abstract><cop>New York</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2021.09.002</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6709-5874</orcidid></addata></record> |
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| subjects | Carbon Catalytic activity Catalytic converters Dispersion Electrocatalysis High temperature Hydrogenation Hydrogenation of dicyclopentadiene Ligands Metal-organic frameworks Nanoparticles Ni nanocatalysts Nickel Nitrogen Porous carbon Porous materials Pyrolysis Selectivity Studies Synergistic effect Triazoles ZnNi MOFs derivatives |
| title | Highly dispersed Ni nanocatalysts supported by MOFs derived hierarchical N-doped porous carbon for hydrogenation of dicyclopentadiene |
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